• KSCE Journal of Civil and Environmental Engineering Research
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• v.29 no.1B
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• pp.105-109
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• 2009

It is a well known fact that baseflow discharge of rainfall runoff impacts on water quality of surface water significantly. In this paper, impacts of nitrate discharged as base flow on stream water quality were studied by using a software, PULSE from USGS to calculate monthly ground water discharge from hydrograph. We used water quality and flow rate data for Ghapcehon2 site in Daejeon city for year 2005 as well as ground water quality data in the watershed acquired from government agencies. Agricultural and forestry land use are dominant for upstream of Ghapcheon2 in the watershed. Base flow contributes about 85~95% of stream flows during spring and fall while 25~38% of stream flow was induced by base flow during summer and winter. Monthly nitrate loading discharged as base flow for Ghapcheon2 was estimated by using averaged nitrate concentration of groundwater in the watershed. Nitrate loading induced by base flow at Ghapcheon2 was estimated as 5.4 ton of $NO_{3}{^-}-N/km^{2}$, which is about 60% of nitrate loading of surface water, 9.2 ton of $NO_{3}{^-}-N/km^{2}$. Seasonal variation of nitrate concentration of base flow was estimated by dividing monthly nitrate loading by monthly base flow discharge. Nitrate concentration of groundwater was increasing from rainy season. From this study, it can be understood that ground water quality monitoring is important for the proper manage of surface water quality.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2003.04a
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• pp.107-110
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• 2003

Reduction of nitrate by zero valent iron (Fe$^{0}$ ) has been previously studied, but the proper treatment for the by-product of ammonium has not been reported. However, in terms of nitrogen contamination, ammonium may be regarded as another form of nitrogen contaminants since it can be oxidized to nitrate again under aerobic conditions. This study is focused on simultaneous removal of nitrate and its by-product of ammonium, with the ZanF (Zeolite anchored Fe), a product derived from zeolite modified by Fe(II) chloride followed by reduction with sodium borohydride. Batch experiments were performed without buffer at two different pH condition with ZanF, iron filing, Fe(II)-sorbed zeolite, and pure zeolite to estimate the nitrate reduction and the ammonium production. At higher pH, removal rate of nitrate was reduced in both ZanF and iron filings. ZnF removed 60 % of nitrate at initial pH of 3.3 with no production of ammonium, while iron filing showed equivalent production of ammonium to the reduced amount of nitrate. In terms of nitrogen contamination, ZanF removed about 60 % and 40 % at initial pH of 3.3 and 6, respectively, while iron filing presented negligible removal against total nitrogen including nitrate and ammonium.

• Journal of Korean Society for Atmospheric Environment
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• v.24 no.5
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• pp.613-621
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• 2008

The purpose of this study is to understand the impact that temperature and relative humidity have on the volatilization loss of particulate nitrate $(NO_3^-)$ from Teflon filters during measurements of ambient fine particles $(PM_{2.5})$. Fine particles $(d_p<2.5{\mu}m)$ were measured using an annular denuder system (ADS) at four representive areas in Seoul. The measurements were made during 28 different days at 24-hr sampling intervals from February 14 to October 15, 1997. In this study, nitrate losses. calculated by the ratio of nitrate on the nylon filter to their sum in both Teflon and nylon titters, varied seasonally in the following order: summer (45.5%) > spring (23.8%) > fall (20.6%) > winter (19.7%). The results showed strong correlations with temperature, but we did not observe any significant effects of relative humidity. However, we observed that both temperature and relative humidity influenced the ambient gas/particle nitrate ratio in a different case study using a denuder.

• Korean Journal of Environmental Agriculture
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• v.25 no.4
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• pp.339-345
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• 2006

Accumulation of nitrate in green vegetables is undesirable due to potential risks to human health. Lettuce was cultivated in pots under greenhouse conditions with compost applications of 2,000 and 4,000 kg/10a, and the growth and nitrate accumulation of lettuce were compared with those found in the lettuce cultivated with chemical fertilizers of recommended levels. Content of $NH_4-N$ in the soils of compost applications were much lower than those found in the soil of chemical fertilizer application. Two weeks after lettuce transplant $NH_4-N$ was not found in the soils of compost applications, and in the soils of chemical fertilizers application $NH_4-N$ was not found three weeks after lettuce transplant. One week after lettuce transplant content of $NO_3-N$ was much higher in the soils of compost applications, and the contents were rapidly decreased. While, the content of $NO_3-N$ in the soil of chemical fertilizers application was rapidly increased due to the nitrification of $NH_4$ released from the applied urea. At the time of harvest contents of $NO_3-N$ in the soils of compost applications were less than 1.4 mg/kg, but in the soil of chemical fertilizers application the content of $NO_3-N$ was 54.2 mg/kg. Contents of $NH_4$ in lettuce were about 20 mg/kg FW and were not much different among the treatments. However, contents of $NO_3$ in lettuce were significantly different between the treatments of chemical fertilizer and compost. There were significant differences in fresh and dry weights, and growth of lettuce in the compost treatment of 4,000 kg/10a was highest among the treatments. These results indicate that the cultivation with compost only as N source can produce higher yield of lettuce and significantly reduce nitrate accumulation as compared to the conventional cultivation with chemical fertilizers.

• Journal of Korean Society of Environmental Engineers
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• v.31 no.1
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• pp.29-34
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• 2009

This study was performed under four operational conditions for nitrogen removal in metal finishing wastewater. The conditions include electrode gap, reducing agent, the recycling of treated wastewater in 1st step and the simultaneous treatment of nitrate and other materials. Result showed that the removal efficiency of $NO_3{^-}-N$ was highest at the electrode gap of 10 mm. As the electrode gap was shorter than 10 mm, the removal efficiency of $NO_3{^-}-N$ decreased due to increasing in concentration polarization on electrode. And, in case that the electrode gap was longer than 10 mm, the removal efficiency of $NO_3{^-}-N$ increased with an increase in energy consumption. Because hydrogen ions are consumed when nitrate is reduced, reducing reaction of nitrate was effected more in acid solution. As 1.2 excess amount of zinc was injected, the removal efficiency of $NO_3{^-}-N$ increased due to increasing in amount of reaction with nitrate. As the effluent from 1st step in the reactor was recycled into the 1st step, the removal efficiency of $NO_3{^-}-N$ increased. Because the zinc were detached from the cathode and concentration-polarization was decreased due to formation of turbulence in the reactor. The presence of $NH_4{^+}-N$ did not affect the removal efficiency of $NO_3{^-}-N$ but the addition of heavy metal decreased the removal efficiency of $NO_3{^-}-N$. As chlorine is enough in wastewater, the simultaneous treatment of nitrate and ammonia nitrogen may be possible. The problem that heavy metal decrease the removal efficiency of $NO_3{^-}-N$ may be solved by increasing current density or using front step of electrochemical process for heavy metal removal.

• Journal of Korean Society for Atmospheric Environment
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• v.10 no.3
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• pp.191-196
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• 1994

Concentration of particulate nitrate originated from sea salt in ambient air was determined from February to October 1993. Sampling was carried out using a two-stage Anderson air sampler at the top of a five-story building located at Kon-Kuk University in Seoul. Concentration of NaNO$_3$, which originated from sea salt was highest in spring time and lowest in summer the and the concentration range was between 0.10 and 0.66 $\mu\textrm{g}$/㎥. NaNO$_3$/TSP ratio was very low 0.05~0.39%) indicating that the portion of NaNO$_3$ in TSP was negligible.

• Bulletin of the Korean Chemical Society
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• v.11 no.2
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• pp.124-126
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• 1990

The potentiometric response behavior of a polypyrrole(PPy) coated Pt electrode to nitrate ion has been studied. The electrode shows a nernstian behavior with a slope of 59 mV over 0.50 M to $1.0{\times}10^{-3}M\;NO_3\;^-$ and a detection limit of $1.0{\times}10^{-4}M\;NO_3\;^-$. The response of the electrode is fast and the selectivities for $I^-,\;ClO_4\;^-,\;and\;IO_4\;^-$ are found to be improved. The effect of pH on the potential response to $NO_3\;^-$ is compared with the existing nitrate ion selective electrodes.

• Bulletin of the Korean Chemical Society
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• v.7 no.5
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• pp.385-388
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• 1986

The reaction of cupric nitrate trihydrate with S-2-pyridyl thioates in acetonitrile was studied. The major products were the corresponding carboxylic acids and $[Cu(NO_3)(C_5H_4NS)(C_5H_5NS$)] (Complex A). Sometimes $[Cu(NO_3)(C_5H_4NS)(H_2O$)] was also obtained in addition to Complex A. When Complex A was recrystallized in dimethylsulfoxide, $[Cu(NO_3)(C_5H_4NS)(C_5H_5NS)$ {$(CH_3)_2SO$}$_2]{\cdot}2H_2O$ was crystallized. The structures of these copper complexes and the role of cupric nitrate in the hydrolysis of S-2-pyridyl thioates are discussed.

• Ocean and Polar Research
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• v.27 no.3
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• pp.341-349
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• 2005

Temporal variation of the natural planktonic community in the Southern Sea of Korea was investigated by using low floating enclosed bags (3.2m deep and 2,500 liter) in order to understand the effect of enriched nitrate on the planktonic community in the spring (March-April) of 2002. Prior to beginning the incubation, the bags were placed in two different concentrations of nitrate, which consisted of control (ambient water) and experimental mesocosms (final concentration of $12{\mu}M$). The nitrate concentration in the experimental mesocosms remained significantly higher than those in control mesocosms throughout the study period (ANOYA, p<0.001). Following the addition of nitrate, abundance and chi-a concentration of phytoplankton peaked on Day 1, when diatoms established the peak in the experimental mesocosms. Diatoms consisted mainly of Thalasxiosira decipiens, Pseudo-nitzschia pungem, Leptocylindrus danicu, Thalassionema nitzschioides, Chaetoceros pseudocrinitus and Actinoptychus senariu. However, the peak did not lead to the difference in abundance and composition of phytoplankton between control and experimental mesocosms during the study period. The dinoflagellates began to increase soon after the diatoms decreased in all mesocosms. Copepods, as a dominant group in the rnosozooplankton community, showed no immediate peak in relation to the nitrate addition, but only their own developmental process from the eggs to adult stage during the study period. The bottom-up control from enriched nitrate via phytoplankton to adult copepods was not distinguished in terms of the abundance of the planktonic community. This might stem from the relatively low nitrate availability of phytoplankton at no N-limited seawater and the weak coupling between rapidly sunken diatoms and copepods through the water column.

• Journal of the Korean Society of Food Science and Nutrition
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• v.28 no.5
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• pp.969-972
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• 1999

Nitrate is taken up from the soil by plants for protein synthesis and present in vegetables as a natural component and/or contaminant. The objective of this study was to estimate nitrate(NO3-) contents of some vegetables(Chinese cabbage, radish, lettuce, spinach) which were produced in Korea and to provide a scientific basis for the evaluation of risk to public health arising from dietary exposure to nitrate. A total of 400 samples were analysed for nitrate contents using our ion chromatography. From the results, in general, nitrate levels in vegetables produced by 2 harvest seasons were not different. The minimum, maximum and mean values of nitrate were 311, 5522 and 2788 for spinach; 542, 4484 and 2287 for lettuce; 273, 4151 and 1551 for radish; 362, 3015 and 1498(mg/kg) for Chinese cabbage. Nitrate contents of vegetables grown in Korea were similar to those of vegetables grown in other countries.