• Title/Summary/Keyword: new compositions in strontium thiosilicate

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Synthesis and Luminescence Properties of a Cyan-blue Thiosilicate-based Phosphor $SrSi_2S_5:Eu^{2+}$

  • Nakamuraa, Masayoshi;Katoa, Hideki;Takatsuka, Yuji;Petrykinc, Valery;Tezuka, Satoko;Kakihana, Masato
    • Journal of Information Display
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    • v.11 no.4
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    • pp.135-139
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    • 2010
  • A series of Sr-Si-S compounds was synthesized using an advanced chemical method in which the use of one solution-based process uniformly dispersed the $Eu^{2+}$ activators in the host crystals, to find new compositions that would suit phosphor applications. Particular focus was given to the Si-rich region. This led to the synthesis of a single-phase compound that showed an unknown X-ray diffraction pattern. This compound had a composition close to that of $SrSi_2S_5$. When this compound is activated with $Eu^{2+}$ ($SrSi_2S_5:Eu^{2+}$), it shows a cyan-blue emission with a main luminescence peak at 495 nm. This emission is excited by wavelengths of 250-440 nm and has a maximum excitation at 350 nm.