• Title/Summary/Keyword: negative emission

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Analysis of Space Charge Propagation in a Dielectric liquid Employing Field-Thermal Electron Emission Model and Finite Element Method (유한요소법과 전계-열전자 방출 모델에 의한 절연유체 내 공간전하 전파해석)

  • Lee, Ho-Young;Lee, Se-Hee
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.58 no.10
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    • pp.2011-2015
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    • 2009
  • In an insulating dielectric liquid such as transformer oil, space charge injection and propagation were analyzed under the Fowler-Nordheim and Richardson-Dushman's thermal emission charge injection conditions for blade-plane electrodes stressed by a step voltage. The governing equations were composed of all five equations such as the Poisson's equation for electric fields, three continuity equations for electrons, negative, and positive ions, and energy balanced equation for temperature distributions. The governing equations for each carrier, the continuity equations, belong to the hyperbolic-type PDE of which the solution has a step change at the space charge front resulting in numerical instabilities. To decrease these instabilities, the governing equations were solved simultaneously by the Finite Element Method (FEM) employing the artificial diffusion scheme as a stabilization technique. Additionally, the terminal current was calculated by using the generalized energy method which is based on the Poynting's theorem, and represents more reliable and stable approach for evaluating discharge current. To verify the proposed method, the discharge phenomena were successfully applied to the blade~plane electrodes, where the radius of blade cap was $50{\mu}m$.

A Study on NOx Emission Characteristics of An Industrial Gas Turbine (산업용 가스터빈의 NOx 배출 특성에 관한 연구)

  • Jeong, Jai-Mo;Park, Jung-Kyu
    • Journal of the Korean Society of Combustion
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    • v.9 no.1
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    • pp.11-17
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    • 2004
  • The purposes of this study are to analyze nitrogen oxides(NOx) formation mechanism and to reduce abnormal NOx emissions in gas turbines. Industrial gas turbines emissions have potential to negative affect to the atmosphere in many different ways such as photochemical smog, acid rain and global warming. In conventional gas turbine combustors, one of the main pollutants such as nitrogen oxide(NOx) species, are principally formed from combustion process of fuel with oxygen in the primary combustion zone, and their emission levels are highly depend on peak temperatures in the combustor. In order to examine the characteristics and the effect of NOx formation, we used gas turbine of which commercial operating in Korea. From the examination, it has been found that NOx emissions are relatively high at low load(output) and during combustion mode change. Also, the effect of Air/Fuel ratio was considered. As the Air/Fuel ratio was increased in Lean-Lean mode, the NOx emission was decreased. The results of this study indicated that NOx emission levels are highly depend on peak temperature and pressure of combustion process in the combustor.

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Econometric Estimation of the Climate Change Policy Effect in the U.S. Transportation Sector

  • Choi, Jaesung
    • Journal of Climate Change Research
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    • v.8 no.1
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    • pp.1-10
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    • 2017
  • Over the past centuries, industrialization in developed and developing countries has had a negative impact on global warming, releasing $CO_2$ emissions into the Earth's atmosphere. In recent years, the transportation sector, which emits one-third of total $CO_2$ emissions in the United States, has adapted by implementing a climate change action plan to reduce $CO_2$ emissions. Having an environmental policy might be an essential factor in mitigating the man-made global warming threats to protect public health and the coexistent needs of current and future generations; however, to my best knowledge, no research has been conducted in such a context with appropriate statistical validation process to evaluate the effects of climate change policy on $CO_2$ emission reduction in recent years in the U.S. transportation. The empirical findings using an entity fixed-effects model with valid statistical tests show the positive effects of climate change policy on $CO_2$ emission reduction in a state. With all the 49 states joining the climate change action plans, the U.S. transportation sector is expected to reduce its $CO_2$ emissions by 20.2 MMT per year, and for the next 10 years, the cumulated $CO_2$ emission reduction is projected to reach 202.3 MMT, which is almost equivalent to the $CO_2$ emissions from the transportation sector produced in 2012 by California, the largest $CO_2$ emission state in the nation.

Soil Emission Measurements of N2O, CH4 and CO2 from Intensively Managed Upland Cabbage Field (배추 밭에서의 N2O, CH4, CO2 토양배출량 측정 및 특성 연구: 주요온실가스 배출량 측정 및 지표생태변화에 따른 특성 연구)

  • Kim, Deug-Soo;Na, Un-Sung
    • Journal of Korean Society for Atmospheric Environment
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    • v.27 no.3
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    • pp.313-325
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    • 2011
  • From October 2009 to June 2010, major greenhouse gases (GHG: $N_2O$, $CH_4$, $CO_2$) soil emission were measured from upland cabbage field at Kunsan ($35^{\circ}$56'23"N, $126^{\circ}$43'14"E), Korea by using closed static chamber method. The measurements were conducted mostly from 10:00 to 18:00LST during field experiment days (total 28 days). After analyzing GHG concentrations inside of flux chamber by using a GC equipped with a methanizer (Varian CP3800), the GHG fluxes were calculated from a linear regression of the changes in the concentrations with time. Soil parameters (e.g. soil moisture, temperature, pH, organic C, soil N) were also measured at the sampling site. The average soil pH and soil moisture were ~pH $5.42{\pm}0.03$ and $70.0{\pm}1.8$ %WFPS (water filled pore space), respectively. The ranges of GHG flux during the experimental period were $0.08\sim8.40\;mg/m^2{\cdot}hr$ for $N_2O$, $-92.96\sim139.38mg/m^2{\cdot}hr$ for $CO_2$, and $-0.09\sim0.05mg/m^2{\cdot}hr$ for $CH_4$, respectively. It revealed that monthly means of $CO_2$ and $CH_4$ flux during October (fall) were positive and significantly higher than those (negative value) during January (winter) when subsoil have low temperature and relatively high moisture due to snow during the winter measurement period. Soil mean temperature and moisture during these months were $17.5{\pm}1.2^{\circ}C$, $45.7{\pm}8.2$%WFPS for October; and $1.4{\pm}1.3^{\circ}C$, $89.9{\pm}8.8$ %WFPS for January. It may indicate that soil temperature and moisture have significant role in determining whether the $CO_2$ and $CH_4$ emission or uptake take place. Low temperature and high moisture above a certain optimum level during winter could weaken microbial activity and the gas diffusion in soil matrix, and then make soil GHG emission to the atmosphere decrease. Other soil parameters were also discussed with respect to GHG emissions. Both positive and negative gas fluxes in $CH_4$ and $CO_2$ were observed during these measurements, but not for $N_2O$. It is likely that $CH_4$ and $CO_2$ gases emanated from soil surface or up taken by the soil depending on other factors such as background concentrations and physicochemical soil conditions.

Membrane-based Direct Air Capture Technologies (분리막을 이용한 공기 중 이산화탄소 제거 기술)

  • Yoo, Seung Yeon;Park, Ho Bum
    • Membrane Journal
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    • v.30 no.3
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    • pp.173-180
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    • 2020
  • As the demand for fossil fuels continues to increase worldwide, carbon dioxide (CO2) concentration in the air has increased over the centuries. The way to reduce CO2 emissions to the atmosphere, carbon capture and sequestration (CCS) technology have been developed that can be applied to power plants and factories, which are primary emission sources. According to the climate change mitigation policy, direct air capture (DAC) in air, referred to as "negative emission" technology, has a low CO2 concentration of 0.04%, so it is focused on adsorbent research, unlike conventional CCS technology. In the DAC field, chemical adsorbents using CO2 absorption, solid absorbents, amine-functionalized materials, and ion exchange resins have been studied. Since the absorbent-based technology requires a high-temperature heat treatment process according to the absorbent regeneration, the membrane-based CO2 capture system has a great potential Membrane-based system is also expected for indoor CO2 ventilation systems and immediate CO2 supply to smart farming systems. CO2 capture efficiency should be improved through efficient process design and material performance improvement.

Seasonal variations of CO2 concentration and flux in vegetation and non-vegetation environments on the Muan tidal flat of Hampyong Bay (함평만 무안 지역 갯벌의 식생 및 비식생 환경에서 이산화탄소 농도와 플럭스의 계절 변동)

  • So, Yoon Hwan;Kang, Dong-hwan;Kwon, Byung Hyuk;Kim, Park Sa
    • Journal of Wetlands Research
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    • v.21 no.4
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    • pp.257-266
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    • 2019
  • In this study, we selected 6 vegetation sites (reed community) and 6 non-vegetation sites (tidal flat) in the Muan tidal flat of Hampyeong Bay, and observed seasonal changes in carbon dioxide concentration, flux and soil temperature at low tide conditions. The study was conducted to identify the characteristics of seasonal changes in vegetation and non-vegetation areas through the data observed in May 30, August 8, 2012 and January 31, 2013. The average carbon dioxide concentration in the vegetation area was the highest in winter, followed by spring and summer, and the non-vegetation area showed the same concentration change as the vegetation area. The carbon dioxide flux in the vegetation area showed a positive (+) value in both spring and summer, but it was negative (-) in the winter. The average value of carbon dioxide flux was the highest in spring, but it was almost similar to summer, and winter was the lowest negative value. Non-vegetation areas showed positive emission in spring, and negative uptake in summer and winter; mean values were the highest in spring, and the difference between summer and winter was small. In summary of seasonal change characteristics of the research area, the emission of carbon dioxide was dominant in both areas in spring. In summer, carbon dioxide emission was dominant in the vegetation area, and the non-vegetation area was observed to uptake by photosynthesis of phytoplankton, but it was very small. In winter, changes in flux in both areas were very slight.

COMBUSTION STABILITY OF DIESEL-FUELED HCCI

  • Shi, L.;Deng, K.;Cui, Y.
    • International Journal of Automotive Technology
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    • v.8 no.4
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    • pp.395-402
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    • 2007
  • Homogeneous Charge Compression Ignition (HCCI) shows great potential for low $NO_x$ emission but is hampered by the problem of no direct method to control the combustion process. Therefore, HCCI combustion becomes unstable easily, especially at lower and higher engine load. This paper presents a method to achieve diesel-fueled HCCI combustion, which involves directly injecting diesel fuel into the cylinder before the piston arrives at top dead center in the exhaust stroke and adjusting the valve overlap duration to trap more high temperature residual gas in the cylinder. The combustion stability of diesel-fueled HCCI combustion and the effects of engine load, speed, and valve overlap on it are the main points of investigation. The results show that: diesel-fueled HCCI combustion has two-stage heat release rate (low temperature and high temperature heat release) and very low $NO_x$ emission, combustion stability of the HCCI engine is worse at lower load because of misfire and at higher load because of knock, the increase in engine speed aids combustion stability at lower load because the heat loss is reduced, and increasing negative valve overlap can increase in-cylinder temperature which aids combustion stability at lower load but harms it at higher load.

On the properties of six cores in the λ Orionis cloud: triggered or non-triggered star formation?

  • Yi, Hee-Weon;Lee, Jeong-Eun;Liu, Tie;Kim, Kee-Tae
    • The Bulletin of The Korean Astronomical Society
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    • v.45 no.1
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    • pp.58.4-59
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    • 2020
  • We present preliminary results of 1.1 and 1.3 mm dust continuum and 12CO (J=2-1) line data obtained with the Submillimeter Array toward six cores harboring Class 0/I objects in the λ Orionis cloud. They are located in bright rimmed clouds, which are exposed to the far-ultraviolet radiation field by the O-type star λ Ori. Compact dust continuum emission is observed from all six cores. Among the six cores, only one core G196.92-10.37 shows a signature of binarity with separation of 4000 AU. The numbers of singles and binaries in our sample are five and one, respectively and the derived multiplicity frequency (MF) is 0.17. This value is lower than those found in the binary surveys toward Class 0/I objects, which may be a hint for negative feedback by the nearby massive star, lambda Ori. The derived excitation temperature (Tex) using 12CO emission shows a lower median value (20 K) than those of triggered star-forming regions (30 K). The lower MF and Tex support our previous study that star formation was not triggered in the λ Orionis cloud. We aim to further investigate whether the Class 0/I YSOs in the λ Orionis cloud have less circumstellar materials and smaller accretion rates than in other filamentary clouds (e.g., Orion A & B), which might be attributed to negative feedback from the massive star in limiting accretion of protostars.

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Interaction between Norfolxacin and Single Stranded DNA

  • 여정아;조태섭;Kim, Seog K.;문형랑;준길자;남원우
    • Bulletin of the Korean Chemical Society
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    • v.19 no.4
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    • pp.449-457
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    • 1998
  • We compared various spectroscopic properties of a norfloxacin-single stranded DNA complex with those of norfloxacin-double stranded DNA complex. Norfloxacin binds to both double-and single stranded DNA, and we observed the following spectroscopic changes for both complexes: hypochromism in the norfloxacin absorption region in the absorption spectrum, the characteristic induced CD spectrum consisting of a weak positive band at 323 nm and a strong positive band at 280-300 nm followed by a negative band in the 260 nm region, a strong decrease in the fluorescence intensity and a red-shift in the fluorescence emission spectrum, and shorter fluorescence decay times. These results indicate that the environments of the bound norfloxacin in both DNAs are similar, although the equilibrium constant of the norfloxacin-single stranded DNA was twice as high as the norfloxacin-double stranded DNA complex. Both complexes were thermodynamically favored with similar negative Δ$G^o$. Negative Δ$H^o$ terms contribute to these spontaneous reactions; Δ$S^o$ term was unfavorable.

Ammonification and NH3 emission in the Soil Amended with Different Animal Manures

  • Wang, Xin-Lei;Zhang, Qian;Park, Sang-Hyun;Lee, Bok-Rye;Kim, Tae-Hwan
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.37 no.1
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    • pp.56-60
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    • 2017
  • Mineralization is an important biological process for conversion of organic nitrogen (N) to inorganic N which can be used by plants directly. To investigate the effect of different manures on soil mineralization, the soil amended with cattle (CtM), goat (GM), chicken manure (ChM) and pig slurry (PS) were incubated under in vitro condition and ammonium N ($NH_4{^+}-N$), ammonification rate and ammonia emission were determined for eighty-four days. $NH_4{^+}-N$ was the highest in PS-amended soil for the whole experimental period. $NH_4{^+}-N$ in PS-amended soil was gradually decreased until day 84, whereas it was rapidly decreased for the first 14 days and then slightly increased until 84 days in ChM-, CtM- and GM-amended soil. The ammonification rate showed negative value for the first 14 days in all treatments. From day 14, ammonification rate started to increase in CtM- and ChM-amended soil, whereas it was maintained in GM- and PS-amended soil until day 84. The daily ammonia emission was the highest in PS-amended soil ($41mg\;kg^{-1}d^{-1}$), followed by CtM-, ChM-, and GM-amended soil at day 1. It was gradually decreased until day 84 in all treatments. The total $NH_3$ emission was the highest in PS-amended soil with $0.6mg\;kg^{-1}$ for 84 days, while less than $0.1mg\;kg^{-1}$ in three other plots. These results indicate that different manures showed different soil ammonification rate and $NH_3$ emission.