• Title/Summary/Keyword: near-IR

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Comparison of Carotenoid Pigments on Korean Dark Sleeper, Odontobutis platycephala and Dark Sleeper, Odontobutis odontobutis interrupta in the Family Eleotridae (구굴무치과에 속하는 동사리와 얼룩동사리의 Carotenoid 색소성분의 비교)

  • 하봉석;김명선;백승한;김현영;김수영;정계임;권문정
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.27 no.5
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    • pp.813-820
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    • 1998
  • This study was performed as a part of comparative biochemical studies of carotenoid pigment for the fresh water fish. Carotenoids in integument of Korean dark sleeper, Odontobutis platycephala, and dark sleeper, Odontobutis odontobutis interrupta, which are all the Korean native fresh water fish, were separated by thin layer chromatography, column chromatography and HPLC. The separated carotenoid were then reduced and isomerized by NaBH4 and I2 respectively to investigate UV-Vis spectrophotometeric patterns and chracterized by IR, 1H-NMR and Mass spectrum. The content of total carotenoids in the integument of Korean dark sleeper was 3.01mg% in April, but it was increased to 3.74mg% in September at the near of spawning period. The carotenoid isolated in April consisted of $\beta$-carotene(25.6%), lutein(18.5%) and zeaxanthin(12.0%) as major carotenoids and also contained isocryptoxanthin, diatoxanthin, tunaxanthin, cynthiaxanthin, canthaxanthin and $\alpha$-cryptoxanthin as minor carotenoids. Similarly, in September the carotenoid consisted of $\beta$-carotene(16.5%), zeaxanthin(13.7%) and cynthiaxanthin(13.6%) as major carotenoids and also contained lutein, isocryptoxanthin, tunaxanthin, $\alpha$-cryptoxanthin, diatoxanthin and canthaxanthin as minor carotenoids. At the near of spawning period, the content of cynthiaxanthin and $\alpha$-cryptoxanthin were increased. The content of total carotenoids in the integument of spawning period. T도 carotenoid isolated in April and September consisted of $\beta$-carotene(24.9%, 27.5%), zeaxanthin(14.4%, 20.9%) and lutein(12.6%, 11.4%) as major carotenoids and also contained cynthiaxanthin, tunaxanthin, diatoxanthin, isocryptoxanthin, $\alpha$-cryp-toxanthin and canthaxanthin as minor carotenoids. At the near of spawning period, the content of zeaxanthin was increased, indicating that the carotenoid composition were dependent upon their living conditions and their integument colors. Both Korean dark sleeper and dark sleeper contained high amount of cynthiaxanthin and diatoxanthin which are found as rare carotenoids in the other of fresh water fish. It is interes that they also contained tunaxanthin which is a specific carotenoid in marine fishes.

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Infrared Spectroscopic Evidences for the Superconductivity of $La_2CuO_4$-related Compounds: A Superconductivity Probe

  • Park, Jeong Cheol;Jo, Seon Woog;Jeong, Jong Hak;Jeong, Gi Ho
    • Bulletin of the Korean Chemical Society
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    • v.21 no.10
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    • pp.1041-1043
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    • 2000
  • We present the effects of temperature (between 10 K and 298 K) and of hole concentration on the frequency and intensity of characteristic phonons in polycrystalline $La_2CuO_4-related$ compounds using FT-IR spectros-copy. The influences of the concentration of carrier doped on the phonon modes are prominent in the IR spectra of $La_2CuO_4-related$ compounds. For $La_2-xSrxCuO_4({\chi}=$ 0.00, 0.03, 0.07, 0.10, and 0.15) and electrochemically (or chemically) oxidized $La_2CuO_4$, the intensities of the transverse oxygen mode around 680cm $-^1$ which cor-responds mainly to Cu-O(1) stretching vibration in the basal plane of CuO6 octahedron, are decreased and dis-appeared depending on the Sr-substitution rate and the amount of excess oxygen, while the longitudinal oxygen mode around 510 cm $-^1$ corresponding to the Cu-O(2) stretching in the basal plane of CuO6 octahedron are near-ly invariable. In particular, after two cycles of cooling-heating between 10 K and 298 K for these sample, the phonons around 680 cm $-^1$ are blue shif 13-15 cm $-^1$, while the phonons around 510 cm $-^1$ are nearly constant. The introduction of the charge carrier by doping would give rise to the small contraction of CuO6 oc-tahedron as Cu $^3+$ requires a smaller site than Cu $^2+$, which results in the shortening of the Cu-O(1) bond length and Cu-O(2) bond length with the increased La-O(2) bond length. These results in the frequency shift of the characteristic phonons. The IR spectra of $La_2Li0.5Cu0.5O_4$ which exhibits an insulator behavior despite the $Cu^3+$ of nearly 100%, corroborate our IR interpretations. The mode around 710 cm $-^1$ corresponding to Cu-O(1) stretching vibration is still strongly remained even at low temperature (10 K). Thus, we conclude that the con-duction electrons formed within $CuO_2$ planes of $La_2CuO_4-related$ superconductors screen more effectively the transverse oxygen breathing mode around 680 $cm-^1$ depending on the concentration of the doped charge carrier in $La_2CuO_4-related$ compounds, which might use as a superconductivity probe.

Combustion Diagnostics Method Using Diode Laser Absorption Spectroscopy (다이오드 레이저를 이용한 연소진단기법)

  • Cha, Hak-Joo;Kim, Min-Soo;Shin, Myung-Chul;Kim, Se-Won;Kim, Hyuck-Joo;Han, Jae-Won
    • 한국연소학회:학술대회논문집
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    • 2003.05a
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    • pp.75-83
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    • 2003
  • Diode laser absorption system is advantageous of their non-invasive nature, fast response time, high sensitivity and real-time measurement capability. Furthermore, recent advances in room-temperature, near-IR and visible diode laser sources for telecommunication, optical data storage applications are enabling combustion diagnostics system based on diode laser absorption spectroscopy. So, combined with fiber-optics and high sensitive detection strategies, compact and portable sensor system are now appearing for a variety of applications. The objective of this research is to take advantage of distributed feed-back diode laser and develope new gas sensing system. It experimentally found out that the wavelength, power characteristics as a function of injection current and temperature. In addition to direct absorption and wavelength modulation spectroscopy have been demonstrated in these experiments and have a bright prospect to this diode laser system.

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Measurement of Exhaust Gas Concentration using Wavelength Modulation Spectroscopy (파장 변조 기법을 이용한 연소배기 가스의 계측)

  • Kim, Dong-Hyuck;Kim, Se-Won;Shin, Myung-Chul;Kim, Yong-Mo
    • 한국연소학회:학술대회논문집
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    • 2006.10a
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    • pp.97-103
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    • 2006
  • This work forcus on the development of gas sensor that measure the concentrations of exhaust gas using diode laser. Each diode laser for exhaust gas measurement is set to work at near-IR using both DA and WMS methods. Also use of fiber-coupled optical elements makes such a sensor rugged and easy to align. On-line data acquisition and processing can be performed with a PC running LabVIEW software, and absorption signals are measured simultaneously by multiplexing method. Finally, It were experimentally compared WMS (Wavelength Modulation Spectroscopy) with DA (Direct Absorption) for the accuracy.

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The Synthesis of Aluminum Alkoxides (알루미늄 알콕사이드의 합성)

  • 정재식;박원규
    • Journal of the Korean Ceramic Society
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    • v.35 no.9
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    • pp.953-957
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    • 1998
  • The effects of catalysts and reactive conditions on the synthesis of aluminum alkoxides are investigated. HgCl2 and I2 as catalysts are used in the synthesis reaction for comparing to no addtion. The absorption peak in IR spectra according to Al-O-L bond of aluminum isopropoxide and aluminum sec-butoxide appear at near 1030cm-1 and 1060cm-1 respectively regardless of kinds of catalysts. The synthesis yield of alu-minum-isopropoxide was 90% in case of no catalyst addition and increased to all of 95% by addition of HgCl2 and I2 The synthesis yield of aluminum sec-butoxide is increased to 95% by addition of I2 catalyst com-paring to no addition.

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AUTOMATIC DETECTION Of NARROW OPEN WATER STREAMS IN AMAZON FORESTS FROM JERS-1 SAR IMAGERY

  • Amano, Takako-Sakurai;Iisaka, Joji;Kamiyama, Masataka;Takagi, Mikio
    • Proceedings of the KSRS Conference
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    • 1999.11a
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    • pp.310-315
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    • 1999
  • We extracted narrow open water streams from JERS-1 SAR images of the Amazon rain forest. The extracted range of these streams were almost comparable to a high level extraction of the same streams from near-IR images of JERS-1 VNIR data notwithstanding that these features in SAR images show the strong dependence of the observation angle. Large water bodies are relatively easy to extract from JERS-1 SAR images, as they tend to appear as very dark areas; but streams whose width is nearly equal to or less than the spatial resolution no longer appear as very dark features. By using strong scatterers distributed sparsely along the radar facing sides of the streams, we can successfully estimate approximate ranges of waterways and then extract relatively dark line-like features within these ranges.

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A CATALOG OF 120 NGC OPEN STAR CLUSTERS

  • Tadross, A.L.
    • Journal of The Korean Astronomical Society
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    • v.44 no.1
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    • pp.1-11
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    • 2011
  • A sample of 145 JHK-2MASS observations of NGC open star clusters is studied, of which 132 have never been studied before. Twelve are classified as non-open clusters and 13 are re-estimated self-consistently, after applying the same methods in order to compare and calibrate our reduction procedures. The fundamental and structural parameters of the 120 new open clusters studied here are derived using color-magnitude diagrams of JHK Near-IR photometry with the fitting of solar metallicity isochrones. We provide here, for the first time, a catalog of the main parameters for these 120 open clusters, namely, diameter, distance, reddening and age.

Half-hourly Rainfall Monitoring over the Indochina Area from MTSAT Infrared Measurements: Development of Rain Estimation Algorithm using an Artificial Neural Network

  • Thu, Nguyen Vinh;Sohn, Byung-Ju
    • Journal of the Korean earth science society
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    • v.31 no.5
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    • pp.465-474
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    • 2010
  • Real-time rainfall monitoring is of great practical importance over the highly populated Indochina area, which is prone to natural disasters, in particular in association with rainfall. With the goal of d etermining near real-time half-hourlyrain estimates from satellite, the three-layer, artificial neural networks (ANN) approach was used to train the brightness temperatures at 6.7, 11, and $12-{\mu}m$ channels of the Japanese geostationary satellite MTSAT against passive microwavebased rain rates from Tropical Rainfall Measuring Mission (TRMM) Microwave Imager (TMI) and TRMM Precipitation Radar (PR) data for the June-September 2005 period. The developed model was applied to the MTSAT data for the June-September 2006 period. The results demonstrate that the developed algorithm is comparable to the PERSIANN (Precipitation Estimation from Remotely Sensed Information using Artificial Neural Networks) results and can be used for flood monitoring across the Indochina area on a half-hourly time scale.

Diode-Laser Absorption Sensors for measurement of combustion Gas (연소배기 가스의 계측을 위한 다이오드 레이저 센서)

  • Shin, Myung-Chul;Kim, Se-Won;Kim, Dong-Hyuck
    • Journal of the Korean Society of Combustion
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    • v.11 no.3
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    • pp.26-35
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    • 2006
  • This work forcus on the development of gas sensor that measure the concentrations of exhaust gas using diode laser, Each diode laser for exhaust gas measurement is set to work at near-IR using both DA and WMS methods. Also use of fiber-coupled optical elements makes such a sensor rugged and easy to align. The results showed that gas concentrations of $O_2$, CO, $CO_2$, NO are accurately measured within ${\pm}2%$ error. The application of WMS method increased the beam intensity 2-3 times higher than DA method. It were experimentally compared WMS (Wavelength Modulation Spectroscopy) with DA (Direct Absorption) for the accuracy.

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