• 한국근적외분광분석학회:학술대회논문집
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• 한국근적외분광분석학회 2001년도 NIR-2001
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• pp.1274-1274
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• 2001

An anharmonicity is a fundamental quantity shaping the potential for stretching OH vibration in phenol and its derivatives. The phenomenon is examined both by experimental and theoretical methods. FT-IR and NIR spectra of series of phenols derivatives were measured in the range of fundamental and first two Overtones of $_{s}(OH)$ Vibrations in $CCl_4$ solutions. The electronic influence of substituents on the analyzed frequencies is discussed and correlated with $pK_{a}$ parameters. Ab initio MP2/6-31G(d,p) and B3LYP/6-31G(g,p) calculations of the potential for proton movement in OH group were performed. Equilibrium structures were also determined. The frequencies of fundamental and overtones were calculated by Numerov-type procedure. The results of calculations are compared with the experimental data. The best linear correlations were obtained for the results of MP2/6-31G(d,p) calculations. It was shown that some structural parameters are especially sensitive on substitution. The linear correlations were found between those parameters and spectroscopic data. The results of calculation are compared with available crystallographic data.

• 천문학회보
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• 제42권2호
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• pp.42.2-42.2
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• 2017

The Large Magellanic Cloud (LMC) is a unique target to study the detail structures of molecular clouds and star-forming regions, due to its proximity and face-on orientation from us. Most part of the astrophysical subjects for the LMC have been investigated, but the magnetic field is still veiling despite its role in the evolution of the interstellar medium (ISM) and in the main force to influence the star formation process. Measuring polarization of the background stars behind interstellar medium allows us to describe the existence of magnetic fields through the polarization vector map. In this presentation, I introduce the near-infrared polarimetric results for the $39^{\prime}{\times}69^{\prime}$ field of the northeastern region of the LMC and the N159/N160 star-forming complex therein. The polarimetric observations were conducted at IRSF/SIRPOL 1.4 m telescope. These results allow us to examine both the global geometry of the large-scale magnetic field in the northeastern region and the close structure of the magnetic field in the complex. Prominent patterns of polarization vectors mainly follow dust emission features in the mid-infrared bands, which imply that the large-scale magnetic fields are highly involved in the structure of the dust cloud in the LMC. In addition, local magnetic field structures in the N159/N160 star-forming complex are investigated with the comparison between polarization vectors and molecular cloud emissions, suggesting that the magnetic fields are resulted from the sequential formation history of this complex. I propose that ionizing radiation from massive stellar clusters and the expanding bubble of the ionized gas and dust in this complex probably affect the nascent magnetic field structure.

• 약학회지
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• 제34권5호
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• pp.302-310
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• 1990

A study has been made of the Korean bentonite aqueous suspension contrast with American bentonite by means of XRD IR swelling, gel formation and rheogram at various conditions such as concentration, temperature and pH. The Korean bentonite was identified as montmorillonite clay containig a small proprotion of crystoballite and mordenite, and its swelling power were acceptable for requirements of Korean pharmacopeia regulations though its values were not satisfied. Korean bentonite swelled to 10 times and American one did to 15 times compared to its bulkiness of powder. The rheogram of Korean bentonite suspension reveals bulged pseudoplatic flow with yield value at higher concentration and pseudoplastic flow without yield value at lower concentration. The higher the concentration, the greater were the apparent viscosity and hysteresis loop. Korean bentonite suspension showed insignificant temperature dependence on both apparent viscosity and hysteresis loop and it was more temperature dependent on viscosity but less on hysteresis loop than those of American sample. The pH dependence was so high on viscosity that apparent minimum value was near pH 7 and maximum value at pH 3 or 7. The hysteresis loop appeared minimum over the pH range 5-7 and maximum near pH 3 or 11. The Korean bentonite was inferior to the American bentonite in swelling volume, gel formation, thioxotropy, however, it would be possible to improve the quality of Korean bentonite by developing the method of purification for bentonite clay.

• 천문학회지
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• 제44권4호
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• pp.135-142
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• 2011

A $200'{\times}200'$ region around 30 Doradus in the Large Magellanic Cloud (LMC) is observed and analyzed in the near-infrared. We obtain polarimetry data in the J, H, and Ks bands using the SIRIUS polarimeter SIRPOL at the Infrared Survey Facility 1.4 m telescope. We measure the Stokes parameters of 2562 point-like sources to derive the degree of polarization and the polarization position angles. We discuss the statistics of the groups classified by color-magnitude diagram and proper motions of the sources, in order to separate the Galactic foreground sources from those present in the LMC. We notice that groups classified by the proper motion data show a tendency towards different polarimetric properties.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2000년도 하계학술대회 논문집 C
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• pp.1608-1610
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• 2000

In this work, the effect of annealing on physical and electrical properties of XLPE cable insulation was investigated. One sample was non-annealed and the other two samples were treated under air circulated oven at 80$^{\circ}C$ for five and ten days. In the DSC patterns of annealed specimen, new peaks appeared at near 80$^{\circ}C$ as a proof of thermal history. The degree of crystallinity increased by annealing effect. In the FT-IR spectrums, the change of absorbances to acetophenone and cumyl alcohol were observated according to the radial direction of cable insulation. They slowly diffused into both semi-conductive layer of the cable in proportion to annealing time and lastly led to near equilibrium state through cable insulation. The AC breakdown strength did not increased but the values were stabilized by effects of crystallinity and diffusion of by-products.

• 제어로봇시스템학회논문지
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• 제17권5호
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• pp.471-478
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• 2011

This UGV (Unmanned Ground Vehicle) is not only widely used in various practical applications but is also currently being researched in many disciplines. In particular, obstacle avoidance is considered one of the most important technologies in the navigation of an unmanned vehicle. In this paper, we introduce a simple algorithm for path planning in order to reach a destination while avoiding a polygonal-shaped static obstacle. To effectively avoid such an obstacle, a path planned near the obstacle is much shorter than a path planned far from the obstacle, on the condition that both paths guarantee that the robot will not collide with the obstacle. So, to generate a path near the obstacle, we have developed an algorithm that combines an edge detection method and a limit-cycle navigation method. The edge detection method, based on Hough Transform and IR sensors, finds an obstacle's edge, and the limit-cycle navigation method generates a path that is smooth enough to reach a detected obstacle's edge. And we proposed novel algorithm to solve local minima using the virtual wall in the local vision. Finally, we verify performances of the proposed algorithm through simulations and experiments.

• 대한원격탐사학회지
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• 제22권3호
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• pp.175-182
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• 2006

Because of the phenological variation of vegetation growth in temperate region, it is often difficult to accurately assess the surface conditions of agricultural croplands, grasslands, and disturbed forests by multi-spectral remote sensor data. In particular, the spectral similarity between soil and dry vegetation has been a primary problem to correctly appraise the surface conditions during the non-growing seasons in temperature region. This study analyzes the spectral characteristics of the mixture of dry vegetation and soil. The reflectance spectra were obtained from laboratory spectroradiometer measurement (GER-2600) and from EO-1 Hyperion image data. The reflectance spectra of several samples having different level of dry vegetation fractions show similar pattern from both lab measurement and hyperspectral image. Red-edge near 700nm and shortwave IR near 2,200nm are more sensitive to the fraction of dry vegetation. The use of hyperspectral data would allow us for better separation between bare soils and other surfaces covered by dry vegetation during the leaf-off season.

• 한국지구과학회지
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• 제30권6호
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• pp.744-758
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• 2009

본 연구에서는 2006-2008년 여름(6-8월)에 발생한 12개 낙뢰 사례에 대하여 기상청의 낙뢰관측 자료와 MTSAT-1R 위성의 적외(IR1) 및 수증기(WV) 채널 휘도온도를 이용하여 낙뢰 발생 시 위성영상 특성을 분석하였다. 낙뢰가 발생하지 않은 경우 IR1 채널의 휘도온도는 290-295K, WV 채널의 휘도온도는 245K 부근에서 최대 분포를 보인다. 그러나 낙뢰가 발생하는 경우, 강한 대류의 영향으로 두 채널 모두에서 휘도온도가 215K 이하로 낮아졌으며, 두 채널의 휘도온도차는 약 -50K에서 0K로 급격히 증가하였다. 뇌우 시스템의 발달 단계에 따라 차이는 있지만 원형 또는 타원형의 중규모 대류복합체에서는 그 대류 중심에서 많은 낙뢰가 발생하고, 스콜선 형 뇌우에서는 낙뢰가 선상으로 발생하는 특징을 보이고 있다. 낙뢰 발생빈도와 휘도온도는 중규모 대류계에서는 휘도온도에 관계없이 비교적 높은 상관성을 보이나 스콜선 형에서는 휘도온도가 낮을 때만 높은 상관성을 보인다. 또한 낙뢰는 두 채널의 휘도온도가 215K 이하, 휘도온도 차가 -3-1K 이고, IR1 채널의 국지표준편차가 급격히 증가하다가 감소하는 지역에서 많이 발생하는 특징을 보였다. 그러나 위 조건은 선상으로 발생하는 낙뢰의 경우 탐지 정확도가 비교적 높지만, 중규모 대류복합체가 소멸단계에 이르러 모루운이 광범위하게 확장된 경우에는 탐지 정확도가 낮다. 따라서 휘도온도의 특성을 이용하여 낙뢰를 탐지하기 위해서는 보다 많은 사례와 다른 채널의 자료를 이용하여 낙뢰 발생시의 위성영상 특성을 정교화하여야 할 것이다.

• Journal of the Optical Society of Korea
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• 제12권1호
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• pp.1-6
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• 2008

We report the simple detection method of the small hydrocarbons, methane and ethane, by continuous-wave cavity ring-down spectroscopy near 1.67 ${\mu}m$ using an external cavity diode laser. The absorption lines of methane between 6002.48 $cm^{-1}$ and 6003.37 $cm^{-1}$ and ethane between 5955.65 $cm^{-1}$ and 5956.4 $cm^{-1}$ have been resolved and employed for the gas detection. The largest absorption cross sections were found to be 6.5$\times10^{-20}cm^2$ and 7.4$\times10^{-21}cm^2$ for methane and ethane, respectively, in each spectral range. The minimum detectable absorption limit of our spectrometer was 4.8${\times}10^{-9}cm^{-1}$/$\sqrt{Hz}$, which corresponds to the detection limits of 3 ppb/$\sqrt{Hz}$ and 27 ppb/$\sqrt{Hz}$ for methane and ethane, respectively. The near-IR continuous-wave cavity ring-down spectroscopic detection method of the small hydrocarbons can be applied for medical diagnosis and environmental monitoring as a fast and convenient method.

• 천문학회보
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• 제41권1호
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• pp.31.4-32
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• 2016

Observing the solar atmosphere with ground-based telescopes in the near-infrared has a number of advantages when compared to classical measurements in visible wavelengths. One of them comes from the magnetic sensitivity of spectral lines, which varies as ${\lambda}_g$, where g is the effective $Land{\acute{e}}$ factor of the transition. This wavelength dependence makes the near-infrared range adequate to study subtle spatial or temporal variations of the magnetic field. Spectral lines, such as the photospheric Fe I $1.5648{\mu}m$ spectral line, with a $Land{\acute{e}}$ factor g=3, have often been used in the past for this type of studies. To study the chromosphere, the Ca II IR triplet and the He I $1.0830{\mu}m$ triplet are the most often observed lines. The latter has the additional advantage that the photospheric Si I $1.0827{\mu}m$ is close enough so that photosphere and chromosphere can be simultaneously recorded with a single detector in a spectrograph. The instrument TIP (Tenerife Infrared Polarimeter) has been continuously operating since 1999 at the 70-cm German VTT of the Observatorio del Teide and has been recently moved to the 1.5-m German GREGOR. During all this time, results have been obtained concerning the nature of the weak photospheric magnetic field of the quiet sun, magneto-acoustic wave propagation, evolution with the cycle of sunspot magnetic fields, photospheric and chromospheric magnetic field in emerging regions, magnetic field in chromospheric structures such as filaments, prominences, flares, and spicules, etc. In this talk, I will review the main results obtained after all these observations and mention the main challenges for the future. With its novel polarization-free design and a complete suite of instruments aimed at simultaneous (imaging and spectroscopic) observations of the solar photosphere and chromosphere, the EST (European Solar Telescope) will represent a major world-wide infrastructure to understand the physical nature of all these phenomena.