• Title/Summary/Keyword: natural resonance

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Synthesis of a small molecular cage consisting of three aminomethyl pyrroles and its selective fluoride recognition

  • Nam Jung, Heo;Hye Jin, Han;Jaewon, Choi;Sung Kuk, Kim
    • Journal of the Korean Magnetic Resonance Society
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    • v.26 no.4
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    • pp.40-45
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    • 2022
  • A small cage-like molecule (2) composed of three aminomethyl pyrroles and two hexa-substituted benzenes has been prepared by reduction of its iminopyrrole analogue (1) using NaBH4. It was revealed by 1H NMR spectroscopic analyses that cage molecule 2 strongly binds the fluoride anion in polar DMSO-d6 relative to CDCl3. Compared to that of compound 1, the lowered affinity of 2 for the fluoride anion is attributable to its increased electron density resulting from the production of thesecondary amine groups.

Platelet-Activating Factor Antagonistic Activity and ^13C NMR Assignment of Pregomisin and Chamigrenal from Schisandra chinensis

  • Lee, Im-Seon;Jung, Keun-Young;Oh, Sei-Ryang;Kim, Dong-Seon;Kim, Jung-Hee;Lee, Jung-Joon;Lee, Hyeong-Kyu;Lee, Seung-Ho;Kim, Eun-Hee;Cheong, Chae-Joon
    • Archives of Pharmacal Research
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    • v.20 no.6
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    • pp.633-636
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    • 1997
  • In the course of searching for PAF receptor antagonists, pregomisin (1) and chamigrenal (2) were isolated from the fruits of Schizandra chinensis Baill by the bioactivity-guided isolation. Both compounds showed PAF antagonistic activity and the $IC_{50}$ values were $4.8{\times}10^{-5} M and 1.2{\times}10^{-4}M,$ respectively. In addition, the $^{13}C$ NMR assignments of 1 and 2 using DEPT, HMQC, COLOC and HMBC were reported for the first time.

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Study on the frequency analysis of the leaf spring (겹판스프링의 진동수해석에 관한 연구)

  • Cho, Jae-Ung;Han, Moon-Sik
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.9 no.6
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    • pp.36-42
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    • 2010
  • In this study, the deformation and stress are analyzed through modal and harmonic response analysis at resonance on leaf spring. The displacement range of 7 to 14 mm is shown at natural frequencies as 6 kinds of resonance modes. The maximum deformation is shown as 8.8781mm at Mode 2. The maximum displacement and stress at leaf spring are shown as 0.0458 mm and 72.533 MPa respectively on 1200 Hz. The comfortability of passenger becomes better on leaf spring at suspension system by use of this design model.

Determination of Alpha Defect Center in the Nature Using EPR Spectroscopy

  • Cho, Young-Hwan;Hyun, Sung-Pil;Pilsoo Hahn
    • Journal of the Korean Magnetic Resonance Society
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    • v.5 no.1
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    • pp.13-18
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    • 2001
  • Natural alpha radiation produced a stable defect center to certain minerals. Electron Paramagnetic Resonance(EPR) spectroscopy is a powerful tool f3r quantifying this defect center. EPR method has been applied to trace alpha-radiation effect around the uranium ore deposit. The results show that EPR technique can be used to measure rapidly and nondestructively the defect center produced by natural alpha radiation. In general, a good correlation was achieved between defect center concentration and actinide elements(U, Th). These results imply that the concentration of defect center is dependent on the alpha radiation dose over long time scale.

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Design and Structural Analysis of Crusher for Useless Wood (폐목재 파쇄기에 대한 설계 및 구조해석)

  • Lee, Jong-Sun;Cho, Dong-Hyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.6 no.2
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    • pp.210-214
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    • 2005
  • The objective of this study is design and structural analysis of crusher for useless wood. Structural analysis and modal analysis were effected in ANSYS and the structural safety was examined in search of displacement, stress, strain. There are avoid to resonance phenomenon by motor control.

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Experiments on Temperature Effect on Air Cavity Resonance and Tire's Vibration Characteristics of a Radial Tire (온도 변화가 승용차용 레이디얼 타이어의 공기공동 공명 및 타이어의 진동특성에 미치는 영향에 관한 실험)

  • Kim, Yong-Woo
    • Transactions of the Korean Society of Automotive Engineers
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    • v.16 no.3
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    • pp.102-110
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    • 2008
  • It is well known that the acoustic cavity inside the tire-wheel assembly contributes to vehicle interior noise and ride comfort. In this paper, we performed acoustic and structural modal testings by varying the temperature ranging from $20^{\circ}\;to\;45^{\circ}C$ to investigate the effects of temperature on acoustic cavity resonance and structural vibration characteristics for unloaded and loaded tires. The testing has given us some findings, which are reported in this paper.

Principles and application of SNIF-NMR

  • Kwon, Hyeok;Son, Woo Sung
    • Journal of the Korean Magnetic Resonance Society
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    • v.23 no.4
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    • pp.98-103
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    • 2019
  • SNIF-NMR is one of the analytical methods used to discriminate impurities in food and natural products. To determine the origin of compounds, SNIF-NMR utilizes frequency of deuterium in site specific fractionated sample using nuclear magnetic resonance. Also, SNIF-NMR is currently used to evaluate the authenticity of various foods such as wine, vanillin and oil, and is known to provide more accurate information than other analytical methods. In this review, the basic principles and practical examples of SNIF-NMR is presented.

Modification and Testing to Prevent the Resonance in a Finger-type Low Pressure Turbine Blade (저압 터빈용 Finger 형 블레이드의 공진 방지를 위한 개선 및 시험)

  • Ha, Hyun-Cheon;Lee, Dong-Jin;Ryu, Seok-Ju;Chung, Hee-Chan
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2000.11a
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    • pp.612-617
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    • 2000
  • This paper describes the experience gained from the treatments for prevention of blade failure occurred in the low-pressure turbine. Some cracks due to high cycle fatigue were found at the blades in low-pressure turbines after long time operation. Such failure was mainly caused by the resonance of the blade with the vane passing frequency excitation. If a natural frequency of the blade exists near the excitation frequency, a resonant vibration can occur and leads to a large amount of stress which may cause fatigue failures in turbine blades. To avoid the resonance of the blade, some modifications have been performed and full-scaled mockup testing has been done to confirm the verification for modification. Test result shows that enlarging the span cover is very useful to change the natural frequency of the grouped blades effectively.

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Design and Structural Analysis of 2nd Crusher for Useless Wood (폐목재 2차 파쇄기에 대한 설계 및 구조해석)

  • Lee Jong-Sun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.6 no.4
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    • pp.355-360
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    • 2005
  • The objective of this study is design and structural analysis of 2nd crusher for useless wood. Structural analysis and modal analysis were effected in ANSYS and the structural safety was examined in search of displacement, stress, strain. There are avoid to resonance phenomenon by motor control.

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Vibration control of the vibration isolation system using the electromagnetic actuator (전자석 액츄에이터에 의한 수동방진 테이블의 제어)

  • Choi, Hyun;Lee, Jung-Youn
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 2003.10a
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    • pp.227-232
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    • 2003
  • As the most precision equipment requiring very strict vibration environment are vulnerable to the surrounding vibration condition, they adapt the passive or active vibration isolation system. When it comes to the passive isolation system, the resonance of the isolation system causes excessive resonance response, and finally results in the degrade the equipment performance. This paper deals with the active control method to control this resonance induced response, and includes the experiment on the active control for controlling the resonance response on the table against the excitation of the same frequency with the natural frequency of the isolation system. The electromagnetic actuator was designed and the control effect was verified by the experiment. The experiment showed that the electromagnetic actuator is effective for controlling the low frequency isolation resonance response of the precision equipment.

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