• Title/Summary/Keyword: natural reaction

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Ailanthoidol Derivatives and their Anti-inflammatory Effects

  • Lee, Na-Li;Lee, Jae-Jun;Kim, Jin-Kyung;Jun, Jong-Gab
    • Bulletin of the Korean Chemical Society
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    • v.33 no.6
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    • pp.1907-1912
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    • 2012
  • Ailanthoidol showed a strong $anti$-inflammatory effect in a previous result. Ailanthoidol derivatives were prepared for the $anti$-inflammatory test using Sonogashira coupling, iodine induced cyclization and Wittig reaction. $Anti$-inflammatory effects of the prepared ailanthoidol derivatives were examined in lipopolysaccharide (LPS)-stimulated RAW 264-7 macrophages. The results showed that some ailanthoidol derivatives inhibited significantly the production of inflammatory mediator nitric oxide.

Analysis of Emotional Responses to Different Graphical Styles of Natural Scenery in Video Games (게임에서의 자연풍경의 그래픽 스타일 차이에 따른 감성 반응 분석)

  • Hansun Hong;Seongsu Kim;Minji Kang;Juyoung Lee
    • Journal of Environmental Science International
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    • v.32 no.12
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    • pp.979-985
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    • 2023
  • After the outbreak of COVID-19, the demand for home-enjoyable video games has surged, driven by extended pandemic conditions and resulting in rapid graphic technology advancements. Consequently, games with diverse expression techniques have emerged, captivating players. Virtual Reality (VR) environments predominantly feature natural landscapes, with advancing graphic technology enabling lifelike scenes. The rise in individuals seeking solace through natural elements in games has followed suit. As VR technology and metaverse interest grow, more people are exposed to digital imagery. However, evidence on the influence of graphic expression methods on emotional response to that is lacking. Our study examined user emotional responses, focusing on natural landscapes in digital graphics of games. Analyzing a group of 47 young adults as frequent digital media consumers, we studied reactions to different image styles (Realism, Semi-Realism, Stylized). In the analysis, Realism-style images were perceived the most positively, while emotional responses to natural landscapes with different graphical expressions showed no significant differences. Results suggest that recognizing digital natural landscapes may outweigh expression style impacting the evaluation of digital nature. This study's empirical analysis enhances the understanding of digital nature's application to actual situations.

Performance Evaluation of RWA Vibration Isolator Using Notch Filter Control (노치 필터 제어기법을 이용한 반작용 휠 미소진동 절연장치의 절연성능 평가)

  • Park, Geeyong;Suh, Jong-Eun;Lee, Dae-Oen;Han, Jae-Hung
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.26 no.4
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    • pp.391-397
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    • 2016
  • Vibration disturbances induced by the reaction wheels can severely degrade the performance of high precision payloads on board satellites with high pointing stability requirements. The unwanted disturbances produced by the reaction wheels are composed of fundamental harmonic disturbances due to the flywheel imbalance and sub/higher harmonic disturbances due to bearing irregularities, motor imperfections and so on. Because the wheel speed is constantly changed during the operation of a reaction wheel, the vibration disturbance induced by the reaction wheels can magnify the satellite vibration when the rotating frequency of wheel meets the natural frequency of satellite structure. In order to provide an effective isolation of the reaction wheel disturbances, isolation performance of a hybrid vibration isolator is investigated. In this paper, hybrid vibration isolator that combines passive and active components is developed and its hybrid isolation performance using notch filter control is evaluated in single-axis. The hybrid isolation performance using notch filter control show additional performance improvement compared to the results using only passive components.

Charge/discharge Capacity of Natural Graphite Anode According to the Charge/discharge Rate in Lithium Secondary Batteries (리튬 이차전지의 음극재료인 천연흑연의 충방전 속도에 따른 충방전 용량)

  • Ryu Ji Heon;Oh Eun Young;Oh Seung M.
    • Journal of the Korean Electrochemical Society
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    • v.7 no.1
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    • pp.32-37
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    • 2004
  • The charge/discharge capacity of natural graphite anode in lithium secondary batteries was examined as a function of charge/discharge rate. When the natural graphite anode was galvanostatically cycled in the range of 0.0-2.0V $(vs.\;Li/Li^+)$, the charging capacity decreased with an increase in the charging rate, which is caused by an earlier approach to the charging cut-off (0.0 V) before the complete charging that is in turn caused by an ever-increasing overpotential at higher rates. Even if the overpotential of discharging reaction also increased at higher discharge rates, the discharging reaction took place in the range of 0.0-0.3 V that is far below the discharge cut-off (2.0 V). As a result, the discharge capacity was not affected by the discharge rate because all the lithium ions once intercalated are fully discharged even at high current condition. As the overpotential of lithium deposition reaction also increased at high current condition, the charge capacity of natural graphite could be enlarged by lowering the charging cut-off voltage below 0.0 V, There is, however, a limitation for the lowering of cut-off voltage because the resistance for lithium deposition is smaller than that of lithium intercalation into graphite. When the charge cut-off voltage was lowered down to -0.04 V under IC condition, lithium ions were inserted into graphite without lithium deposition such that the discharge capacity could be raised up to $11\%$.

The Study on the CEC Increase and Granulation of Natural Zeolite -The Effect of NaOH Concentration and Na2O/Al2O3 Ratio (천연(天然) Zeolite의 CEC 증가(增加)와 입단화(粒團化)에 관(關)한 연구(硏究) -1. NaOH농도(濃度)와 조반비(曺礬比)(Na2O/Al2O3)의 영향(影響))

  • Choi, Jyung;Hur, Nam-Ho
    • Korean Journal of Soil Science and Fertilizer
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    • v.26 no.2
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    • pp.67-71
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    • 1993
  • This study was carried out to develop the soil conditioner and/or the absorbent of high CEC with the natural zeolite poeder whose price was very low. The $SiO_2/Al_2O_3$ ratio & CEC of the natural zeolite were 6.78 and 67.5me/100g respectively. The CEC of the post-reaction product which was treated with 3N-NaOH and $Na_2O/Al_2O_3$ ratio. 9.5 for 8hours was about 200me/100g, which was the highest value than any other treatments. The dominant clay minerals were clinoptilolite, mordenite and smectite in natural zeolite, while phillipsite in the post-reaction product.

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Study of Kinetics for Removal H2S by Natural Manganese ore Sorbent (황화수소 제거를 위한 천연망간광석 탈황제의 반응 속도 연구)

  • Yoon, Yeo Il;Kim, Myung Wook;Kim, Sung Hyun
    • Clean Technology
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    • v.7 no.3
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    • pp.187-194
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    • 2001
  • The desulfurization process which belongs to the gas refining part is the unit process that eliminates $H_2S$ and COS in the coal gas formed by the coal gasification part in the integrated gasification combined cycle(IGCC). In this study, natural manganese ores were selected as the raw material of the desulfurization sorbent due to economical efficiency. Initial rates for the reactions between $H_2S$ and desulfurization sorbent using natural manganese ores were determined in a temperature range of $400{\sim}800^{\circ}C$ using a thermobalance reactor. All reactions were first order with respect to $H_2S$ and were in accord with the Arrhenius equations. When sulfidation reaction was controlled by diffusion, the temperature dependence of the effective diffusivity was given by the Arrhenius equation. Activation energies and frequency factors were obtained from the product layer diffusion coefficient of various sorbents by plotting as Arrhenius equation form.

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Homogeneous Preparation of Barium Titanate by Dimethyl Oxalate in Ethanol Solution (에탄올 용액에서 Dimethyl Oxalate에 의한 티탄산바륨의 균일한 제조)

  • Ryu, Kyoung-Youl;Lim, Myoung-Hee;Huh, Woo-Young;Lee, Chul
    • Analytical Science and Technology
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    • v.12 no.5
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    • pp.382-386
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    • 1999
  • Spherical particles of barium titanyl oxalate(BTO) were homogeneously precipitated by thermal decomposition of dimethyl oxalate in hydrochloric mixture solutions of water and ethanol. The experimental parameters such as composition of the mixture solvents. the eoncentration of hydrochloric acid and reaction temperature had the paramount effect on the size of panicles collected from the bottom of the reaction vessel at the aging time of 120 min and the composition of BTO. Stoichiometric BTO powders were obtained under certain conditions as relatively low alcohol content in the mixtures, high chloride concentration and high temperature, Monosized, submicrometer, but titanium excess particles were obtained under certain reverse conditions.

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A Study on Gemmological Characters and Identificational Methods of Coral (산호의 보석학적 특성 및 감별 방법)

  • Kim, Kyung-Jin
    • The Journal of the Korea Contents Association
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    • v.5 no.6
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    • pp.146-151
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    • 2005
  • The coral is precious and organic gemstone. It is Beautifully Red color. Coral jewelry have been used for a long time in Asia. Especially in Korea, The Coral is an traditional and popular gemstone. It is significant to get the base data for the purpose of distinguishing natural coral from imitation coral by comparing about gemmological character in this study. Color, luster, transparency, streak color, refractive index, hardness, chemical reaction, ultraviolet fluorescence, specific gravity, observation of microscope and XRD analysis were conducted for identification of natural and imitation coral. As a result, natural coral has usually $CaCO_3$ composition and calcite structure. But, it is known that imitation coral impregnate calcic and dyeing materials with pigment. And they were distinguished also from not only XRD analysis but also a few simple experiments like specific gravity, refractive index and chemical reaction. Natural coral is harder and luster then imitation coral. In breaking method, the streak color is used certification.

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Sex Identification of the First Incubated Chicks of the Crested Ibis Nipponia nippon in Korea (한국 최초 인공번식에 성공한 따오기의 성별구별)

  • Kim, Kyung-A;Cha, Jae-Seok;Kim, Tae-Jwa;Kim, Kyung-Min;Park, Hee-Cheon
    • Journal of Life Science
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    • v.21 no.5
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    • pp.626-630
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    • 2011
  • In October 2008, a pair of Crested ibis Nipponia nippon, an endangered avian species in the world, was donated to Korea from China. They have since been the subject of a successful program to incubate chicks for the first time in South Korea. This study was carried out to determine the sex of chicks from the Crested ibis through polymerase chain reaction (PCR) using the sex-related gene and the chromodomain helicase DNA binding protein (CHD) gene. The result of the CHD gene, which was used with a single set of primers and a restriction enzyme treatment after the PCR process, was more accurate in identifying the gender of the Crested ibis. In addition, we compared the CHD gene sequences with the previously reported sequences and found 1~2 different bases between females (CI2, CI4, CI5, and CI6) than in studies previously reporting female sequences.

Kinetics and Stereochemistry for the Aquation of trans-$[Co(en)(tmd)Cl_2]^+$Cation (Trans-$[Co(en)(tmd)Cl_2]^+$ 錯이온의 水化反應에 對한 反應速度와 立體化學)

  • Jeong, Jong-Jae;Roh, Byung-Gil;Kim, Eun-Ki;Oh, Sang-Oh
    • Journal of the Korean Chemical Society
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    • v.35 no.6
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    • pp.607-611
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    • 1991
  • The stereochemical ratio cis and trans isomer of the hydration reaction of trans-$[Co(en)(tmd)Cl_2]^+$ complex ion were studied with varing temperature by the spectrophotometric method. It was observed that the ratio of cis-isomer was about 30%, and the intermediate was rearranged. And in order to investigate this mechanism more clearly, stability energy profile, interaction diagram and orbital correlation diagram were calculated by the EHT method. By the calculation, the mechanism of cis-isomer was in good agreement with the experimental results, and it was estimated that the hydration reaction was carried through some distorted square pyramid (sp).

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