• Food Science and Biotechnology
• /
• 제16권5호
• /
• pp.691-709
• /
• 2007

Concerns on environmental waste problems caused by non-biodegradable petrochemical-based plastic packaging materials as well as consumer's demand for high quality food products has caused an increasing interest in developing biodegradable packaging materials using annually renewable natural biopolymers such as polysaccharides and proteins. However, inherent shortcomings of natural polymer-based packaging materials such as low mechanical properties and low water resistance are causing a major limitation for their industrial use. By the way, recent advent of nanocomposite technology rekindled interests on the use of natural biopolymers in the food packaging application. Polymer nanocomposites, especially natural biopolymer-layered silicate nanocomposites, exhibit markedly improved packaging properties due to their nanometer size dispersion. These improvements include increased mechanical strength, decreased gas permeability, and increased water resistance. Additionally, biologically active ingredients can be added to impart the desired functional properties to the resulting packaging materials. Consequently, natural biopolymer-based nanocomposite packaging materials with bio-functional properties have huge potential for application in the active food packaging industry. In this review, recent advances in the preparation and characterization of natural biopolymer-based nanocomposite films, and their potential use in food packaging applications are addressed.

• Nuclear Engineering and Technology
• /
• 제52권5호
• /
• pp.918-924
• /
• 2020

Film boiling is of great importance in nuclear safety as it directly influences the integrity of nuclear fuel in case of accidents involving loss of coolant. Recently, nuclear power plant safety under earthquake conditions has received much attention. However, to the best of our knowledge, there are no existing studies reporting film boiling in an oscillating system. Most previous studies for film boiling were performed on stationary systems. In this study, numerical simulations were performed for saturated film boiling of water on a horizontal surface under low frequencies to investigate the effect of system oscillation on film boiling heat transfer. A coupled level-set and volume-of-fluid method was used to track the interface between the vapor and liquid phases. With a fixed oscillation amplitude, overall, heat transfer decreases with oscillation frequency. However, there is a frequency region in which heat transfer remains nearly constant. This lock-on phenomenon occurs when the oscillation frequency is near the natural bubble release frequency. With a fixed oscillation frequency, heat transfer decreases with oscillation amplitude. With a fixed maximum amplitude of the additional gravity, heat transfer is affected little by the combination of oscillation amplitude and frequency.

• International Journal of Industrial Entomology and Biomaterials
• /
• 제5권2호
• /
• pp.163-170
• /
• 2002

In this paper, silk fibroin (SF)/polyurethane (PU) blend films were fabricated to develop a new biomaterial for biomedical applications. These blend films were prepared using formic acid as a cosolvent, and structural characteristics and properties of blend films were investigated. FTIR results suggested that there was no specific interaction between SF and PU, implying molecular immiscibility in SF/PU blend films. Furthermore, it was revealed by XRD method that the crystalline region of blend components was not perturbed by counterpart polymers. The degree of phase separation of SF/PU blend films was diminished by increasing PU content in blend. Especially, the blend with 70% content of PU showed no evidence of macro-phase separation in SEM observation. However, SF/PU blend (70/30) was revealed to be phase-separated in a lower dimension confirmed by DMTA measurement. TGA result showed that thermal decomposition temperature of blend film was slightly decreased compared to those of SF and PU polymer itself, Though mechanical properties of SF/PU blend films were not good enough due to the solvent, blood compatibility of PU can be enhanced markedly by mixing with SF for SF/PU blend film.

• 대한기계학회논문집
• /
• 제19권10호
• /
• pp.2595-2606
• /
• 1995

Buoyancy-assisted melting of an unconstrained ice in an isothermally heated horizontal enclosure was numerically analyzed in a range of wall temperatures encompassing the density inversion point. The problem as posed here involves two physically distinct domains each of which has its own scales and respective heat transfer mode. These two domains join at the junction where the liquid squeezed out of the film region flushes into the lower melt pool. Both of these domains have been treated separately in the literature by a patching technique which invokes several, otherwise unnecessary, assumptions. The present study eliminates successfully such a superfluous procedure by treating the film and lower melt pool regions as a single domain. As a result of this efficient solution procedure, the interaction of the water stream ejected at the junction and the natural convection in the melt pool could be clarified for different wall temperatures. Though limited by two-dimensionality, the present results conformed indirectly the earlier reported transition of the flow pattern, as the wall temperature was increased over the density inversion point. The transient evolution of the melting surface, the time rate of change in melt volume fraction, the local and temporal variation of the heat transfer coefficients are analyzed and presented.

• 한국식품위생안전성학회지
• /
• 제14권1호
• /
• pp.90-96
• /
• 1999

Biodegradable films were prepared by solution blending method in the weight ratio of Chitosan and Algin for the purpose of useful bioimplants. The possibility of bioimplants, which prepared from natural polymers as a skin substitute and food wrapping materials were evaluated by measuring the biodegradability. these biodegradable films were inserted in the back of rats and their biodegradability was investigated by hematological change as a function of time. Rats study showed that low-Chitosan induced increments of monocyte and basophil after 48 hours of implantation. And medium-Chitosan showed increase of lymphocyte and decreased neutrophil counts after 48 hours of implantation. Low, medium Chitosan showed high hemoglobin contents, medium and high Chitosan showed high hematocrit value after 48 hours of implantation. As a result, medium, high-Chitosan induced potential incompatibility in the tissue after 48 hours, but there was little effects to the skin inflammation. The values of biodegradable films, which prepared from natural polymers measured in this study were some satisfiable results at short period with those of ideal skin bioimplants and artificial skin.

• 대한기계학회:학술대회논문집
• /
• 대한기계학회 2007년도 춘계학술대회B
• /
• pp.3098-3103
• /
• 2007

In this paper, natural convection of a magnetic fluids(W-40) in a half circular pipe enclosure are investigated by numerical and experimental method. One side wall is kept at a constant temperature(25$^{\circ}C$), and the opposite side wall is also kept at a constant temperature(20$^{\circ}C$). Under above conditions, various magnitudes of the magnetic fields were applied up. Theoretical study through the governing equation derived by Siliomis is carried out with numerical analysis by the GSMAC Method. And the thermo-sensitive liquid crystal film(R20C5A) is utilized in order to visualize wall-temperature distributions as an experimental method. This study has resulted in the following fact that the natural convection of a magnetic fluids are controlled by the direction and intensity of the magnetic fields.

• Bulletin of the Korean Chemical Society
• /
• 제31권5호
• /
• pp.1182-1186
• /
• 2010

A novel poly(safranine)-modified electrode has been constructed for the determination of 4-nitrophenol (4-NP) in natural water sample. The electrochemical behavior of poly(safranine) film electrode and its electrocatalytic activity toward 4-NP were studied in detail by cyclic voltammetry (CV) and adsorptive linear stripping voltammetry (LSV). All experimental parameters were optimized and LSV was proposed for its determination. In optimal working conditions, the reduction current of 4-NP at this poly(safranine)-modified electrode exhibited a good linear relationship with 4-NP concentration in the range of $8.0{\times}10^{-8}$ to $4.0{\times}10^{-5}mol\;L^{-1}$. The detection limit was $3.0{\times}10^{-8}mol\;L^{-1}$. The high sensitivity and selectivity of the sensor were demonstrated by its practical application for the determination of trace amounts of 4-NP in natural water and fruit samples.

• Transactions on Electrical and Electronic Materials
• /
• 제1권1호
• /
• pp.1-5
• /
• 2000

Diamond films have been achieved on Si(100) substrates using helicon plasma chemical vapor deposition(HPCVD), Gas mixtures with methane and hydrogen have been used. The growth characteristics were investigated by means of X-ray photoelectroton spectroscopy, Atomic force microscopy and X-ray diffraction. We obtained a plasma density as high as 10$\^$10/~10$\^$11/ cm$\^$-3/ by helicon source. The smooth(100) faces of submicron diamond crystallites were found to exhibit pyramidal shaped architecture, The XPS spectrum for the nucleation layer indicates the presence of diamond at 285.4 eV, close to the reported value of 285.5 eV for diamond , XRD results demonstrates the existence of polycrystalline diamond as the diamond (111) and (220) peaks.

• Nuclear Engineering and Technology
• /
• 제28권6호
• /
• pp.532-541
• /
• 1996

Theoretical and numerical study on heat transfer and evaporation in the vertical channel has been carried out and basic correlations have been derived for the heat transfer evaluation of PCCS. Analysis program was developed with low-Reynolds-number k-$\varepsilon$ model and surface transfer rates were calculated for the turbulent natural convection in the vertical channel. In relation to dry cooling by buoyancy-driven air, first, the system parameters which govern overall heat transfer rate are determined through the adequate nondimensionalization procedure. After comparison with existing experimental data, numerical results are used to derive heat transfer correlation by sensitivity calculations. In relation to wet cooling by falling water film, numerical analysis are carried out for evaporation process with real film surface conditions and evaporation correlation is derived through analogy concept and correction factors.

• Carbon letters
• /
• 제7권4호
• /
• pp.245-248
• /
• 2006

Thin films of carbon-nano materials (CNMs) of different morphology have been successfully deposited on ceramic substrate by CVD at temperatures $800^{\circ}C$, $850^{\circ}C$ and $900^{\circ}C$ using plant based oils in the presence of transition metal catalysts (Ni, Co and Ni/Co alloys). Based on the return and insertion loss, microwave absorption properties of thin film of nanocarbon material are measured using passive micro-Strip line components. The result indicates that amongst CNMs synthesized from oil of natural precursors (mustered oil - Brassica napus, Karanja oil - Pongamia glabra, Cotton oil - Gossipium hirsuta and Neem oil - Azadirachta indica) carbon nano fibers obtained from neem's seed oil showed better microwave absorption (~20dB) in the range of 8.0 GHz to 17.90 GHz.