• 한국의류산업학회지
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• 제16권3호
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• pp.462-468
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• 2014

This study investigates the dyeability of soybean protein fabric after dyeing with gallut. In this study, the colorants of gallnut were extracted with boiling water at $60^{\circ}C$ and 60min. Soybean protein fabric was dyed with extracted solution from gallnut according to concentration, temperature and time. After dyeing with gallut solution, dyeability (K/S) was obtained by CCM observation. Al, Cu and Fe were employed as a mordanting agents. Various color changing were produced by the interactions of mordants that were different from soybean protein fabric; however, Al mordant was not indicated as a variable color change. Fastness to washing and light were also investigated. Consequently, the dyeability of the soybean protein fabric dyed with gallut showed reasonable results at 100% o.w.f, $90^{\circ}C$, for 60min. Fastness to washing according to concentration indicated good result as more than grade (4-5) in general. Fastness to light was almost the same compared to fastness to washing at all concentrations. Fastness to washing according to mordants indicated good grade (4) in principle at Al, Cu, and Fe; in addition, fastness to light indicated a good grade too. Fastness to light also indicated the highest dyeability at Fe mordant. This study shows that gallut is a reasonable dyestuff to soybean protein fabric and that it is possible to manufacture a variety of products that use soybean protein fabric.

• Journal of the Korean Wood Science and Technology
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• 제34권3호
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• pp.90-98
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• 2006

일반적으로 동물성 섬유(견, 모)는 단백질 섬유로서 매염제를 쓰지 않고도 염색이 잘되는 편이지만, 식물성 섬유인 면, 마 등은 섬유소이므로 색소의 흡착이 불량하여 염색성이 우수한 염색 보조제로 전처리 한 다음, 주매염제를 처리해야 좋은 결과를 얻을 수 있다. 식물성 섬유의 일종인 인피섬유로 이루어진 한지의 천연염색 효과 향상을 위해 염색 보조제로 콩즙, 탈지분유 및 키토산을 한지에 전처리를 한 다음, 황벽나무 수피, 찔레나무 지엽, 꼭두서니 및 자초 뿌리로부터 염료를 추출하고 $Al_2(SO_4)_3$와 $Fe(OH)(CH_3COO)_2$를 매염제로 사용하여 염색한 한지의 염색특성과 견뢰도를 분석하였다. 천연염색 한지의 색상 및 색차 분석결과 염색 보조제를 사용한 것이 모든 염료에서 무처리 시료보다 염색이 양호하였으며, 사용한 염색 보조제 중에서는 콩즙으로 전처리한 시료가 가장 우수한 염색 효과를 나타내었다. 촉진노화 시험을 통한 천연염색 한지의 견뢰도를 분석한 결과 자초가 가장 불량한 것으로 나타났으며, 꼭두서니가 비교적 우수한 것으로 나타났다.

• 한국자원식물학회지
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• 제18권1호
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• pp.71-77
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• 2005

복숭아나무 전정 과정에서 발생하는 부산물인 절지의 천연염료로서 이용성을 조사하였다. 복숭아 가지 추출물로 견과 면직물을 염색한 결과 견직물의 표면색은 매염제에 따른 차이가 있는 가운데 무염색 포에 비해 색차(${\Delta}E$값)가 11.63에서 30.86까지 나타났다. 면직물은 무매염시 17.71에서 황산철 매염시 40.41로 견직물 보다 염색성이 좋은 것으로 나타났다. 매염제에 따라서는 소석회와 가성소다 매염시 a값이 높게 나타났으며, 황산구리와 명반, 식초 매염시는 b값이 높게 나타났다. 세탁을 3회 실시한 뒤 표면색을 조사한 결과 매염제에 따른 차이는 다소 있었으나 전체적으로 무염색구와의 사이에 색차가 줄어든 것으로 나타나 세탁 견뢰도는 다소 약한 것으로 나타났다. pH가 다른 수세액에 의한 수세 및 일광 처리 후 표면색의 변화를 조사한 결과 처리 전후간에 차이가 적어 pH에 대한 견뢰도 및 일광 견뢰도는 비교적 좋은 것으로 나타났다.

• 한국자원식물학회지
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• 제18권2호
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• pp.216-222
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• 2005

복숭아나무 전정 과정에서 발생하는 부산물인 절지의 천연염료로서 이용성을 조사하였다. 복숭아 가지 추출물로 견과 면직물을 염색한 결과 견직물의 표면색은 매염제에 따른 차이가 있는 가운데 무염색포에 비해 색차(${\Delta}$값)가 11.63에서 30.86까지 나타났다. 면직물은 무매염시 17.71에서 황산철 매염시 40.41로 견직물 보다 염색성이 좋은 것으로 나타났다. 매염제에 따라서는 소석회와 가성소다 매염시 a값이 높게 나타났으며, 황산구리와 명반, 식초 매염시는 b값이 높게 나타났다. 세탁을 3회 실시한 뒤 표면색을 조사한 결과 매염제에 따른 차이는 다소 있었으나 전체적으로 무염색구와의 사이에 색차가 줄어든 것으로 나타나 세탁 견뢰도는 다소 약한 것으로 나타났다. pH가 다른 수세액에 의한 수세 및 일광처리 후 표면색의 변화를 조사한 결과처리 전후간에 차이가 적어 pH에 대한 견뢰도 및 일광 견뢰도는 비교적 좋은 것으로 나타났다.

• 펄프종이기술
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• 제48권3호
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• pp.57-65
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• 2016

Indigo (Polygonum tinctorium L.) is a typical blue dye which had been used from ancient times. This study was going to shade the complicated traditional methods extracting indigo dye by the fermentation and producing as adsorbate on calcium hydroxide, which says so called as the 'Indigo lime'. Accordingly we were going to make indigo through the hydrolysis of the hot water extractives of indigo leaves simply. During hot-water extraction, ${\beta}$-glucosidase which required hydrolysis of the linkage between indigo and glucose was not activated. To achieve this goal, indican was acid-hydrolyzed to glucose and indigo. The acetic acid, citric acid, hydrochloric acid, and sulfuric acid were used for the hydrolysis of hot water extractives. The hydrolysis conditions of extractives performed in water bath at $80^{\circ}C$ for 120 minutes and in an autoclave for 120 minutes. In the acid hydrolysis of extracted indican by hot water, the indican yields of acetic acid and hydrochloric acid hydrolysis were higher than sulfuric acid in water bath. Also, the indican yield of hydrochloric acid hydrolysis was better than sulfuric acid in autoclave. The hot water extracted indican was confirmed by HPLC analysis and its structure was confirmed by UV-Vis and FT-IR spectroscopy, compared with isolated indigo and commercial synthesized indigo. This improved extraction and hydrolysis methods can be replace the traditional indigo making method.

• 한국지역사회생활과학회지
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• 제18권3호
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• pp.391-398
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• 2007

Ginkgo leaves, which have been known as medical materials, were selected as new natural dyes in this study, in which it was examined whether they have the function of UV-blocker or not. Cotton, linen & Hanji(Korean traditional paper) were dyed with Ginkgo. Al, Cr, Cu, Fe and Sn were selected as mordants. UV-blocking rate of dyed samples was measured after dyeing and mordant treatment. The results of this study are as follows. First, most surface color of dyed samples was yellow except that Hanji mordanted with Cu was yellowish red. Second, dyeing repetition had positive correlations with K/S values of cotton ($r=.\;758^{**}$), linen ($r=.\;500^*$) and Hanji ($r=.\;819^{**}$), because K/S values were increased according to dyeing repetition. Third, solar UV-blocking rates had positive correlations with dyeing repetitions (p<0.01), because UV-blocking rates had increased according to dyeing repetition. Fourth, UV-blocking ability of Hanji was highest among samples, as UV-blocking rates of cotton and linen dyed after 3 dyeing repetition were up to 93%, Hanji's values were up to 98%. Therefore, it was proven that Ginkgo extracts used in this experiment as dyestuff have excellent dyeing ability and high UV-blocking ability. It is hoped that this work will lead to further research to confirm the physiological effects when human wear the clothes made from Hanji.