• Title/Summary/Keyword: natural cellulose

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Study on the noodle-making properties of rice added with natural polymers (천연고분자 첨가에 의한 쌀국수 제면성 연구)

  • Cho, Hee-Jung;Yoo, Young-Jin;Kang, Mi-Young;Um, In-Chul
    • Current Research on Agriculture and Life Sciences
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    • v.29
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    • pp.55-62
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    • 2011
  • In this study, four natural polymers were added into rice flour to prepare rice noodle and their effects on the fabrication of rice noodle were examined. Also, the effect of water dosage and natural polymer content on the noodle-making properties of rice noodle was investigated. Addition of xanthan gum showed the best performance of noodle formation, while crystalline cellulose did not help the improvement of noodle making properties of rice dough. Regardless of natural polymer type, the amount of water dosage and polymer content influenced significantly the performance of rice noodle formation. In case of xanthan gum, 3% polymer content and 64~68% water dosage were the best conditions to fabricate a good rice noodle. Guar gum showed the best performance at 2~3% guar gum addition and 66% water content. Finally, 3% carboxymethyl cellulose and 64% water dosage were optimum condition for good formation of rice noodle.

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Grafting of MMA onto MCC through free radical method and its application to all natural cellulose composite film preparation (Microcrystalline cellulose에 자유 라디칼을 이용한 methyl methacrylate의 그래프팅 반응과 이를 이용한 천연복합필름의 제조)

  • Lee, Soo;Park, Sang-Hee;Jin, Seok-Hwan;Lee, Sun-Young
    • Journal of the Korean Applied Science and Technology
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    • v.25 no.4
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    • pp.459-468
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    • 2008
  • Methyl methacrylate(MMA) was grafted onto microcrystalline cellulose(MCC) with ceric ammonium nitrate(CAN) as a redox initiator at the various conditions. The cellulose triacetate(CTA) composite films added MCC and MMA-grafted MCC powders were prepared on a glass plate. The graft yield(GY) and graft efficiency(GE) of the grafted MCC were calculated with the simple equations by the weight balance method. The double bond of C=O on the grafted MCC surfaces was confirmed by the fourier transform infrared spectroscopy with attenuated total reflection(FT-IT ATR) spectrophotometer. After grafting, the degree of crystallinity of cellulose powders was decresed by judging from x-ray diffraction(XRD) data. Scanning electron microscope(SEM) photos showed the only solvent and CAN solution could change the roughness of MCC powders and the effect of powder dispersions in composite matrix. The tensile strength of MCC/CTA composite films was decreased with increase of MCC powder contents. When 5% grafted MCC was added, the tensile strength of grafted MCC/CTA composite films was increased from 82.3 MPa to 97.2 MPa. The thermal property of powders was also analyzed by the thermogravimetric analysis(TGA).

A Study of the Cationization of Bamboo-cotton Blended Fabric (대나무-면 복합직물의 양이온화에 관한 연구)

  • Noh, Young-Ju;Lee, Shin-Hee
    • Fashion & Textile Research Journal
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    • v.24 no.2
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    • pp.260-266
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    • 2022
  • Cellulose fiber is a material used in various fields. It is the most used type of fiber because of its excellent hygroscopicity and dyeability. Recently, as natural fiber materials have been highlighted due to the influence of eco-friendliness and well-being, bamboo fiber has become a commonly used eco-friendly fiber. Cellulose fibers are part of the -OH hydroxyl group, which means they are more chemically reactive than synthetic fibers. In this study, the cationization properties of bamboo-cotton blended fabrics cationized using CHPTAC (3-chloro-2-hydroxypropyl trimethyl ammonium chloride) in the PDC (padding-drying-curing) method were investigated. Various characteristics according to cationization were studied through elemental analysis, FT-IR (fourier-transform infrared spectroscopy) analysis, X-ray diffraction analysis, TGA (thermogravimetric) analysis, and SEM (scanning electron microscope) analysis. The nitrogen content of the cationized bamboo-cotton blended fabric increased with an increase in the concentration of the cationizing agent CHPTAC, and it was seen to be highly bound to cellulose molecules. As a result of the FT-IR analysis, both 100% pure cotton fabrics and CHPTAC-0 and CHPTAC-150 fabrics were seen to be typical cellulose. As a result of the X-ray diffraction analysis, both 100% pure cotton fabrics and CHPTAC-0 and CHPTAC-150 fabrics showed typical cellulose I structures. As a result of the X-ray diffraction analysis, both 100% pure cotton fabrics and CHPTAC-0 and CHPTAC-150 fabrics showed typical cellulose I structures. As the cationization progressed, micropores appeared on the surface of the blended fabric.

A Study on the Dyeability of Natural Dyes of Sustainable Seaweed-Containing Fiber (지속 가능한 해초 함유 섬유의 천연염료 염색성에 관한 연구)

  • Kim, Sojin;Choi, Kyoungmi
    • Journal of Fashion Business
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    • v.26 no.3
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    • pp.87-97
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    • 2022
  • This study investigated the dyeability and color change of the natural dyes of SeaCell, a biodegradable functional fiber that is permanently added to cellulose fibers with natural additives extracted from seaweeds. The natural dyes used in the study are five dyes. Gardenia and turmeric, which are yellow-based natural dyes, Sappan wood and Lac, which are red-based natural dyes, and Indigo, a blue-based natural dye, were selected. The dyeability and color change according to the change of the mordant conditions and the number of times of dyeing were investigated. In addition, the dyeing properties and colors of cotton and silk fibers were compared under the same dyeing conditions as SeaCell. The study results are as follows. It was found that SeaCell had lower dyeing properties than silk, a protein fiber, in gardenia, sappan wood, and lac dyes, but had higher dyeing properties than cotton with the same cellulose component as SeaCell fibers. In the case of turmeric, it showed higher dyeing properties than cotton except for the no mordant condition. In the case of Indigo dye, SeaCell shows the best dyeability, indicating that it is a very suitable fiber for Indigo dyeing. As sustainable functional fibers are continuously developed in the future, natural dyes that are environmentally friendly and human-friendly are actively introduced and commercialized, and it is expected that they can be used as reference materials.

Microbial Modification of Extracellular Polysaccharides

  • Jin Woo Lee
    • Journal of Life Science
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    • v.9 no.1
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    • pp.69-80
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    • 1999
  • Some trials to alter the structure of extracellular polysaccharides by means of biotransformation and microbial modification have been reported. Seaweed alginate was acetylated by intact and resting cells of Pseudomonas syringae ATCC 19304. Glucose analogs such as 3-O-methyl-D-glucose used as sole carbon sources was directly incorporated into curdlan by agrobacterium sp. ATCC 31749. The 2-amino-2-deoxy-D-glucose (glucosamine)and 2-acetamido-2-deoxy-D-glucose (N-acetylglucosamine) were incorporated into microbial cellulose by Acetobacter xylinum ATCC 10245. The changed monomeric composition in pullulan by Aureobasidium pullulans ATCC 42023 as well as zooglan by Zoogoea ramigera ATCC 25935 was another effect of glucose analogs used a carbon source. There was no effect of glucose analogs found in polysacharide-7 (PS-7) produced by Beijerinckia indica. ATCC 21423.

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Self sustained n-type memory transistor devices based on natural cellulose paper fibers

  • Martins, R.;Barquinha, P.;Pereira, L.;Goncalves, G.;Ferreira, I.;Fortunato, E.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.1044-1046
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    • 2009
  • Here we report the architecture for a non-volatile n-type memory paper field-effect transistor. The device is built using the hybrid integration of natural cellulose fibers (pine and eucalyptus fibers embedded in an ionic resin), which act simultaneously as substrate and gate dielectric, with amorphous GIZO and IZO oxides as gate and channel layers, respectively. This is complemented by the use of continuous patterned metal layers as source/drain electrodes.

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Functional Analysis of a Gene Encoding Endoglucanase that Belongs to Glycosyl Hydrolase Family 12 from the Brown-Rot Basidiomycete Fomitopsis palustris

  • Song, Byeong-Cheol;Kim, Ki-Yeon;Yoon, Jeong-Jun;Sim, Se-Hoon;Lee, Kang-Seok;Kim, Yeong-Suk;Kim, Young-Kyoon;Cha, Chang-Jun
    • Journal of Microbiology and Biotechnology
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    • v.18 no.3
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    • pp.404-409
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    • 2008
  • The brown-rot basidiomycete Fomitopsis palustris is known to degrade crystalline cellulose (Avicel) and produce three major cellulases, exoglucanases, endoglucanases, and ${\beta}$-glucosidases. A gene encoding endoglucanase, designated as cel12, was cloned from total RNA prepared from F. palustris grown at the expense of Avicel. The gene encoding Cel12 has an open reading frame of 732 bp, encoding a putative protein of 244 amino acid residues with a putative signal peptide residing at the first 18 amino acid residues of the N-terminus of the protein. Sequence analysis of Cel12 identified three consensus regions, which are highly conserved among fungal cellulases belonging to GH family 12. However, a cellulose-binding domain was not found in Cel12, like other GH family 12 fungal cellulases. Northern blot analysis showed a dramatic increase of cel12 mRNA levels in F. palustris cells cultivated on Avicel from the early to late stages of growth and the maintenance of a high level of expression in the late stage, suggesting that Cel12 takes a significant part in endoglucanase activity throughout the growth of F. palustris. Adventitious expression of cel12 in the yeast Pichia pastoris successfully produced the recombinant protein that exhibited endoglucanase activity with carboxymethyl cellulose, but not with crystalline cellulose, suggesting that the enzyme is not a processive endoglucanase unlike two other endoglucanases previously identified in F. palustris.

Paper Properties Improvement by adding Microfibrillated Cellulose-Mineral Composites (Microfibrillated Cellulose (MFC)와 중질탄산칼슘 (GCC)로 구성된 복합충전제를 이용한 종이 물성 향상)

  • Lee, Jung Myoung
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.48 no.2
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    • pp.83-90
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    • 2016
  • Increasing the amount of filler in paper is of high interest for paper industry while maintaining its key sheet quality properties. In this study, a MFC-GCC composite, made through a co-grinding NBSK (Northern bleached softwood kraft) pulp with a ground calcium carbonate (Intracarb 60), was used as a strength aid in paper in order to evaluate a potential cost reduction through filler increase without sacrificing paper quality. Hand-sheets were made of NBSK and/or eucalyptus pulp by using white water recirculation in a Tappi sheet former and was compared its properties without or with MFC additions at different filler levels. It was found that the MFC-GCC composite has a large surface area compared to the fiber, allowing the formation of more hydrogen bonds in the web, thus giving natural strength to the paper. Overall results are encouraging that the MFC-GCC composite allows papermaker to reduce basis weight and maintain critical sheet properties.

Smouldering Combustion of Combustible Natural Polymer Dust Layer (가연성 천연고분자 분체의 훈소에 관한 연구)

  • Kim, Hong
    • Journal of the Korean Society of Safety
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    • v.5 no.1
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    • pp.7-18
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    • 1990
  • This study measured the smouldering temperature of dust layer for various combustible natural polymer material by practical apparatus. The dust layer was either put on the preheated plate of constant temperature, or formed with cylinderical metal sleeve of various diameters and depths at room temperature and then heated up to a pre-determined smouldering temperature. Plots of arrival times versus smouldering temperature were made to compare the smouldering characteristics with kinds of dusts. The natural polymer material was divided into theree groups by characteristics of smouldering mechanism. This groups are cellulose group, lipide group and glucose group.

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Rheological Behavior of Lyotropilc Solutions of Cellulose in the $NH_3/NH_4SCN$ Solvent System

  • Jo, Jae-Jeong;Cuculo, J.A.;Theil, M.H.
    • Proceedings of the Korean Fiber Society Conference
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    • 1990.06b
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    • pp.36-37
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    • 1990
  • In the past, facile dissolution of cellulose has been hampered by the lack of suitable nondegrading solvents. Recently, this problem has been solved in our laboratory by the discovery of an inexpensive, convenient solvent system, that is the mixture of $NH_3\;and\;NH_4SCN$, for cellulose. Also, the $cellulose/NH_3/NH_4SCN$ solution system has been found to form the anisotropic, i.e., liquid crystalline phase. It is believed that both the cholesterio and the nematic phase occur. This finding has prompted extensive on-going researoh on the formation of the liquid crystalline phase from an inexpensive natural source such as cellulose since the nematic phase is envisioned as an excellent precursor sources for products with desirable properties, for example, high modulus and high strength. This interest naturally leads to a desire to understand the theological properties of the nematic phase so that the transformation of the nematic phase to the solid state with desirable properties can be efficiently accomplished, ;From this point of view, the theological behavior of the $cellulose/NH3_/NH_4SCN$ system has been studied as a function of shear rate and shear stress over a wide range of solvent compositions, cellulose concentration, centrifugation and urea contents, Results indicate that the viscosity decreases with increasing shear rate. A marked shear thinning behavior and a quasi-Newtonian behavior were observed in the low shear rate region and in the high shear rate region, respectively for all solvent compositions. The $cellulose/NH_3/NH_4SCN$ solution system only exhibited the viscosity increase with increasing cellulose concentration and failed to show the viscosity drop generally observed at the point of incipience of liquid crystal formation, This may be due to the gel-like nature of the solution by the association of the rodlike molecules into bundles which may serve as crosslinking points giving the cellulose solution a network structure. Also, simply hydrogen bonding may be so restrictive of molecular mobility that a viscosity drop is blocked. In addition to the above results, yield stress and thixotropy were also observed in the $cellulose/NH_3/NB_4SCN$ solution system which are characteristics of liquid crystal and gel, The results of the effect of centrifugation on viscosity show that viscosity decreases by the application of centrifugation. This may be explained by the change of the piled polydomain structure to the dispersed polydomain structure due to the pressure gradient generated during centrifugation.ation.

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