• Proceedings of the Korean Society for Agricultural Machinery Conference
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• 2017.04a
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• pp.111-111
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• 2017

There still exist adhesives that have toxic compounds or consist of those materials in both our life and lots of industries. For instance, formaldehyde adhesive had been still used for woodworking and some medical adhesives had been considered as toxicity problems. In this situation, natural adhesives from raw materials have been suggested as an one of considerable interests. Natural adhesives in recent have been reported fabrication methods via biological materials such as proteins, celluloses, and starches. By-products derived from agricultural something have them richly and each has additional special properties. Using these properties to make natural adhesives, unique adhesives would be attained. In particular, rice-based adhesive is such a good example. Rice-based by-product adhesives have interestingly some pros pertaining to high adhesive strength, excellent water resistance and could dramatically be reduced a formaldehyde a harmful component of plywood. Hence, rice-based adhesive like glues could be applied to lots of industries including agricultural and biological technology. This review paper highlighted some recent development on natural adhesives as a promising biomaterial for agricultural and biological technology fields. The design of agricultural by-product-based natural adhesives were described to demonstrate the application of agricultural and biological technology

• Journal of Adhesion and Interface
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• v.12 no.4
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• pp.125-132
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• 2011

As the enhancement of indoor air quality is increasingly compelling the use of natural materials without any emission, this study reports the preparation and performance of natural garlic adhesives for wallpaper. The natural garlic adhesives were successfully prepared by the extraction of the clove of raw garlic with water to isolate carbohydrates and proteins. Properties of the prepared garlic adhesives such as the non volatile solids content, viscosity, density, and pH were 62%, 2,789 mPa.s, $1.3g/cm^3$, and 6.6, respectively. The non-volatile solids content has a great impact on the adhesion performance of the prepared garlic adhesives, which was adequate about 60%. Bonding strength of prepared garlic adhesives was greater than the requirement of a Korean standard for wallpaper. In addition, the garlic adhesives showed antibacterial activity inheriting from the garlic. It is expected that the prepared garlic adhesives could be used as safe and natural adhesives without emitting any volatile organic compounds and formaldehyde gas.

• Korea Science and Art Forum
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• v.37 no.5
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• pp.239-248
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• 2019

This study started from the need to improve one of shortcomings of synthetic PVAc adhesives - potential physical harm and environmental hazards to the workers or their users. As a matter of fact, PVAc adhesives are currently mainly used because of their convenience and economy for the production of woodcrafts. The purpose of this study was to develop natural adhesives through research on natural adhesives in step with the current increase of societal attention to environmental friendliness and rapid surge in their demand in the face of such problems. So, the study attempted research on the bases to develop natural adhesives for woodcraft, using cellulose extracts from wood - natural adhesive material. The findings of the study were as follows. Firstly, natural adhesives showed the improved effect in the field of adhesive strength, a basic physical property by 0.2 - 4 times compared with the existing materials and the study confirmed they had the similar or stable pH value. Besides, they had good reversibility, demonstrating their basic physical property as a natural adhesive for woodcraft. While, their durability to ultraviolet ray degradation also showed an excellent result value being better by 1.5 - 8.5 times than the existing materials. The study expects natural adhesives with improved and better performances compared with the existing materials could be developed, if further research on adhesive strength, antibiosis, conservative property were to continue by developing refinery technology for cellulose extracts from wood and rendering the functionality to them.

• Journal of the Korean Wood Science and Technology
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• v.35 no.4
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• pp.38-44
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• 2007

As environmental issues is important thing, our study aims to develop natural adhesives made by rosin instead of synthesis adhesive with the formaldehyde emission. Natural adhesives were formulated to enhance curing speed and adhesion performances with various drying agent contents. Adhesion performances were evaluated with tack values measured by texture analyzer and shear strengths determined by single lap shear test. The adhesion performances of nature adhesives developed in this study and compared with those of overseas natural adhesives made by AURO, BioFa, Livos. Optimum drying agent formulation was Co 0.7 part, Zr 1.0 part, Ca 0.5 part, and Activ8 0.1 part. Shear strength of the adhesives manufactured by the optimum drying agent formulation was $93.2{\pm}19.1N/cm^2$.

• Journal of Conservation Science
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• v.31 no.2
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• pp.115-123
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• 2015

This study aims to increase the transparency of the natural adhesives made with lacquer and glue. For the purpose, samples were prepared by mixing urushiol with glue in varied proportion and the characteristics and adhesive properties were investigated. By adding glue on urushiol, IR spectra of the natural adhesives became similar to that of glue as the N-H band related with protein of glue increased, while that of methylene C-H bond related to urushiol decreased. Samples were dried within a day and maintained a bright color without blackening by oxidation during the curing process. The natural adhesives with urushiol and glue showed various range of viscosity and tensile shear strength as Cemedine C or Epoxy resin according to mixing ratio. In addition, the sample of mixing ratio of 6:4 showed bright and transparency in appearance and tensile shear strength similar to that of Araldite AY103-1/HY956 for earthenware layer.

• Journal of Adhesion and Interface
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• v.14 no.3
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• pp.128-134
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• 2013

This study investigated the natural adhesives for ceramics conservation that can be used as a substitution for synthetic resins. Samples were prepared by mixing lacquer with animal glue and the structure and adhesion properties of the samples were analyzed. The structure analysis with FT-IR showed that carbonyl (C=O), amine (N-H) and aromatic (C=C) bonds are increased by adding animal glue on lacquer. Comparing to the viscosity and tensile strength of the sample to the Paraloid B-72 and Araldite rapid type, these natural adhesives can be a substitution for the synthetic resins. Through methodical and intensive study, we expect practical uses of this eco-friendly natural adhesives for ceramics conservation.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2009.11a
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• pp.443-446
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• 2009

In this study, a series of degradation test for structural adhesives was performed to investigate the possibility of replacement of the alternative adhesives to the conventional adhesives. Four types of the adhesives were exposed to combined environmental conditions over 1000 hours at an accelerated aging tester, which can simulate natural weather conditions such temperature, moisture and ultraviolet. Mechanical and chemical properties of the adhesives were evaluated through material testing system and FT/IR spectrometer. According to the results, the conventional adhesives can be replaced by the alternative adhesives because the alternative adhesives were more stable to environmental conditions rather than the conventional adhesives.

• Journal of Conservation Science
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• v.37 no.3
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• pp.282-288
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• 2021

This basic research was conducted to support the development of woodcraft bio-adhesives using peach gum, which is the resin produced by peach trees. The synthesis conditions of these adhesives were optimized by performing 144 experiments. The application potential of peach gum adhesives was explored by comparing their properties with those of three natural adhesives and four synthetic adhesives. The best adhesive strength was obtained by dissolving the resin in 80 mL of distilled water containing 1.5 g NaOH, 1.65 g H₂O₂ ( pH 8.0-9.0), 0.5 g NaClO, and 0.5 g H₂BO₂. The adhesive strength, which showed minimal changes and excellent reversibility, was 125.39 kgf/cm². Ultraviolet radiation-mediated deterioration in strength in the absence of total aerobic bacteria was negligible (△E^*ab = 2.75). These data confirm the potential value of peach gum-based bio-adhesives for woodcraft as well as their utility as alternatives for natural and synthetic adhesives used for the manufacture and restoration of handicrafts and preservation of cultural assets.

• Journal of the Korea Furniture Society
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• v.22 no.3
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• pp.219-229
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• 2011

Sick building syndrome symptoms that are experienced by building occupants may be caused by toxic substances such as formaldehyde and VOCs, which are known to be emitted from building materials and wood composite products such as wood-based panel, furniture, engineered flooring and construction adhesive. In Korea, the use of wood composite products for indoor environments has increased over the last decade. Recently, wood composite products have been installed in approximately 95% of newly constructed residential buildings. The use of these products has resulted in problems related to human health, and consequently a realization about the importance of indoor air quality. In addition, consumer demand is increasing for natural materials because conventional building materials and wood composite products are made by adding urea-formaldehyde resin or they contain formaldehyde-based resin. More recently, many efforts have been made to reduce formaldehyde emission from building materials that laid in the indoor environment. Especially, if conventional formaldehyde-based adhesives are replaced with green adhesives for residential spaces, it is possible to reduce most of the emission amounts of formaldehyde in indoor environments. In line with this expectation, many researches are being conducted using natural materials such as tannin and cashew nut shell liquid (CNSL). This study discussed the affects and possibilities of green adhesives to reduce formaldehyde emission in indoor environments.

• Journal of the Korea Furniture Society
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• v.11 no.1
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• pp.53-59
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• 2000

This study was to measure formaldehyde emission and bonding strength of plywoods manufactured with urea-melamine formaldehyde adhesives, which were made from three different mixing ratios of urea and melamine, and with four different formaldehyde/urea-melamine molar ratios of 1.0,1.1,1.2 and 1.4. The results were as follows 1. Amount of formaldehyde emission was the lowest at the first method of molar ratio(F/(M+U)) 1.0. Amounts of formaldehyde emission of experimental manufactured adhesives were lower than that of commercial adhesive. 2. Bonding strength of dry specimen was the highest at the first method of molar ratio(F/(M+U)) 1.4. Dry bonding strength of molar ratio(F/(M+U)) 1.4 was similar to commercial adhesive. 3. Bonding strength of wet specimen was the highest at the second method of molar ratio(F/(M+U)) 1.4. Bonding strength of wet specimen used by the third method of molar ratio(F/(M+U)) 1.4 was almost equal to commercial adhesive.