• Title/Summary/Keyword: nano-reinforcing agent

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Foaming Behavior, Structure, and Properties of Rubber Nanocomposites Foams Reinforced with Zinc Methacrylate (아연 메타아크릴레이트로 보강된 발포고무 나노복합체의 발포거동, 구조 및 특성)

  • Basuli, U.;Lee, G.B.;Jang, S.Y.;Oh, J.;Lee, J.H.;Kim, S.C.;Jeon, N.D.;Huh, Y.I.;Nah, C.
    • Elastomers and Composites
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    • v.47 no.4
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    • pp.297-309
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    • 2012
  • Different amounts of foaming agents were employed in natural rubber(NR)/butadiene rubber(BR) blends to understand the foaming behavior in presence of nano-reinforcing agent, zinc methacrylate (ZMA). The ZMA greatly improved most of the mechanical properties of the rubber foams, however it did not show considerable effect on the cell morphology, such as cell size, density and porosity. It was also observed that the foaming agent concentration affected all the mechanical parameters. When the content of foaming agent was increased, the number of foams was increased leading to a decrease in density of the compounds. But the size and distribution of foams remained unchanged with increased foaming agent. The effect of high styrene-butadiene rubber (HSBR) was also studied. The size of cells became smaller and the cell uniformity was improved with increasing HSBR. The foam rubber compounds showed much efficient energy absorbing capability at higher strains.

Rapid Sintering of Nanocrystalline (W,Ti)C-Graphene Composites (나노구조 (W,Ti)C-Graphene 복합재료 급속소결)

  • Kim, Seong-Eun;Shon, In-Jin
    • Korean Journal of Metals and Materials
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    • v.56 no.12
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    • pp.854-860
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    • 2018
  • In spite of the many attractive properties of (W,Ti)C, its low fracture toughness limits its wide application. To improve the fracture toughness generally a second phase is added to fabricate a nanostructured composite. In this regard, graphene was considered as the reinforcing agent of (W,Ti)C. (W,Ti)C-graphene composites that were sintered within 2 min using pulsed current activated heating under a pressure of 80 MPa. The rapid consolidation method allowed retention of the nano-scale microstructure by blocking the grain growth. The effect of graphene on the hardness and microstructure of the (W,Ti)C-graphene composite was studied using a Vickers hardness tester and FE-SEM. The grain size of (W,Ti)C was reduced remarkably by the addition of graphene. Furthermore, the hardness decreased and the fracture toughness improved with the addition of graphene.

Effects of Cerium Oxide Nano Particles(CNP) Containing on The Mechanical of Pit and Fissure Sealant (세륨옥사이드나노입자(CNP)첨가가 치면열구전색재 기계적 성질에 미치는 영향)

  • Jeong, Mi-Ae;Kim, Dong-Ae
    • The Journal of the Korea Contents Association
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    • v.20 no.6
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    • pp.433-438
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    • 2020
  • The aim of this study was to investigate the mechanical properties of pit and fissure sealant containing cerium oxide nano particles(CNP). Used to mix with pit and fissure sealant (ConciseTM, USA). CNP was added into liquid (0- 4.0 wt%) of pit and fissure sealant. The specimens for the vickers hardness (VHN; 10 × 2 mm), Three-point flexure (FS; 2 × 2 × 25 mm) with flexure modulus (FM) were obtained from cements at 1, 7, and 14 days after storing in (37±1)℃ distilled water. All mechanical strength tests were conducted using machine (Instron 3344) with a cross-head speed of 1 mm/min. Data were statistically analyzed by one-way ANOVA and Duncan posthoc test(p<0.05). Mechanical properties of conventional pit and fissure sealant could be enhanced by addition of CNP. Three-point flexure and modulus of pit and fissure sealant containing CNP were showed a slightly higher value not significantly with the group(p>0.05). The vickers hardness values were increase significantly with incubation time(p<0.05). Results indicated that CNP can be used considered as potential reinforcing agent for increasing mechanical properties for conventional pit and fissure sealant. Therefore, it was suggest that the additional effects of CNP and research on a wide range of substances.

Properties and Fabrication of Nanostructured 2/3 Cr-ZrO2 Composite for Artificial Joint by Rapid Sinerting (급속 소결에 의한 인공관절용 나노구조 2/3 Cr-ZrO2 복합재료 제조 및 특성)

  • Kang, Hyun-Su;Kang, Bo-Ram;Shon, In-Jin
    • Korean Journal of Materials Research
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    • v.24 no.9
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    • pp.495-501
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    • 2014
  • Despite having many attractive properties, $ZrO_2$ ceramic has a low fracture toughness which limits its wide application. One of the most obvious tactics to improve its mechanical properties has been to add a reinforcing agent to formulate a nanostructured composite material. Nanopowders of $ZrO_2$ and Cr were synthesized from $CrO_3$ and Zr powder by high energy ball milling for 10 h. Dense nanocrystalline $2/3Cr-ZrO_2$ composite was consolidated by a high-frequency induction heated sintering method within 5 min at $600^{\circ}C$ from mechanically synthesized powder. The method was found to enable not only rapid densification but also the inhibition of grain growth, preserving the nano-scale microstructure. Highly dense $2/3Cr-ZrO_2$ composite with relative density of up to 99.5% was produced under simultaneous application of a 1 GPa pressure and the induced current. The hardness and fracture toughness of the composite were 534 kg/mm2 and $7MPa{\cdot}m1/2$, respectively. The composite was determined to have good biocompatibility.

A Study on Increased Properties of Cellulose-Based Biodegradable Polymer Composites (셀룰로오스 기반 생분해성 고분자 복합재의 물성 증가에 관한 연구)

  • Sangjun Hong;Ajeong Lee;Sanghyeon Ju;Youngeun Shin;Teahoon Park
    • Composites Research
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    • v.36 no.2
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    • pp.126-131
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    • 2023
  • Growing environmental concerns regarding pollution caused by conventional plastics have increased interest in biodegradable polymers as alternative materials. The purpose of this study is to develop a 100% biodegradable nanocomposite material by introducing organic nucleating agents into the biodegradable and thermoplastic resin, poly(lactic acid), to improve its properties. Accordingly, cellulose nanofibers, an eco-friendly material, were adopted as a substitute for inorganic nucleating agents. To achieve a uniform dispersion of cellulose nanofibers (CNFs) within PLA, the aqueous solution of nanofibers was lyophilized to maintain their fibrous shape. Then, they were subjected to primary mixing using a twin-screw extruder. Test specimens with double mixing were then produced by injection molding. Differential scanning calorimetry was employed to confirm the reinforced physical properties, and it was found that the addition of 1 wt% CNFs acted as a reinforcing material and nucleating agent, reducing the cold crystallization temperature by approximately 14℃ and increasing the degree of crystallization. This study provides an environmentally friendly alternative for developing plastic materials with enhanced properties, which can contribute to a sustainable future without consuming inorganic nucleating agents. It serves as a basis for developing 100% biodegradable green nanocomposites.