• Advances in nano research
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• 제14권5호
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• pp.435-442
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• 2023

Sports activities, including playing tennis, are popular with many people. As this industry has become more professionalized, investors and those involved in sports are sure to pay attention to any tool that improves athletes' performance Tennis requires perfect coordination between hands, eyes, and the whole body. Consequently, to perform long-term sports, athletes must have enough muscle strength, flexibility, and endurance. Tennis rackets with new frames were manufactured because tennis players' performance depends on their rackets. These rackets are distinguished by their lighter weight. Composite rackets are available in many types, most of which are made from the latest composite materials. During physical exercise with a tennis racket, nanocomposite materials have a significant effect on reducing injuries. Materials as strong as graphite and thermoplastic can be used to produce these composites that include both fiber and filament. Polyamide is a thermoplastic typically used in composites as a matrix. In today's manufacturing process, materials are made more flexible, structurally more vital, and lighter. This paper discusses the production, testing, and structural analysis of a new polyamide/Multi-walled carbon nanotube nanocomposite. This polyamide can be a suitable substitute for other composite materials in the tennis racket frame. By compression polymerization, polyamide was synthesized. The functionalization of Multi-walled carbon nanotube (MWCNT) was achieved using sulfuric acid and nitric acid, followed by ultrasonic preparation of nanocomposite materials with weight percentages of 5, 10, and 15. Fourier transform infrared (FTIR) and Nuclear magnetic resonance (NMR) confirmed a synthesized nanocomposite structure. Nanocomposites were tested for thermal resistance using the simultaneous thermal analysis (DTA-TG) method. scanning electron microscopy (SEM) analysis was used to determine pores' size, structure, and surface area. An X-ray diffraction analysis (XRD) analysis was used to determine their amorphous nature.

• Advances in nano research
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• 제15권1호
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• pp.1-13
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• 2023

Ti₃C₂T_x MXene, a 2D material, is known to exhibit unique characteristics that are strongly dependent on surface termination groups. Here, we developed a novel annealing approach with Ca as a reducing agent to simultaneously remove F and O groups from the surface of multilayered MXene powder. Unlike H₂ annealing that removes F effectively but has difficulty in removing O, annealing with Ca effectively removed both O and F. X-ray photoelectron spectroscopy (XPS) and energy dispersive X-ray spectroscopy revealed that the proposed approach effectively removed F and O from the MXene powder. The results of O/N analyses showed that the O concentration decreased by 57.5% (from 2.66 to 1.13 wt%). In addition, XPS fitting showed that the volume fraction of metal oxides (TiO₂ and Al₂O₃) decreased, while surface termination groups (-O and -OH) were enhanced, which could increase the hydrophilic and adsorption properties of the MXene. These findings suggest that when F and O are removed from the MXene powder, the interlayer spacing of its lattice structure increases. The proposed treatment also resulted in an increase in the specific surface area (from 5.17 to 10.98 m²/g), with an increase in oxidation resistance temperature in air from ~436 to ~667 ℃. The benefits of this novel technology were verified by demonstrating the significantly improved cyclic charge-discharge characteristics of a lithium-ion battery with a Ca-treated MXene electrode.

• 문화기술의 융합
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• 제9권3호
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• pp.593-599
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• 2023

질산니켈육수화물염(nickel(II) nitrate hexahydrate) 수용액을 공업용 펄프에 함침시킨 전구체를 이용하여 세라믹스 분말을 제조하는 간단한 액상 합성법으로 산화니켈(NiO) 나노입자를 성공적으로 합성하였다. 질산니켈육수화물염 수용액이 함침된 전구체의 미세구조를 주사전자현미경(SEM)으로 확인하였고, 전구체의 열처리온도 증가에 따라 생성되는 산화니켈(NiO) 입자의 결정구조 및 입자크기를 X선회절분석(XRD) 및 SEM으로 분석하였다. 그 결과 전구체의 유기물질이 완전하게 열분해 되는 온도는 495-500℃이며, 열처리 온도의 증가에 따라 생성되는 산화니켈 입자의 크기 및 결정성이 증가하는 것을 XRD, SEM 분석을 통하여 확인하였다. 500-800℃에서 각각 1시간 동안 열처리하여 얻어진 산화니켈 입자의 크기는 50-200nm였다. 열처리 온도 380℃에서 NiO 결정상이 형성되고, 800℃까지는 NiO 단일상만 존재하며, 열처리 온도가 높아짐에 따라 생성되는 입자의 크기가 커지고 있음을 XRD 및 SEM 분석으로 확인하였다.

• Advances in nano research
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• 제15권4호
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• pp.295-304
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• 2023

In this paper, a powerful photocatalyst based on carbon nanocomposite is developed in order to obtain a new material applicable in water treatment and especially for the discoloration of effluents used in the textile industry. For that, TiO₂-graphene nanocomposites have been successfully synthesized by a mixture of Functionalized Graphene Sheet (FGS) and tetrachlorotitanium complexes to form FGS-TiO₂ nanocomposite. In the presence of an anionic surfactant, we used a new chemical process to functionalize graphene sheets in order to make them an excellent medium for blocking and preventing the aggregation of TiO₂ nanoparticles. The components of these nanocomposites are characterized by means of X-ray diffraction (XRD), Fourier Transform Infrared Spectroscopy (FT-IR), Scanning Electron Microscopy (SEM) and Transmission Electron Microscopy (TEM), which confirms the successful formation of the FGS-TiO₂ nanocomposite. It was found that the TiO₂ nanoparticles were dispersed uniformly on the graphene plane which possesses better charge separation capability than pure TiO₂. The FGS-TiO₂ nanocomposites exhibited higher photocatalytic activity compared to pure TiO₂ for the removal of three dyes: such as Methylene Blue (MB), Bromophenol Blue (BB) and Alizarin Red-S (AR) in water. The removal process was fast and more efficient with FGS-TiO₂ nanocomposite in daylight (in the absence of UV irradiation) compared to pure TiO₂ nanoparticles without and under UV in all pH range.

• Tribology and Lubricants
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• 제39권5호
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• pp.167-172
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• 2023

Titanium alloys are widely recognized among engineering materials owing to their impressive mechanical properties, including high strength-to-weight ratios, fracture toughness, resistance to fatigue, and corrosion resistance. Consequently, applications involving titanium alloys are more susceptible to damage from unforeseen events, such as scratches. Nevertheless, the impact of microscopic damage remains an area that requires further investigation. This study delves into the microscopic wear behavior of α-titanium crystal structures when subjected to linear scratch-induced damage conditions, utilizing molecular dynamics simulations as the primary methodology. The configuration of crystal lattice structures plays a crucial role in influencing material properties such as slip, which pertains to the movement of dislocations within the crystal structure. The molecular dynamics technique surpasses the constraints of observing microscopic phenomena over brief intervals, such as sub-nano- or pico-second intervals. First, we demonstrate the localized transformation of lattice structures at the end of initialization, indentation, and wear processes. In addition, we obtain the exerted force on a rigid sphere during scratching under linear movement. Furthermore, we investigate the effect of the relaxation period between indentation and scratch deformation. Finally, we conduct a comparison study of nanoindentation between crystal and amorphous Ti substrates. Thus, this study reveals the underlying physics of the microscopic transformation of the α-titanium crystal structure under wear-like accidental events.

• 한국염색가공학회지
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• 제35권4호
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• pp.239-245
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• 2023

Cellulose is an abundant biodegradable material in nature with excellent properties, but due to its poor processability, it has been widely studied for processing through modification. Cellulose acetate propionate (CAP) is a cellulose derivative in which the hydroxyl group of cellulose is replaced by acetyl and propionyl groups. CAP has several advantages, such as excellent solubility, structural stability, light and weather resistance, and good transparency. Porous nanofibers with excellent specific surface area, which can be applied in various fields, can be easily formed by the phase separation method using highly volatile solvents. High speed centrifugal spinning is a nano/micro fiber preparation method with advantages such as fast spinning and easy alignment control. In this study, a CAP/polybutylene succinate (PBS) spinning solution with chloroform as solvent was prepared to prepare porous microfibers and the fiber morphology was examined as a function of the disk rotation speed in an high speed centrifugal spinning device.

• 대한방사선기술학회지:방사선기술과학
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• 제46권6호
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• pp.519-526
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• 2023

This study was intended to evaluate the shielding rate of radiation shields manufactured using 3D printers that have recently been used in various fields by comparing them with existing shields made of lead, and to find out their applicability through experiments. A 3D printer shield made of tungsten filament 1 mm, 2 mm, 4 mm shield, RNS-TX (nanotungsten) 1.1 mm, lead 0.2 mmPb, and 1mmPb were exposed to ^99mTc, ¹⁸F, and ²⁰¹TI for 15, 30, 45 minutes, and 60 minutes after measuring cumulative dose three times. Based on this, the shielding rate of each shield was calculated based on the dose in the absence of the shield. In addition, ^99mTc, ¹⁸F, and ²⁰¹TI were located 100 cm away from the phantom in which the OSLD nano Dot device was inserted, and if there was no shield for 60 minutes, the dose of thyroid was measured using 1.0 mm of lead shield, 1.1 mm of RNS-TX shield, and 2 mm of tungsten shield made by 3D printer. The use of shields during radiation shielding emitted from open radiation sources all resulted in a reduction in dose. The radiation dose emitted from the radionuclides under the experiment was all reduced when the shield was used. This study has been confirmed that tungsten is a material that can replace lead due to its excellent performance and efficiency as shield, and that it even shows the possibility of manufacturing a customized shield using 3D printer.

• 한국건축시공학회지
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• 제24권2호
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• pp.215-226
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• 2024

본 연구에서는 초고분말 플라이 애시가 다량 치환된 자기감지형 그라우트의 성능을 검토하기 위하여 실험적 연구를 진행하였다. 또한 기존의 대표적인 산업부산물인 고로슬래그 미분말과 플라이 애시를 동일한 양으로 치환하여 굳지 않은 그라우트의 유동특성, 경화 그라우트에서 압축강도, 길이변화율, 전기적 특성을 평가하였다. 실험결과 초고분말 플라이 애시 치환시 소성점도가 크게 낮아져 유동성이 향상되었으며, 압축강도도 플레인보다 초기재령에서부터 높게 나타났다. 또한 전기적 특성에서도 FCR-Stress, FCR-Strain의 관계가 유사하게 나타났다.

• Advances in nano research
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• 제16권5호
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• pp.473-487
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• 2024

The current study employs the nonlocal Timoshenko beam (NTB) theory and von-Kármán's geometric nonlinearity to develop a non-classic beam model for evaluating the nonlinear free vibration of bi-directional functionally-graded (BFG) nanobeams. In order to avoid the stretching-bending coupling in the equations of motion, the problem is formulated based on the physical middle surface. The governing equations of motion and the relevant boundary conditions have been determined using Hamilton's principle, followed by discretization using the differential quadrature method (DQM). To determine the frequencies of nonlinear vibrations in the BFG nanobeams, a direct iterative algorithm is used for solving the discretized underlying equations. The model verification is conducted by making a comparison between the obtained results and benchmark results reported in prior studies. In the present work, the effects of amplitude ratio, nanobeam length, material distribution, nonlocality, and boundary conditions are examined on the nonlinear frequency of BFG nanobeams through a parametric study. As a main result, it is observed that the nonlinear vibration frequencies are greater than the linear vibration frequencies for the same amplitude of the nonlinear oscillator. The study finds that the difference between the dimensionless linear frequency and the nonlinear frequency is smaller for CC nanobeams compared to SS nanobeams, particularly within the α range of 0 to 1.5, where the impact of geometric nonlinearity on CC nanobeams can be disregarded. Furthermore, the nonlinear frequency ratio exhibits an increasing trend as the parameter µ is incremented, with a diminishing dependency on nanobeam length (L). Additionally, it is established that as the nanobeam length increases, a critical point is reached at which a sharp rise in the nonlinear frequency ratio occurs, particularly within the nanobeam length range of 10 nm to 30 nm. These findings collectively contribute to a comprehensive understanding of the nonlinear vibration behavior of BFG nanobeams in relation to various parameters.

• Advances in nano research
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• 제16권3호
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• pp.217-229
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• 2024

This paper presents results of visual analysis of cracks formation and propagation of concretes made of quaternary binders (QBC). A composition of the two most commonly used mineral additives, i.e. fly ash (FA) and silica fume (SF) in combination with nanosilica (nS), has been proposed as a partial replacement of the cement. The principal objective of the present study is to achieve information about the effect of simultaneous incorporation of three pozzolans as partial replacement to the OPC on the fracture processes in concretes made from quaternary binders (QBC). The modern and precise non-contact measurement method (NCMM) via digital image correlation (DIC) technique was used, during the studies. In the course of experiments it was established that the substitution of OPC with three pozzolans including the nanoadditive in FA+SF+nS FA+SF+nS combination causes a clear change of brittleness and behavior during fractures in QBCs. It was found that the shape of cracks in unmodified concrete was quasi-linear. Substitution of the binder by SCMs resulted in a slight heterogeneity of the structure of the QBC, including only SF and nS, and clear heterogeneity for concretes with the FA additive. In addition, as content of FA rises throughout each of QBC series, material becomes more ductile and shows less brittle failure. It means that an increase in the FA content in the concrete mix causes a significant change in fracture process in this composite in comparison to concrete with the addition of silica modifiers only.