• Bulletin of the Korean Chemical Society
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• v.33 no.9
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• pp.2949-2954
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• 2012

Nano ZnO with an average size of 8 nm was prepared by thermal decomposition of zinc oxalate at $450^{\circ}C$. A series of based composite polymer electrolyte PEO-$LiClO_4$ and nano ZnO as a filler have been synthesized using solution cast technique, with varying the filler ratio systematically. XRD, DSC and FTIR studies have been conducted to investigate the structure and interaction of different groups in the composite polymer electrolyte. Effect of nano ZnO ceramic filler concentration on the structure of composites and their electrical properties (DC-conductivity, AC-conductivity, dielectric constant, dielectric loss and impedance) at different frequencies and temperatures was studied. Melting temperature ($T_m$) of PEO decreased with the addition of both $LiClO_4$ salt and nano ZnO filler due to increasing the amorphous state of polymer. All composite samples showed an ionic conductivity. The maximum room temperature ionic conductivity is found for $(ZnO)_{0.5}(PEO)_{12}(LiClO_4)$ composite sample. All the results are correlated and discussed.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2009.11a
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• pp.249-249
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• 2009

we have studied that a effect depending on dielectric properties of epoxy resin mixing filler nano/micro. When compare with nano/micro composite and virgin, the nano/micro composite is better than virgin. A specimen mixing nano/micro is changed as temperate, however the width of change is low.

• Advances in nano research
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• v.7 no.6
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• pp.419-429
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• 2019

The effect of an increasing percentage of nanofiller (glass cenosphere) with Glass/Epoxy hybrid composite curved panels modeled mathematically using the multiscale concept and subsequent numerical eigenvalues of different geometrical configurations (cylindrical, spherical, elliptical, hyperboloid and flat) predicted in this research article. The numerical model of Glass/Epoxy/Cenosphere is derived using the higher-order polynomial type of kinematic theory in association with isoparametric finite element technique. The multiscale mathematical model utilized for the customized computer code for the evaluation of the frequency data. The numerical model validation and consistency verified with experimental frequency data and convergence test including the experimental elastic properties. The experimental frequencies of the multiscale nano filler-reinforced composite are recorded through the impact hammer frequency test rig including CDAQ-9178 (National Instruments) and LABVIEW virtual programming. Finally, the nano cenosphere filler percentage and different design associated geometrical parameters on the natural frequency data of hybrid composite structural configurations are illustrated through a series of numerical examples.

• Journal of Electrical Engineering and Technology
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• v.9 no.3
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• pp.978-983
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• 2014

The polymer nano composite possess good priority recently for engineering applications. Especially the electrical insulating materials attract the high performance of nano composites. In this work the ballmill synthesiation process of nano sized Alumina ($Al_2O_3$), the preparation of new nano composite material with an content of enamel and synthesized Alumina as 1wt%, 3wt% and 5wt%. Experimental investigation has been carried out for the prepared nano composites materials with respect to dielectric parameter measurements such as dielectric loss (tan ${\delta}$), dielectric constant (${\varepsilon}$), dielectric strength under various temperature. The partial discharge level also measured for all the samples and the PD inception voltage is also observed and compared. Weight loss of the material has been analyzed through TGA. It has been experimentally proved that 3wt% of Alumina nano filler added enamel has significant improvement in the dielectric and thermal properties.

• Journal of the Korean Electrochemical Society
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• v.11 no.3
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• pp.190-196
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• 2008

The multilayered membrane for lithium rechargeable batteries based on poly (vinylidene fluoride) (PVdF) is prepared with the coated layer containing nano-sized filler. The prepared membranes were subjected to studies of mechanical strength, morphology, interfacial stability, impedance spectroscopy, ionic conductivity, and cycle performance. The localized inorganic filler in the PVdF composite membrane rendered mechanical strength much reduced because of its low stretching ratio and it results in around half value of the mechanical strength of highly stretched PVdF membrane. In order to achieve high ionic conductivity and interfacial stability without sacrificing high mechanical strength, coating layer with nano-filler was newly introduced to PVdF membrane. The ionic conductivity of the coated membrane was 1.03 mS/cm, and the interface between the coating layer and PVdF membrane was stable when the membrane was immersed into liquid electrolyte. The discharge capacity of the cell based on nano-filler coated PVdF membrane was around 91% of the initial discharge capacity after 250 cycles, which is an improvement in cycle performance compared to the case for the non-coated PVdF membrane.

• Journal of the Society of Disaster Information
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• v.11 no.2
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• pp.235-243
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• 2015

The methods to improve the protection and explosion-proof performance of concrete structures include the backside reinforcement or concrete material property improvement and the addition of structural members or supports to increase the resistance performance, but they are inefficient in terms of economics and structural characteristics. This study is about the basic study on the fiber composite panel cover, and the nano-composite material and adhesive as the filler, to maximize the specific performance of each layer and the protection and explosion-proof performance as the composite panel component by improving the tensile strength, light weight, adhesion and fire-proof performances. The fiber composite panel cover (aramid-polyester ratios of 6:4 and 6.5:3.5) had a 2,348 MPa maximum tensile strength and a 1.8% maximum elongation. The filler that contained the nano-composite material and adhesive had a 4 MPa maximum tensile shear adhesive strength. In addition, the nano-composite filler was 30% lighter than the normal portland cement

• Journal of the Korean Ceramic Society
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• v.49 no.6
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• pp.549-555
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• 2012

Silicon carbide(SiC) exhibits many unique properties, such as high strength, corrosion resistance, and high temperature stability. In this study, a SiC-fiber web was prepared from polycarbosilane(PCS) solution by employing the electrospinning process. Then, the SiC-fiber web was pyrolyzed at $1800^{\circ}C$ in argon atmosphere after it was subjected to a thermal curing. The SiC-fiber web (ground web)/phenolic resin (resol) composite was fabricated by hot pressing after mixing the SiC-fiber web and the phenolic resin. The SiC-fiber web composition was controlled by changing the fraction of filler (filler/binder = 9:1, 8:2, 7:3, 6:4, 5:5). Thermal conductivity measurement indicates that at the filler content of 60%, the thermal conductivity was highest, at 6.6 W/mK, due to the resulting structure formed by the filler and binder being closed-packed. Finally, the microstructure of the composites of SiC-fiber web/resin was investigated by FE-SEM, EDS, and XRD.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2009.11a
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• pp.150-150
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• 2009

In this paper, various kinds of epoxy based nanocomposites were made and AC breakdown properties of nano-$TiO_2$ and micro-silica filler mixture of epoxy based composites were studied by sphere to sphere electrode. Moreover, nano- and micro-filler combinations were adopted as an approach toward practical application of nanocomposite insulating materials. AC breakdown test was performed at room temperature $(25^{\circ}C)$, $80^{\circ}C$ and $100^{\circ}C$. The result shows breakdown strength about non-filled, nano-scale $TiO_2$, micro-scale silica and nano-$TiO_2$, micro-silica filled epoxy composites.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2008.04c
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• pp.73-74
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• 2008

In this paper, we have investigated dispersibility, volume resistivity of nano-composite by solution mixing method. Dispersibility measured by FE-SEM(Field Emission Scanning Electron Microscope. And volume resistivity measured by ASTM D991. To expect interaction used dual filler system. But, dual filler system had influence on polymer complex. So, polymer chain mobility doesn't resist.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.67 no.9
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• pp.1181-1188
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• 2018

In order to develop new insulating materials for GIS Spacer using environmentally friendly insulating gas, three kinds of dispersed liquid nano composites of solid epoxy /nano layered silicate filled material were prepared. And the epoxy/nano/micro silica composite was prepared by mixing epoxy/nano 3 phr dispersion/4 kinds of filler contents(40,50,60, 70wt%). The electrical insulation breakdown strengths of the nano and nano/micro mixed composites were evaluated by using 8 kinds of samples including the original epoxy. The mechanical tensile strength of the epoxy / nano / micro silica composite were evaluated, also. The TEM was measured to evaluate the internal structure of nano/micro composites. As a result, it was confirmed that the layered silicate nano particles was exfoliated through the process of inserting epoxy resin between silicate layers and the layers. In addition, dispersion of nano / micro silica resulted in improvement of electrical insulation breakdown strength with increase of filling amount of dense tissue with nanoparticles inserted between microparticles. In addition, the tensile strength showed a similar tendency, and as the content of microsilica filler increased, the mechanical improvement was further increased.