• Title/Summary/Keyword: nano titanium dioxide

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Strength properties of Cement Mortar by the Nano admixture of dry process and wet process (건식 및 습식 나노 혼화재를 사용한 시멘트 모르타르의 강도 특성)

  • Kim, Yeon-Hee;Choi, Eung-Kyoo;Park, Jong-Keun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.12 no.3
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    • pp.1452-1457
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    • 2011
  • Strength properties of cement mortar was carried out silica fume(SF) and Titanium Dioxide($TIO_2$) by nano admixture of dry process and wet process. Experimental parameters were Nano admixture as the dry process and wet process 5, 10, 15 or 20%. As a result, strength properties of cement mortar by silica fume(SF) and Titanium Dioxide($TIO_2$) were similar and in a comparative experiment of the dry process and wet process Nano admixture using wet process Nano admixture showed a greater strength properties.

The determination of effect of TiO2 on dynamic behavior of scaled concrete structure by OMA

  • Tuhta, Sertac
    • Advances in nano research
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    • v.11 no.6
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    • pp.641-648
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    • 2021
  • In this article, the dynamic parameters (frequencies, mode shapes, damping ratios) of the scaled concrete structure and the dynamic parameters (frequencies, mode shapes, damping ratios) of the entire outer surface of titanium dioxide, 80 micron in thickness are compared using operational modal analysis method. Ambient excitation was provided from micro tremor ambient vibration data on ground level. Enhanced Frequency Domain Decomposition (EFDD) was used for the output only modal identification. From this study, a good correlation between mode shapes was found. Titanium dioxide applied to the entire outer surface of the scaled concrete structure has an average of 11.78% difference in frequency values and 10.15% in damping ratios, proving that nanomaterials can be used to increase rigidity in structures, in other words, for reinforcement. Another important result determined in the study was the observation of the adherence of titanium dioxide and similar nanomaterials mentioned in the introduction to concrete structure surfaces was at the highest level.

The determination of effect of TiO2 on dynamic behavior of scaled WPC warehouse by OMA

  • Tuhta, Sertac
    • Advances in nano research
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    • v.12 no.1
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    • pp.65-72
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    • 2022
  • The dynamic properties (frequencies, mode shapes, damping ratios) of the scaled WPC warehouse are compared using the operational modal analysis approach to the dynamic parameters (frequencies, mode shapes, damping ratios) of the full outer surface of titanium dioxide, 70 micron in thickness. Micro tremor ambient vibration data on ground level was used to provide ambient excitation. For the output-only modal identification, Enhanced Frequency Domain Decomposition (EFDD) was used. This study discovered a strong correlation between mode shapes. Titanium dioxide applied to the entire outer surface of the scaled WPC warehouse results in an average 14.05 percent difference in frequency values and 7.61 percent difference in damping ratios, demonstrating that nanomaterials can be used to increase rigidity in structures, or for reinforcement. Another significant finding in the study was the highest level of adherence of titanium dioxide and similar nanomaterials mentioned in the introduction to WPC structure surfaces.

Properties of Cement Mortar with Manganese Doped Titanium Dioxide Nano-Wires (망간 도핑 이산화티탄 나노와이어를 혼입한 시멘트 모르타르의 특성)

  • Lee, Jun-Cheol;Hou, Yao-Long
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.05a
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    • pp.323-324
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    • 2023
  • The properties of cement mortar mixed with manganese-doped titanium dioxide nanowires (TiO2(Mn)-NWs) were investigated in this study. The TiO2(Mn)-NWs were synthesized using solvo-thermal synthesis and electro-spinning techniques. The TiO2(Mn)-NWs at weights of 1%, 2%, and 3% of the cement were respectively mixed into the cement mortar. The results showed that as the amount of TiO2(Mn)-NWs increased, the flow value of the cement mortar was decreased and the setting time of cement mortar was accelerated. Moreover, as the amount of TiO2(Mn)-NWs increased, the compressive strength of cement mortar was increased and the efficiency of acetaldehyde removal was improved.

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Synthesis and Property of Titanium Dioxide Nanosol with a High Crystalline Characteristics (고결정성을 갖는 이산화티탄 나노 졸의 합성 및 특성)

  • Sim, Jae-Kyung;Park, Jong-Kwon;Cho, Jung-Eun;Jeong, Noh-Hee
    • Applied Chemistry for Engineering
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    • v.30 no.6
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    • pp.694-697
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    • 2019
  • In recent years, titanium dioxide powders were produced as nanoparticles or nanowires or nanotubes in one-dimensional structure, and mesoporous spheres in 3-D to improve their crystallinities, which were further used as photo-electrode materials and for preventing photo-aging. In this study, a nano sol composed of titanium dioxide exhibiting a high crystallinity was synthesized using n-alcohol as a solvent. The crystallinity of the nano sol was confirmed by FE-SEM, and XRD, while the UV blocking rate confirmed by UV-Vis spectrometry results. Changes in the crystallinity were investigated by varying the types of solvents such as butanol, propanol and ethanol. The synthesized particle sizes were from 200 to 250 nm, and the optical transmittance showed a high blocking rate in the UVB and UVA range. It is expected that a high transmittance at 550 nm wavelength can increase the photoelectric conversion efficiency of solar cells and the UV blocking efficiency.

Fabrication of ZnO and TiO2 Nanocomposite Fibers and Their Photocatalytic Decomposition of Harmful Gases (ZnO와 TiO2 함유 복합나노섬유의 제조와 유해물질분해 성능 평가)

  • Hur, Yoon-Sun;Lee, Seung-Sin
    • Journal of the Korean Society of Clothing and Textiles
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    • v.35 no.11
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    • pp.1297-1308
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    • 2011
  • This research investigates the application of ZnO (zinc oxide) nanoparticles and $TiO_2$ (titanium dioxide) nanoparticles to polypropylene nonwoven fabrics via an electrospinning technique for the development of textile materials that can decompose harmful gases. To fabricate uniform ZnO nanocomposite fibers, two types of ZnO nanoparticles were applied. Colloidal $TiO_2$ nanoparticles were chosen to fabricate $TiO_2$ nano- composite fibers. ZnO/poly(vinyl alcohol) (PVA) and $TiO_2$/PVA nanocomposite fibers were electrospun under a variety of conditions that include various feed rates, electric voltages, and capillary diameters. The morphology of electrospun nanocomposite fibers was examined with a field-emission scanning electron micro- scope and a transmission electron microscope. Decomposition efficiency of gaseous materials (formaldehyde, ammonia, toluene, benzene, nitrogen dioxide, sulfur dioxide) by nanocomposite fiber webs with 3wt% nano-particles (ZnO or $TiO_2$) and 7$g/m^2$ web area density was assessed. This study shows that ZnO nanoparticles in colloid were more suitable for fabricating nanocomposite fibers in which nanoparticles are evenly dispersed than in powder. A heat treatment was applied to water-soluble PVA nanofiber webs in order to stabilize the electrospun nanocomposite fibrous structure against dissolution in water. ZnO/PVA and $TiO_2$/PVA nanofiber webs exhibited a range of degradation efficiency for different types of gases. For nitrogen dioxide, the degradation efficiency was 92.2% for ZnO nanocomposite fiber web and 87% for $TiO_2$ nanocomposite fiber web after 20 hours of UV light irradiation. The results indicate that ZnO/PVA and $TiO_2$/PVA nano- composite fiber webs have possible uses in functional textiles that can decompose harmful gases.

Preparation of TiO2:Fe,V nanoparticles by flame spray pyrolysis and photocatalytic degradation of VOCs (화염분무열분해법을 이용한 TiO2:Fe,V 나노분말의 제조 및 VOCs 분해 특성)

  • Chang, Han Kwon;Jang, Hee Dong;Kim, Tae-Oh;Kim, Sun Kyung;Choi, Jin Hoon
    • Particle and aerosol research
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    • v.5 no.1
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    • pp.1-7
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    • 2009
  • Fe- and V-doped titanium dioxide nanoparticles consisting of spherical primary nanoparticles were synthesized from a mixed liquid precursor by using the flame spray pyrolysis. The effects of dopant concentration on the powder properties such as morphology, crystal structure, and light adsorption were analyzed by TEM, XRD, and UV-Vis spectrophotometer, respectively. As the V/Ti molar ratio increased, pure anatase particles were synthesized. On the contrary, rutile phase particles were synthesized as the Fe/Ti ratio increased. Photocatalytic property of as-prepared $TiO_2:Fe,V$ nanoparticles was investigated by measuring the removal efficiency for volatile organic compounds (VOCs) under the irradiation of visible light. After 2 hrs under visible light, the removal efficiencies of benzene, p-xylene, ethylbenzene, and toluene were reached to 21.9%, 21.4%, 19.8% and 17.6% respectively.

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Preparation of blocking ultraviolet mica composites using Nano-TiO2 (Nano-TiO2를 이용한 자외선차단 마이카 복합체 제조)

  • Yun, Ki Hoon;Lee, Jaebok;Moon, Young-Jin;Go, Hee Kyoung;Lee, Yi;Lee, Dong-Kyu
    • Journal of the Korean Applied Science and Technology
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    • v.35 no.4
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    • pp.1197-1205
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    • 2018
  • UV protection cosmetics belong to functional cosmetics and contain organic or inorganic UV blocking pigments. The inorganic UV blocking pigments are mainly zinc oxide and titanium dioxide. It is known that inorganic UV blocking pigment has a diameter of 60 to 100 nm and has good blocking ability of UVA and UVB. Also, it has high inactivity against sunlight including UV and is excellent in safety. In addition, it is not absorbed or accumulated on the skin like organic pigments and does not cause skin irritation or allergy. In this study, mica, a plate-shaped inorganic pigment, nanosized titanium dioxide, an UV blocking material, and hydrophobic silica were surface-treated with surfactants. And then, titanium dioxide nanoparticles and silica were physically adsorbed on the mica by non-chemical mutual attraction due to differences in charge. Thereafter, the mica complex was surface-treated with silane to prepare a hydrophobic UV blocking pigment complex. The plate-shaped UV blocking composite improves the cohesiveness of a general nanoparticle material titanium dioxide, enhances UV blocking effect due to uniform dispersion, and can greatly improve dispersion stability in cosmetic formulations by surface treatment with hydrophobic property. The surface charge of the pigment was evaluated by zeta potential. The properties of the UV blocking pigment complex were evaluated by FE-SEM, XRD, FT-IR and UV-VIS.