• Title/Summary/Keyword: nActivated Carbon

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High-energy-density activated carbon electrode for organic electric-double-layer-capacitor using carbonized petroleum pitch

  • Choi, Poo Reum;Kim, Sang-Gil;Jung, Ji Chul;Kim, Myung-Soo
    • Carbon letters
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    • v.22
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    • pp.70-80
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    • 2017
  • Activated carbons (ACs) have been used as electrode materials of electric double-layer capacitors (EDLC) due to their high specific surface areas (SSA), stability, and ecological advantages. In order to make high-energy-density ACs for EDLC, petroleum pitch (PP) pre-carbonized at $500-1000^{\circ}C$ in $N_2$ gas for 1 h was used as the electrode material of the EDLC after KOH activation. As the pre-carbonization temperature increased, the SSA, pore volume and gravimetric capacitance tended to decrease, but the crystallinity and electrode density tended to increase, showing a maximum volumetric capacitance at a medium carbonization temperature. Therefore, it was possible to control the crystalline structure, SSA, and pore structure of AC by changing the pre-carbonization temperature. Because the electrode density increased with increasing of the pre-carbonization temperature, the highest volumetric capacitance of 28.4 F/cc was obtained from the PP pre-carbonized at $700^{\circ}C$, exhibiting a value over 150% of that of a commercial AC (MSP-20) for EDLC. Electrochemical activation was observed from the electrodes of PP as they were pre-carbonized at high temperatures above $700^{\circ}C$ and then activated by KOH. This process was found to have a significant effect on the specific capacitance and it was demonstrated that the higher charging voltage of EDLC was, the greater the electrochemical activation effect was.

Evaluation of Improvement on Sediment for Practical Application in Prawn Farm (새우 양식장에 적용을 위한 저질개선 평가)

  • Kim Woo-Hang;Kim Doo Hee
    • Proceedings of KOSOMES biannual meeting
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    • 2004.05b
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    • pp.81-84
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    • 2004
  • Control of Sediment is very important in prawn farm due to the eruption of toxic material such as W1ionized H2S, NH3 and NO2-. In this study, column test study, column with filter media such as activated carbon, zeolite, oyster shell and iron chloride to evaluate the reduction of toxicity from sediment ammonia-N(NH3) was effectively removed by Zeolite and oyster shell. It was indicated that ammonium ion(NH4+) was removed by ion exchange of zeolite. And the ammonia in the column of oyster shell was existed as the form of NH4+, which is not toxic for prawn because oyster shell was stably kept around pH 8. Therefore, some of ammonia(NH3) was reduced by oyster shell. Hydrogen sulfide and COD were effectively removed by adsorption of activated carbon and a partial removal of hydrogen sulfide was accomplished by Oyster shell. Phosphorous was removed by activated carbon, oyster shell and iron chloride. In prawn farm, the concentration of ammonia was increased with increase of pH by algae photosynthesis in the column of activated carbon, zeolite and iron chloride, but it was revealed that pH was stably kept in the column of oyster shell.

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Effects of Phytohormone and Activated Carbon on the Growth and Rooting of Teratoma Shoot Induced from Crown Gall Callus in Nicotiana tabacum cv. NC 2326 (연초 Crown Gall Callus유래 Teratoma Shoot의 생육과 발근에 미치는 식물호르몬과 활성탄의 영향)

  • Yang, Deok-Chun;Kang, C.K.;Choi, K.T.
    • Journal of the Korean Society of Tobacco Science
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    • v.14 no.1
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    • pp.33-41
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    • 1992
  • These studies were conducted to investigate effects of phytohormone and activated carbon on the growth and rooting of teratoma shoots induced from Nicotiana tabacum cv. NC2326 transformed by Aerobacterium tumefaciens C58. GA was effective for shoot elongation and reduction of multiple shoots from teratoma shoot, however, leaves of teratoma shoot cultured on the medium with GA were pointed. ABA was also effective in promoting shoot elongation, but was not for reduction of multiple shoots. Teratoma shoot cultured on the medium with 1 n activated carbon promoted shoot elongation and inhibited the number of shoots differentiated, but was grown as abnormal shoot. Addition of 1% activated carbon and 0.5mg/l BA to culture media was effective for shoot elongation and reduction of multiple shoot and for formation of round leaves as normal leaves. Though these shoots were inoculated on the rooting medium, they could not from roots but formed multiple shoots. Boric acid, myo-inositol and sucrose were also ineffective on the rooting of teratoma shoots.

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A Study on the Decomposition Characteristics of CFC-113 by Activated Carbon (활성탄 촉매를 이용한 CFC-113의 분해특성에 관한 연구)

  • 이우근;정주영;김진범
    • Journal of Korean Society for Atmospheric Environment
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    • v.13 no.4
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    • pp.319-325
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    • 1997
  • The catalytic decomposition of CFC-113(1,1,2-trichloro-1,2,2-trifluoroethane) was studied over an activated carbon catalyst in a fixed-bed reactor at the temperature from 300 to 600$^\circ$C, the space velocity (SV) of 1800 $\sim 14400h^{-1}$ and the mole ratio(decomposition agent/CFC-113) of 0.25 $\sim$ 5. In the absence of a decomposition agent, the decomposition efficiency of CFC-113 was low but when a decomposition agent was added to the gas stream, it was dramatically increased with the increase of temperature. In particular, in the presence of n-hexane as the decomposition agent it showed a high decomposition efficiency compared with benzene at 400$^\circ$C. It was found that the decomposition activity of CFC-113 was very sensitive to reaction temperature. Thus it is expected that to raise the reaction temperature is more effective than to increase the residence time and the amount of decomposition agent. Over the activated carbon catalyst more than 99% decomposition was achieved at the reaction temperature of 600$^\circ$C, SV of 7200$h^{-1}$, the mole ration $(C_6H_{14}/CFC-113)$ of 1 in this study.

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Application of Particle Counter in Water Treatment Process (정수처리공정에서의 입자분석 적용방안)

  • Shin, Sang-Hee;Jeon, Hyun-Sook;Lee, Chan-Hyung;Bae, Gi-Soo
    • Journal of Korean Society on Water Environment
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    • v.29 no.3
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    • pp.337-342
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    • 2013
  • The particle counter compared with the turbidimeter provides good precision and sensitivity and can get the characteristics of particulates effectively. The purpose of this study is to provide the application of particle counter in sand and activated carbon filters. The particle count by size could be more easily sense when the water quality is changed by the influent of high turbidity or algae. We could decide the optimal backwashing cycles and detect the efficiencies of filters by monitoring the total particle count of effluent in sand and activated carbon filters.

The Effect of Some Amendments to Reduce Ammonia during Pig Manure Composting (몇 가지 처리제의 첨가에 의한 돈분의 퇴비화 과정 중 암모니아 발생 저감 효과)

  • Joo, Jin-Ho;Kim, Dae-Hoon;Yoo, Jae-Hong;Ok, Yong-Sik
    • Korean Journal of Soil Science and Fertilizer
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    • v.40 no.4
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    • pp.269-273
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    • 2007
  • Occurrence of malodor could cause adverse impacts on human health and increase public interest. Therefore, scientific methods to decrease odor is required. Endeavor to decrease odor from compost however has not fully been successful. The purpose of this research is assessment of some amendments to reduce $NH_3$ from immature composts. Calcium hydroxide was applied to composts due to it's characteristics to increase pH. Activated carbon and zerovalent iron (ZVI) were selected because of their adsorption properties. The research results were as follows: Calcium hydroxide, activated carbon, zerovalent iron increased the composting temperature above $60^{\circ}C$. The addition of calcium hydroxide, activated carbon, and ZVI to compastry process increased pH 8.6 - 8.8 from $1^{st}$ day to $14^{th}$ day. During the 14 days of composting, addition of calcium hydroxide, activated carbon and ZVI changed EC from $2.15-0.66dS\;m^{-1}$, $1.48-1.11dS\;m^{-1}$, respectively and $1.77-0.68dS\;m^{-1}$. The difference in EC of the compost was due to irregularities of samples. Organic matter in the compost decreased through out theexcept control. The $NH_4-N/NO_3-N$ ratio of all experimental compost increased through the process. The addition of activated carbon, calcium hydroxide and ZVI decreased $NH_3$ from 0.1ppm, 0.7ppm and 1.7ppm more than the control (pig manure and sawdust), 9.3ppm, in 30 days of composting. In conclusion, odor from prematured compost decreased by addition of chemicals like calcium hydroxide, activated carbon, zerovalent iron. Moreover, use of these $NH_3$ reducers alone or together combined at different periods of composting etc. could decrease $NH_3$.

Denitrification of Wastewater in a Fluidized Bed Biofilm Reactor (유동층 생물막 반응기에서의 폐수 탈질화)

  • 신승훈;서일순;장인용
    • KSBB Journal
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    • v.16 no.4
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    • pp.337-343
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    • 2001
  • Activated carbon particles of 1.274 mm diameter and sand particles of 0.455 mm diameter were employed as the support of the biofilm formed in fluidized bed biofilm reactors(FBBRs) for the wastewater denitrification. Ethanol was used as the electron donor in the anoxic respiration. The steady-state biofilm thickness increased as the nitrate loading rate increased, and the activated carbon particles induced thicker biofilm than the sand particles. The FBBRs with sand support showed higher efficiency and rate of the nitrate removal than those with activated carbon support, and exhibited the biomass concentration of 37 kg/㎥ and the nitrate removal rate of 21 kg N/㎥d.

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Removal of Pesticide (Oxamyl) from Water using Activated Carbons Developed from Apricot Stones

  • El-Nabarawy, Th.;Sayed Ahmed, S.A.;Youssef, A.M.
    • Carbon letters
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    • v.8 no.4
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    • pp.299-306
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    • 2007
  • Four stream- activated carbons were prepared by carbonizing apricot stones at $600^{\circ}C$ followed by gasification with steam at $950^{\circ}C$ to burn-off's=17, 32, 49 and 65%. The textural parameters of these activated carbons were determined from nitrogen adsorption results at 77 K. The total pore volume and the mean pore radius increased with the increase of % burn-off whereas the surface area increased with the increase of burn- off from 17 to 32 and further to 49%. Further increase of burn-off to 65% was associated with a considerable decrease in surface area as a result of pronounced pore widening due to pore erosion. The surface pH values of the carbons investigated range between 7.1 and 8.2. The adsorption of oxamyl onto the activated carbon followed pseudo-second order kinetics and the equilibrium adsorption isotherms fitted Langmuir adsorption model. The adsorption of oxamyl proved to be of the physical type and took place in non-micropores. The amount of oxamyl adsorbed expressed as $q_m$ depends to a large extent to the surface area located in non-micropores $S^{\propto}\;_n$, where a straight line relationship passing through the origin was obtained.

Micro-Structural and Electrochemical Properties of Activated Carbon Synthesized from Natural Bamboo (천연 대나무로부터 합성된 활성 탄소의 미세구조 및 전기화학적 특성)

  • YANG, DONG-CHEOL;KIM, SU-WON;CHOURASHIYA, M.G.;PARK, CHOONG-NYEON;PARK, CHAN-JIN
    • Journal of Hydrogen and New Energy
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    • v.30 no.5
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    • pp.418-427
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    • 2019
  • Activated carbon was synthesized from bamboo charcoal by KOH activation at various temperatures for electrochemical double layer capacitor applications. The micro-structural and surface properties of all the samples were characterized by X-ray diffraction, scanning electron microscopy and N2 adsorption/desorption isotherm method. The electrochemical properties of the activated bamboo charcoal were examined by cyclic voltammetry in the potential window of -1.0 to 0.2 V in 6 M KOH electrolyte at different scan rates. An electrode made from the sample activated with 7.5 M KOH and heat treated at $750^{\circ}C$ for 3 h gave a maximum capacitance of 553 F/g at 1 mV/s and 450 F/g at 10mV/s.