• Transactions of the Korean Society of Mechanical Engineers B
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• v.34 no.12
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• pp.1035-1042
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• 2010

The thermal stratification effect has been thought as one of the way to avoid dramatically generating the heat from HCCI combustion. We investigate the effect of thermal stratification on HCCI combustion fueled by DME and n-Butane. The thermal stratification occurs in a combustion chamber of a rapid compression machine with premixture by buoyancy effect that is made of fuel and air. The premixture is then adiabatically compressed, and during the process, the in-cylinder gas pressure is measured and two-dimensional chemiluminescence images are prepared and analyzed. Under the thermal stratification, the LTR starting time and the HTR starting time are advanced than that of homogeneous case. Further, the LTR period and the luminosity duration under homogeneous conditions are shorter than the corresponding quantities under stratified conditions. Additionally, under stratified conditions, the brightest luminosity intensity is delayed longer than that of homogeneous condition.

• 한국신재생에너지학회:학술대회논문집
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• 2007.11a
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• pp.89-92
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• 2007

Partail oxidation(POX) of n-butane was investigated in this research by employing ceria-promoted Ni/calcium hydroxyapatite catalysts ($Ce_xNi_{2.5}Ca_{10}(OH)_2(PO_4)_6$ ; x = $0.1{\sim}0.3$) which had recently been reported to exhibit good catalytic performance in POX of methane and propane. The experiments were carried out with changing ceria content, $O_2/n-C_4H_{10}$ ratio and temperature. As the $O_2/n-C_4H_{10}$ feed ratio increased up to 2.75, n-$C_4H_{10}$ conversion and $H_2$ yield increased and the selectivity of methane and other hydrocarbons decreased. But with $O_2/n-C_4H_{10}$ = 3.0, $n-C_4H_{10}$ conversion and $H_2$ yield decreased. This is considered due to that too much oxygen may inhibit the reduction of Ni or induce the oxidation of Ni, which results in poor catalytic activity. The optimum $O_2/n-C_4H_{10}$ ratio lay between 2.50 and 2.75. $Ce_{0.1}Ni_{2.5}Ca_{10}(OH)_2(PO_4)_6$ showed the highest $n-C_4H_{10}$ conversion and $H-2$ yield on the whole. In durability tests, higher hydrogen yield and better catalyst stability were obtained with the $O_2/n-C_4H_{10}$ ratio of 2.75 than with the ratio of 2.5.

• Journal of the Korean Institute of Telematics and Electronics
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• v.25 no.4
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• pp.407-416
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• 1988

Thick film city gas sensors were fabricated using \ulcornerFe2O3 and \ulcorner-Fe2O3 as raw materials. Their electrical properties and sensitivity characteristics were investigated and the surface conditions for various firing temperatures were analyzed. The fabricated devices exhibited high sensitivity to butane gas(75~80% n 1, 000ppm butane ambient). Also they showed good selectivity and long-term stability. A city gas alarm system using fabricated sensors was made for the practical application.

• Journal of the Korean Society of Safety
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• v.31 no.3
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• pp.60-67
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• 2016

The gas leak and explosion accident is able to give a fatal injury to nearby people from the explosion center and interest in effect of the explosion on the human body is increased. Accidents by Portable Butane Gas Range of a gas explosion accident occupy the most share. As a result, the injury on the human body frequently occur. However, It is situation that are experiencing difficulties in consequence analysis of explosion accidents owing to shortage of explosion power data and lack of research on the effect of the human body by the gas explosion. This paper acquire human injury data by performing the actual explosion experiment with Portable Butane Gas Range and evaluate power by explosion and effect of explosion on the human body to perform explosion simulation with LS-DYNA program. It is intended to contribute to the exact cause of the accident investigation and the same type of accident prevention.

• Journal of the Korean Institute of Gas
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• v.4 no.3 s.11
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• pp.46-52
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• 2000

In order to evaluate the risk assessment of Fireball, a program, FIRESTOR, was developed. With this program, thermal fluxes due to the fireball of propane and n-butane were predicted to analyze the damage of Puchen gas explosion accident and thermal fluxes compared with the BLEVE ESTIMATOR, and commercial program SAFER Dupont Co. Thermal fluxes with variation of distance from the explosion source by BLEVE ESTIMATOR, SAFER and FIRESTOR was made a comparative analysis each other for the constant pressure of propane and n-butane. The values calculated by FIRESTOR were between those by BLEVE ESTIMATOR and SAFER. Consequently FIRESTOR is proved to be an good program to analyze the damage of Fireball.

• International Journal of Automotive Technology
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• v.7 no.3
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• pp.251-259
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• 2006

For practical application on the HCCI engine, the solution of subjects, such as control of auto-ignition timing and avoidance of knocking, is indispensable. This study focused on the technique of controlling HCCI combustion appropriately, changing the mixture ratio of two kinds of fuel. Methane and DME/n-Butane were selected as fuels. The influences, which the mixing ratio of two fuels does to ignition timing, ignition temperature, rate of heat release and oxidation reaction process, were investigated by experiment with 4-stroke HCCI engine and numerical calculation with elementary reactions.

• Journal of Mechanical Science and Technology
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• v.16 no.8
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• pp.1127-1134
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• 2002

The effects of pressure and temperature on the autoignition of propane and n-butane blends were investigated using a rapid compression machine (RCM) , which is widely used to examine the autoignition characteristics. The RCM was designed to be capable of varying the compression ratio between 5 and 20 and minimize the vortex formation on the cylinder wall using a wedge-shaped crevice. The initial temperature and pressure of the compressed gas were varied in range of 720∼900 K and 1.6∼ 1.8 MPa, respectively, by adjusting the ratio of the specific heat of the mixture by altering the ratio of the non-reactive components (N$_2$, Ar) under a constant effective equivalence ratio (ø$\_$f/= 1.0) The gas temperature after the compression stroke could be obtained from the measured time-pressure record. The results showed a two-stage ignition delay and a Negative Temperature Coefficient (NTC) behavior which were the unique characteristic of the alkane series fuels. As the propane concentration in the blend were increased from 20% and 40% propane, the autoignition delay time increased by approximately 41 % and 55% at 750 K. Numerical reduced kinetic modeling was performed using the Shell model, which introduced some important chemical ideas, represented by the generic species. Several rate coefficients were calibrated based on the experimental results to establish an autoignition model of the propane and n-butane blends. These coefficients can be used to predict the autoignition characteristics in LPG fueled Sl engines.

• Journal of the Korean Applied Science and Technology
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• v.28 no.2
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• pp.140-145
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• 2011

Cationic gemini-surfactant, namely 1,4-butane-bis(N-alkanoyloxyethyl-N,Ndimethyl)-diammonium bromide was synthesized and their inhibition effect on corrosion of mild steel in 1 M HCl solution was tested by weight loss method. The synthesized product was confirmed by FT-IR and $^1H-NMR$ spectroscopy. Surface tensions were measured by surface tensiometer Sigma 70. Their c.m.c. values evaluated by surface tension method was $4.1{\times}10^{-5}{\sim}5.4{\times}10^{-5}$ mol/L. The Krafft point of the these surfactants were <0~$10.7^{\circ}C$. The emulsifying properties of synthesized cationic gemini surfactants and sodium dodecyl sulfate (SDS), tetradecyl trimethyl ammonium bromide (TTAB) was investigated. Of these, 1,4-butane-bis(N-lauroyloxyethyl-N,N-dimethyl)- diammonium bromide, CGL 14-4-14 has been confirmed as a good emulsifier. The inhibition efficiency increases by increasing cationic gemini surfactant concentration. As a result, these surfactants are expected to be applied as corrosion inhibitors.

• Proceedings of the Korea Association of Crystal Growth Conference
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• 1997.06a
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• pp.67-71
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• 1997

Activated carbons are the microporous carbonaceous adsorbents which are prepared from carbon-containing source materials such as wood, coal, lignite, peteroleum and sometimes synthetic high polymers. [1-2] Activated carbons shows an ability to adsorbe hydrocarbons of the gas phase. Activated carbons are used in the purification of many kinds of gas phases like hexane, benzene, toluene, gasoline, phenol etc.[3] In this study, cokes from bitminous coal were activated for the purpose of preparing the activated carbons by steam activation. The effect of the activation temperature, time, steam concentration and flow rate on the n-butane adsorption, burn off, surface area and average pore size of the activated carbons, were investigated. The adsorption characteristics of the activated carbons for gasoline are indirectly estimated by n-butane adsorption.

• Journal of the Korean Chemical Society
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• v.7 no.2
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• pp.128-132
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• 1963

A study has been made on the applicability of gas-liquid partition chromatography to the qualitative and quantitative analysis of complex mixture of gaseous hydrocarbons. While phthalate columns are widely used for this $purpose^9$, they separates neither saturated hydrocarbons from the unsaturated nor n-butane from isobutene or butene-1, therefore combined columns such as phthalate and dimethylsulfolane have been used for the perfect separation of gaseous hydrocarbons. It is shown by this study, however, that hydrocarbons having $C_1$ through $C_4$ can be separated with a 2-meters tetraethyleneglycol dimethylether column except ethane from ethylene, and trans-from cis-2-butene especially operated at $15^{\circ}C$$ using helium as the carrier gas. The column effluents were in order of methane, (ethane, ethylene), propane, propylene, isobutane, n-butane, isobutylene, butene-1, (trans-& cis-2-butene, isopentane), (butadiene-1, 3, n-pentane). Two kinds of liquified petroleum gases in market are analysed qualitatively and quantitatively. The results indicate that use of this 2-meters TEGDE column permits the separation and identification of all the commonly encountered aliphatic gaseous hydrocarbons.