• Title/Summary/Keyword: n-Paraffin

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Studies on the Pollutants from Petroleum (II) On the Normal-and Iso-paraffins Detected in the Fishes from the Near Sea of Korea (석유로부터 유래되는 오염물질에 관한 연구(II) 한국 연근해산 어류중 Normal- 및 Iso-paraffin 함량)

  • 하배진;박영현;이수환;황귀서
    • YAKHAK HOEJI
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    • v.28 no.1
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    • pp.11-16
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    • 1984
  • As main index of petroleum pollution in the marine organisms n-, iso-paraffins were purified with clean-up method and measured by FID-GC. Ten species of fishes from the near seas of Korea were employed for the study. n-Heptadecane was detected in most fishes. n-Hexadecane and n-octadecane of n-paraffins were highly accumulated in four species of fishes(Seriola quinqueradiata, Sardinia melamosticta, Clupanodon punctatus and Stromateoids argentus), also n-tetradecane and n-hexadecane accumulated in Cololadis saira. Remarkable peak pattern of n-paraffins was not observed in other fishes. Pristane of iso-paraffins was detected in four species of fishes (Sardinia melamosticta, Clupanodon punctatus, Stromateoides orgentus and Cololadis saira).

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CONTROL OF HARDNESS OF OIL-WAX GELS BY A NOVEL BRANCHED WAX AND APPLICATION TO LIPSTICKS

  • Yoshida, K.;Shibata, M.;Ito, Y.;Nakamura, G.;Hosokawa, H.
    • Proceedings of the SCSK Conference
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    • 2003.09a
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    • pp.469-479
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    • 2003
  • A novel branched wax has been developed for the control of the hardness of oil-wax gels. Using this wax, glossier application and smoother texture but tough lipstick can be obtained. Oil-wax gels are oily solids composed of liquid and crystalline solid oils (waxes). They are widely used in various cosmetic products, especially lipsticks. The control of gel hardness is one of the most important techniques in improvement of the lipstick quality. Addition of small amounts of commercial branched paraffin wax (e.g. microcrystalline wax, b-PW) to n-paraffin wax (n-PW) has been commonly used to increase gel hardness. However, gel hardness is very sensitive to the quantity of b-PW and the gel obtained is not always hard enough for practical use. In this study we examined the relationship between the gel hardness and the properties of the wax crystal in the gel. We have found that, when b-PW is added to n-PW, the wax crystal size becomes smaller (hardening the gels) and its crystallinity is decreased (softening the gels) simultaneously. Considering this result, we have developed a novel branched wax, Bis(polyethylenyl)- tetramethyldisiloxane (named ESE). ESE molecules are composed of a central tetramethyldisiloxane unit (branch unit) with polyethylene units at both ends. The central unit may suppress crystal growth while the ends are expected to prevent a decrease in wax crystallinity during crystallization. When ESE is added to n-PW, the wax crystal obtained becomes smaller without decreasing in crystallinity; consequently, the gel hardness is dramatically increased. By using ESE, the total amount of wax in a lipstick can be decreased by 30% without spoiling the stick toughness, thereby achieving glossy application and smooth texture.

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Inverse Emulsion Polymerization of Water Absorbent Polymer for Strength Enhancement of Mortars (모르타르 강도 증진을 위한 고분자 흡수제의 역유화 중합)

  • Hwang, Ki-Seob;Jung, Myoung-Geun;Jang, Seok-Soo;Jung, Yong-Wook;Lee, Seung-Han;Ha, Ki-Ryong
    • Polymer(Korea)
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    • v.34 no.5
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    • pp.434-441
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    • 2010
  • Sodium polyacrylate (PAANa) was synthesized by inverse emulsion polymerization method to absorb excess water in concrete. Liquid paraffin was used as a continuous phase. Acrylic acid (AA) was neutralized by aqueous sodium hydroxide solution (8 M). Different amount of N,N'-methylene bisacrylamide (MBA) was used as a crosslinking agent to change crosslinking density of the synthesized PAANa. The size distribution of synthesized particles was measured by particle size analyzer. Swelling ratio of crosslinked PAANa was evaluated from the equation in D. I. water, cement aqueous solution, and $Ca(OH)_2$ aqueous solution. The FTIR spectroscopy was used to characterize $Ca^{2+}$ ion interaction with PAANa. Incorporation of 1.0 wt% PAANa into cement increased compressive and flexural strength approximately 30% and 10%, respectively, compared with those of ordinary portland cement.

Thermal performance of the spherical capsule system using paraffin as the thermal storage material (파라핀 축열재를 사용한 구형캡슐 시스템의 전열성능)

  • Cho, K.N.;Choi, S.H.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.9 no.3
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    • pp.354-363
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    • 1997
  • The purpose of the present work is to show the best thermal storage material and the sensitivity of the parameters on the thermal performance by experimentally investigating the effects of the parameters on the thermal performance of the spherical capsule system using paraffins superior to the commercial one. The paraffins were n-Tetradecane and the mixture of n-Tetradecane 40% and n-Hexadecane 60%. The experimental parameters were the Reynolds number of 8, 12, and 16 and the inlet temperature of-7, -4, -1, and $2^{\circ}C$. The charging and the discharing time, the dimensionless thermal storage amount, and the averge heat transfer coefficient in the tank were obtained by utilizing the local temperature variation in the tank. The local charging and discharging time in the tank was axially and radially different a lot. The effects of the inlet temperature on the charging and the discharging time were larger during the charging process than during the discharging process, but the effects of the Reynolds number on the charging and the discharging time were in reverse order. The paraffins were better by 11~72% than the water with the inorganic material in the charging time aspect, but no difference in the discharging time aspect. The effects of the Reynolds number on the dimensionless thermal storage amount were smaller than the effects of the inlet temperature during the charging process, but in reverse order during the discharging process within the working range of the experimental parameters. The effects of the inlet temperature and the Reynolds number on the average heat transfer coefficient were larger during the discharging process than during the charging process. The average heat transfer coefficient for the paraffins was larger by 40% maximum than that for the commercial material during the charing and the discharging process.

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Emulsification of Bunker-C Oil by a Marine Bacterium Achromobacter sp. M-1220 (해양세균 Achromobacter sp. M-1220균주에 의한 Bunker-C 유의 유화)

  • 박중연;박인식;서근학;홍용기
    • Microbiology and Biotechnology Letters
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    • v.16 no.5
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    • pp.384-388
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    • 1988
  • A marine bacterium Achromobacter sp. M-1220 was isolated from enrichment culture for emulsification of Bunker-C oil. The bacterium can emulsify approximately 7.5g of Bunker-C oil per liter in sen water medium within 1 drys at 18$^{\circ}C$ and multiply from 8$\times$10$^5$ cells to 9$\times$10$^9$ cells per mi. Optimum pH and salt concentration were pH 7.5 and 3% for the emulsification of Bunker-C oil. Emulsification takes place actively in both high sulfur-containing Bunker-C oil and high sulfur-con-taming crude oil. The amount of emulsification depends on the exogenous addition of nitrogen and phosphate sources. The bacterium can also utilize n-hexndecane, n-paraffin me benzene among the petroleum compounds as a sole carbon source.

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Studies on the Production of Microbial Cell Protein from Hydrocarbon (탄화수소로부터 균체단백질의 생산에 관한 연구)

  • 정동효;박준희
    • Microbiology and Biotechnology Letters
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    • v.6 no.4
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    • pp.173-179
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    • 1978
  • 1) To study the productivity of single cell protein from the n-paraffin utilizing yeast, 235 yeast strains were isolatea from 90 samples 2) Optimum cell growth temperature of three strains selected was 40~45$^{\circ}C$ and these were identified as Candida tropicalis, Candida krusei and Torulopsis molischiana. 3) A-28 strain easily assimilated tetradecane, hexadecane and octadecane, but B-8 strain and C-15 strain assimilated more hexadecane than other n-paraffins. 4) Out of the selected three strains, the mass doubling time, specific growth rate and cell yield were 3.4~4.0 hours, 0.170~0.215, 86~98%, respectively. 5) Crude protein, fat, fiber, ash and nitrogen free extract of the selected three strains were found to be 48.2~61.2% 3.7~8.0%, 3.5~4.2%, 5.6~6.7%, 23.5~31.8%, respectively, and thiamine and riboflavin contents of dried yeast cell were 0.78~0.93 mg% and 6.03~7.3 mg%, respectively. 6) Yeast protein contained evenly most of amino acid, but the sulfur-containing amino acids were particularly low.

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Diagnosis of Neospora caninum Infection by PCR using Formalin-fixed, paraffin-embedded tissues

  • Lee, Jung-Keun;Kim, Jae-Hoon;Hwang, Woo-Suk;Lee, Byung-Chun;Park, Jae-Hoon;Kim, Dae-Yong
    • Proceedings of the Korean Society of Veterinary Pathology Conference
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    • 2000.09a
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    • pp.25-25
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    • 2000
  • N. caninum infections have been associated with neonatal paresis as well as abortion around the world. Bovine abortion induced by N. caninum was first reported in 1997 in Korea. Diagnosis of N. caninum infection is usually based on histopathology and immunohistochemical detection of organism. However, often the tissues having lesion suggestive of N. caninum infection were negative on immunohistochemistry. (omitted)

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Tansport Rate of Chromium ion from Waste Water through the Liquid Surfactant Membrane Containing Carrier (운반체 함침 유화액막에 의한 폐수중 크롬(VI)의 이동속도)

  • Woo, In-Sung;Kim, Kyoung-Ho;Lee, Sang-Jin;Kang, An-Soo;Choi, Sei-Young
    • Elastomers and Composites
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    • v.23 no.1
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    • pp.11-17
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    • 1988
  • The transport of chromium(VI) ion from waste water through the liquid surfactant membrane containing tri-n-octylamine as a carrier, was analyzed by a slab model and was investigated through experiments. For the experiment of membrane stability, concentrations of surfactant and liquid paraffin oil were analyzed. Extraction experiments were carried out to observe the effect of system variables, such as concentrations of carrier, and initial chromium(VI) ion in external aqueous phase at $25^{\circ}C$. It is concluded that the most stable formation of liquid membrane emulsion was obtained when surfactant concentration is above 3 wt.% and liquid paraffin oil concentration is 50 vol.%. The theoretical equation on the transport of chromium(VI) ion agreed well with the experimental results.

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Fundamental Study on the Chemical Ignition Delay Time of Diesel Surrogate Components (모사 디젤 화학반응 메커니즘의 각 성분이 화학적 점화 지연 시간에 미치는 영향에 관한 기초 연구)

  • Kim, Gyujin;Lee, Sangyul;Min, Kyoungdoug
    • Transactions of the Korean Society of Automotive Engineers
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    • v.21 no.3
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    • pp.74-81
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    • 2013
  • Due to its accuracy and efficiency, reduced kinetic mechanism of diesel surrogate is widely used as fuel model when applying 3-D diesel engine simulation. But for the well-developed prediction of diesel surrogate reduced kinetic mechanism, it is important to know some meaningful factors which affect to ignition delay time. Meanwhile, ignition delay time consists of two parts. One is the chemical ignition delay time related with the chemical reaction, and the other is the physical ignition delay time which is affected by physical behavior of the fuel droplet. Especially for chemical ignition delay time, chemical properties of each fuel were studied for a long time, but researches on their mixtures have not been done widely. So it is necessary to understand the chemical characteristics of their mixtures for more precise and detailed modeling of surrogate diesel oil. And it shows same ignition trend of paraffin mixture with those of single component, and shorter ignition delay at low/high initial temperature when mixing paraffin and toluene.

Changes in Facilitated Transport Behavior of Silver Polymer Electrolytes by UV Irradiation

  • Jongok Won;Yosang Yoon;Kang, Yong-Soo
    • Macromolecular Research
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    • v.10 no.2
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    • pp.80-84
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    • 2002
  • Silver species other than the silver ion were formed by UV irradiation on polymer electrolyte membranes containing silver salts and their effect on complexation behavior between the silver and olefin was investigated through the separation performance of olefin/paraffin mixtures. The ideal propylene/propane separation factor reached 350 and the separation coefficient was ca.15 due to the high loading amount of silver ions into poly(2-ethyl-2-oxazoline) (POZ) without UV irradiation. On UV irradiation either in air or under nitrogen, the silver-POZ membranes became yellow-brown initially due to the formation of colloidal silver particles, and finally black and metal-like luster. Even when Ag$^{+}$ was converted, to some extent, to Ag$^{\circ}$ by UV irradiation in air at the early stage, the separation coefficient of olefin/paraffin mixtures was maintained. This suggests that silver species other than the silver ion is active for olefin carrier for facilitated transport. Meanwhile the steady decrease of the separation coefficient was observed in the silver/POZ membranes irradiated under $N_2$. It is suggested that the reduction of silver ions in POZ goes through a different photoreduction mechanism with UV irradiation depending on the environment.t.