• 한국전기전자재료학회논문지
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• 제17권2호
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• pp.184-189
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• 2004

The effects of $Y_2$ $O_3$-substitution on the piezoelectric properties of Pb[(N $i_{1}$3/N $b_{2}$3/)$_{0.15}$(Z $r_{1}$2/ $Ti_{1}$2/)$_{0.85}$] $O_3$ceramics were investigated. It was found that $Y^{3+}$ ions incorporate into Pb-sites of the ceramics, resulting in a increased lattice anisotropy and formation of Pb-vacancies. As a result, an orthorhombic-tetragonal phase transition was induced when $\chi$>0.005. At the morphotropic phase boundary of x=0.005, piezoelectric constants( $k_{p}$, $k_{33}$, and $d_{33}$) showed maximum values of 0.53, 0.58, and 350pC/N, respectively. A 30-layer actuator fabricated with the above material showed a maximum strain of 0.12％ under 100V DC bias.

• 한국전기전자재료학회논문지
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• 제11권4호
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• pp.281-287
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• 1998

$BiNbO_4$ ceramics doped with 0.07wt% $V_2O_5$ and 0.03wt% CuO (BNC3V7) were sucessfully sintered at $900^{\circ}C$ through the firing process with Ag electrode. The BNC3V7 shows typically Dielectric constant of 44.3, Thermal Coefficient of resonance Frequency(TCF) of 2 ppm/$^{\circ} and $Qxf_o$ value of 22,000 GHz. The laminated chip Low Pass Filter (LPF) is very sensitive to chip processing parameters, was confirmed by the computer simulation as a function of Q(Quality factors), filter size, capacitor layer thickness, inductor pattern widths. The multilayer type LPF was fabricated by screen-printing with Ag electrode after tape casting and then compared with the simulated characteristics. The results show that characterization of band pass width was similar to that of designed ones.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2004년도 하계학술대회 논문집 Vol.5 No.2
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• pp.615-618
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• 2004

The piezoelectricity and polarization of multilayer ceramic actuators, being designed to stack ceramic layer and electrode layer alternately, were investigated under a consideration of geometry, the thickness ratio of the ceramic layer to electrode layer The actuators were fabricated by tape-casting of $0.42PbTiO_3-0.38PbZrO_3-0.2Pb(Mn_{1/3}Nb_{2/3})O_3$ followed by laminating, burn-out and co-firing process. The actuators of $5\times5mm^2$ in area were formed in a way that $60{\sim}200{\mu}m$ thick ceramics were stacked 10 times alternately with $5{\mu}m$ thick electrode. Increase in polarization and electric field-displacement with increasing thickness ratio of the ceramic/electrode layer and thickness/cross section ratio were attributed to the change of $non-180^{\circ}/180^{\circ}$ domain ratio which was affected by the interlayer internal stress and Poisson ratio of ceramic layer. The piezoelectricity and actuation behaviors were found to be dependent upon the volume ratio (or thickness ratio) of ceramic layer relative to ceramic layer. Concerning with the existence of internal stress, the field-induced polarization and deformation were described in the multilayer actuator.

• 마이크로전자및패키징학회지
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• 제13권1호통권38호
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• pp.31-35
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• 2006

본 논문에서는 전력용 반도체 스위칭 소자인 SCR(Silicon Controlled Rectifier)과 적층형 PTC 서미스터의 전기적 특성을 이용하여 각종 전기화재 및 전기사고를 예방 보호하는 제어시스템에 대해 연구된다. PTC(Positive Temperature Coefficient) 서미스터는 온도변화에 따른 저항특성이 정(+)온도계수를 갖는 특징이 있다. 이 PTC는 정온도계수를 갖는 $BaTiO_3$계 세라믹스의 정방정계-입방정계 구조를 가지고 상변이점인 큐리(Curie)온도 이상으로 온도가 증가하면 저항이 급격히 증가하는 현상을 보인다. 본 논문에서는 이러한 정저항 온도특성과 자체 발열특성을 갖는 적층형 PTC 서미스터를 전기단락사고나 과부하사고 등의 전기사고의 감지센서로 이용하여 전기화재사고로부터 보호하는 제어시스템에 대해 제안한다. 또한 제안된 보호제어시스템의 다양한 실험결과를 통해 이론적 해석의 타당성을 입증시킨다.

• 한국결정성장학회지
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• 제29권6호
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• pp.283-293
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• 2019

우주공간, 고에너지 플라즈마, 방사선 조사 환경과 같은 극한환경에서의 응용 분야가 증가함에 따라 더 높은 용융점 및 기계적 강도, 열전도도의 향상을 필요로 하는 재료에 대한 수요가 계속적으로 증가하고 있다. 이에 따라 대표적인 내열 소재인 탄소-탄소 복합체의 내산화/내삭마 특성을 개선하기 위하여 초고온 세라믹스를 이용하는 방법에 대하여 리뷰하였다. 초고온 세라믹스를 합성하는 가장 간단한 방법인 CVD 코팅법과 다른 코팅법인 pack cementation, 용사법의 장단점을 서로 비교하였다. 복잡한 형상의 C/C 복합체에 CVD 코팅법을 적용하기 위한 방법으로 열역학 계산 및 CFD 시뮬레이션의 활용 가능성을 제안하였다. 또한 이런 방법을 통하여 제작한 TaC/SiC 이중 층 코팅과 TaC/SiC 다중 층 코팅의 내산화 특성을 비교한 결과, 다중 층 코팅을 적용하였을 때 더 뛰어난 내산화성을 보이는 것을 확인하였다.

• Journal of Electrical Engineering and Technology
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• 제6권2호
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• pp.263-269
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• 2011

In this study, the compositions for the microwave dielectric materials were investigated to obtain the improved dielectric properties, the high temperature stability, and the sintering temperature of less than $900^{\circ}C$, which was necessary for cofiring with the internal conductor of silver. In addition, the dielectric sheets were prepared by the tape casting technique, after which the sheets were laminated and sintered. In this process, the optimum ratio of powder and binder, laminating pressure, temperature, and possibility for cofiring with the internal conductor were studied. Finally, multilayer chip treplexer filter for the 800-2,000 MHz range were fabricated, and the frequency characteristics of the triplexer filter were investigated. When the $0.6TiTe_3O_8-0.4MgTiO_3+3wt%SnO+7wt%H_3BO_3$ ceramics were sintered at $820^{\circ}C$ for 0.3 hours, the microwave dielectric properties of the dielectric constant of 29.91, quality factor of 33,000 GHz, and temperature coefficient of resonant frequency of -2.76 ppm/$^{\circ}C$ were obtained. Using the Advanced Design System (ADS) and High Frequency Structure Simulator (HFSS), the multilayer chip triplexer filter acting at the range of 800-2,000 MHz were simulated and manufactured. The manufactured triplexer filter had the excellent frequency properties in the CDAM800, GPS and PCS frequency regions, respectively.

• 한국통신학회논문지
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• 제23권4호
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• pp.988-996
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• 1998

BN 세라믹에 소결조제로 0.07wt% $V_{2}O_{5}$ 와 0.03wt% CuO을 첨가 하였을 때(BNC3V7) Ag 전극과 동시 소성이 가능한 $900^{\circ}C$ 소결할 수 있었다. 이때 BNC3V7 시편은 유전상수 44.3 $Qxf_{o}$값 22,000 GHz, TCF 값 ppm$/^{\circ}C$의 유전특성을 얻을 수있었다. PCS대역에서 사용 가능한 적층칩 대역 필터를 기존의 방법과 태핑기법에 의한 2가지 방법으로 설계하였다. 입출력 태핑 기법을 이용하여 필터를 제조할 경우 입출력 커플링을 이용한 기존방법에 비해 layer를 감소시킬 수 있어 구조가 간단해진다는 장점이 있다. 적층칩 대역 필터는 Tape casting한 후 Ag전극을 이용하여 Screen printing하여 제작 하였다. 제작된 필터는 $900^{\circ}C$에서 소결하여 설계된 필터와 특성 값을 비교 하였다. 태핑된 칩 필터와 기존 칩 필터 모두 중심주파수는 90MHz 낮은 주파수 대역으로 이동 하였지만 대역 통과 특성은 설계 값과 유사 하였다. 태핑된 칩 필터의 스퓨리어스 특성은 기존 칩 필터에 비해 향상되었다.

• 한국전기전자재료학회논문지
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• 제27권6호
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• pp.372-376
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• 2014

We investigated the effect of excess CuO on the sintering behavior, ferroelectric, and piezoelectric properties of lead-free $Bi_{0.5}(Na_{0.82}K_{0.18})_{0.5}TiO_3$ (BNKT) ceramics. The addition of excess CuO was found to greatly contribute to the densification and grain growth, however, excess CuO over 3 mol% was precipitated at grain boundaries after sintering. BNKT with 1~2 mol% CuO in excess sintered at $975^{\circ}C$ showed piezoelectric properties comparable to those of unmodified BNKT sintered at $1,175^{\circ}C$. These results seem meaningful for its application to low cost multilayer actuators (MLAs) because low firing ceramics make it possible to apply less expensive base metals to the inner electrode of MLAs.

• 한국전기전자재료학회논문지
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• 제33권5호
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• pp.337-343
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• 2020

This study investigated the low temperature sintering with various templates of Bi-based lead-free piezoelectric ceramics. The effects of using CuO-coated Na_0.5Bi_4.5Ti₄O₁₅ templates on the sintering behavior as well as the dielectric, ferroelectric, and piezoelectric properties of Bi_1/2(Na_0.78K_0.22)_1/2TiO₃ (BNKT) ceramics have been examined. In comparison with the specimens sintered with the Na_0.5Bi_4.5Ti₄O₁₅ templates without CuO coating, those sintered with the CuO-coated Na_0.5Bi_4.5Ti₄O₁₅ templates showed larger template sizes as well as a larger electric field induced strain (S_max/E_max) of 422 pm/V after sintering at temperatures as low as 975℃. These results are promising for low-cost multilayer ceramic actuator applications.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2002년도 추계학술대회 논문집 Vol.15
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• pp.317-321
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• 2002

Piezoelectric properties of $(Pb_{1-x}Y_x)[(Ni_{1/3}Nb_{2/3})_{0.15}(Zr_{1/2}Ti_{1/2)})_{0.85}]O_{3}$ (x=0~0.05) ceramics were investigated, The stoichiometric PNN-PZT ceramics required the sintering temperature above $1100^{\circ}C$, but the addition of $Y_{2}O_{3}$ in the PNN-PZT ceramic lowered the sintering temperature down to $1000^{\circ}C$. In case of x=0.005, the electro-mechanical coupling $factor(K_p)$, the piezoelectric $constant(d_{33})$, and the maximum strain ratio of PNN-PZT ceramics sintered at $1000^{\circ}C$ were 53.1%, 395pC/N, and $2200{\times}10^{-6}$ respectively, A 30-layer piezoelectric actuator$(10{\times}10{\times}1.7mm)$ fabricated with the above material showed the maximum strain of $2.09{\mu}m$ under 100V DC bias.