• Title/Summary/Keyword: multifunctional properties

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Processing and properties of $Al_{2}O_{3}/SiC$ nanocomposites by polycarbosilane infiltration

  • Jung-Soo Ha;Chang-Sung Lim;Chang-Sam Kim
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.12 no.2
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    • pp.80-86
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    • 2002
  • $Al_{2}O_{3}/SiC$ nanocomposites were made by infiltrating partially sintered alumina bodies with polycarbosilane (PCS) solutions, which is a SiC polymer precursor, with pressureless sintering. The SiC content, densification, phases, strength, and microstructure were investigated with the processing parameters such as PCS solution concentration and heat treatment condition for PCS pyrolysis and sintering. The results were compared with those for pure alumina and nanocomposite samples made by the existing polymer precursor route (i.e. the PCS addition process). The SiC contents of up to 1.5 vol% were obtained by the PCS infiltration. PCS pyrolysis, followed by air heat treatment, was needed before sintering to avoid a cracking problem and to attain a densification as high as 98 % of theoretical. The nanocomposites exhibited significantly higher strength than pure alumina and those prepared by the PCS addition process despite larger grain size. Besides $\alpha-Al_{2}O_{3}/SiC$ and $\beta-SiC$ phases, mullite was present a little in the nanocomposites, which resulted from the reaction of $SiO_{2}$ in the pyrolysis product of PCS with the $Al_{2}O_{3}$ matrix during sintering. The nanocomposites had intagranular particles believed to be SiC, which is a typical feature of $Al_{2}O_{3}/SiC$ nanocomposites.

Mechanical Behaviors under Compression in Wire-woven Bulk Kagome Truss PCMs (II) - Effects of Geometric and Material Imperfections - (벌크형 와이어직조 카고메 트러스 PCM의 압축거동 (II) - 결함의 영향 -)

  • Hyun, Sang-Il;Choi, Ji-Eun;Kang, Ki-Ju
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.31 no.7 s.262
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    • pp.792-799
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    • 2007
  • A newly developed cellular metal based on kagome lattice is an ideal candidate for multifunctional materials achieving various optimal properties. Intensive efforts have been devoted to develop efficient techniques for mass production due to its wide potential applications. Since a variety of imperfections would be inevitably included in the realistic fabrication processes, it is highly important to examine the correlation between the imperfections and material strengths. Previous performance tests were mostly done by numerical simulations such as finite element method (FEM), but only for perfect structures without any imperfection. In this paper, we developed an efficient numerical framework using nonlinear random network analysis (RNA) to verify how the statistical imperfections (geometrical and material property) contribute to the performance of general truss structures. The numerical results for kagome truss structures are compared with experimental measurements on 3-layerd WBK (wire-woven bulk kagome). The mechanical strength of the kagome structures is shown relatively stable with the Gaussian types of imperfections.

Mechanical Behaviors under Compression in Wire-woven Bulk Kagome Truss PCMs-Part II: Effects of Geometric and Material Imperfections (벌크형 와이어직조 카고메 트러스 PCM 의 압축거동- 제 2 보: 결함의 영향)

  • Hyun, Sang-Il;Choi, Ji-Eun;Kang, Ki-Ju
    • Proceedings of the KSME Conference
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    • 2007.05a
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    • pp.78-83
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    • 2007
  • A newly developed cellular metal based on kagome lattice is an ideal candidate for multifunctional materials achieving various optimal properties. Intensive efforts have been devoted to develop efficient techniques for mass production due to its wide potential applications. Since a variety of imperfections would be inevitably included in the realistic fabrication processes, it is highly important to examine the correlation between the imperfections and material strengths. Previous performance tests were mostly done by numerical simulations such as finite element method (FEM), but only for perfect structures without any imperfection. In this paper, we developed an efficient numerical framework using nonlinear random network analysis (RNA) to verify how the statistical imperfections (geometrical and material property) contribute to the performance of general truss structures. The numerical results for kagome truss structures are compared with experimental measurements on 3-layerd WBK (wire-woven bulk kagome). The mechanical strength of the kagome structures is shown relatively stable with the Gaussian types of imperfections.

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Wear, Oxidation and Shear Characteristics of Mixed Lubricating Oil (Mineral/Vegetable oil) with ZnDTP (ZnDTP를 첨가한 혼합윤활유(광유/식물성 오일)의 마모, 산화 및 전단 특성)

  • Lim, TaeYoon;Kim, YangHoe;Na, Byung-Ki
    • Tribology and Lubricants
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    • v.34 no.4
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    • pp.160-167
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    • 2018
  • Vegetable oils can contribute to the goal of energy independence and security owing to their naturally renewable resources. One of the representative vegetable oils is biodiesel, which is being used in domestic and European markets as a blended fuel with automotive diesel. Vegetable oils are promising candidates as base fluids to replace petroleum lubricants because of their excellent lubricity and biodegradability. We prepared biodiesel with a purity of 99.9% via the esterification of waste cooking oil. Blended biodiesel and Petro-lube base oil were mixed to produce five types of mixed lubricating oil. We analyzed the various characteristics of the blended biodiesel with Petro-lube base oil for different blending ratios. The lubricity of the vegetable lubricant improves as the content of biodiesel increases. In addition, since zinc dialkyldithiophosphates (ZnDTPs) are widely used as multifunctional additives in petroleum-based lubricants, we optimized the blending ratio for lubricity, oxidation stability, and shear stability by adding ZnDTP as a performance additive to improve the biodiesel properties, such as oxidation stability and hydrolysis. The optimized lubricants improve by approximately 25% in lubricity and by 20 times in oxidation stability and shear stability after the addition of ZnDTP.

Tuning Hydrophobicity of TiO2 Layers with Silanization and Self-assembled Nanopatterning

  • Nghia, Van Trong;Lee, Young Keun;Lee, Jaesang;Park, Jeong Young
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.291-291
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    • 2013
  • The wettability of TiO2 layers is controlled by forming highly ordered arrays of nanocones using nanopatterning, based on self-assembly and dry etching. Nanopatterning of TiO2 layers is achieved via formation of self-assembled monolayers of SiO2 spheres fabricated using the Langmuir-Blodgett technique, followed by dry etching. Compared to a thin film TiO2 layer, the nanopatterned TiO2 samples show a smaller static water contact angle, where the water contact angle decreases as the etching time increases, which is attributed to the Wenzel equation. When TiO2 layers are coated by 1H,1H,2H,2H-perfluorooctyltrichlorosilane, we observed the opposite behavior, exhibiting superhydrophobicity (up to contact angle of $155^{\circ}$) on the nanopatterned TiO2 layers. Self-assembled nanopatterning of the TiO2 layer may provide an advanced method for producing multifunctional transparent layers with self-cleaning properties.

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Nondestructive Sensing Evaluation of Electrospun PVDF Fiber and Carbon Nanotube/Epoxy Composites Using Electro-Micromechanical Technique (Electro-Micromechanical 시험법을 이용한 Electrospun PVDF Fiber 및 CNT 강화 Epoxy 복합재료의 비파괴 감지능 평가)

  • Jung, Jin-Gyu;Kim, Sung-Ju;Park, Joung-Man
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2005.11a
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    • pp.153-156
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    • 2005
  • Nondestructive sensing of electrospun PYDF web and multi-wall carbon nanotube (MWCNT)/epoxy composites were investigated using electro-micromechanical technique. Electrospinning is a technique used to produce micron to submicron diameter polymeric fibers. Electrospun PVDF web was also evaluated for the sensing properties by micromechanical test and by measurement electrical resistance. CNT composite was especially prepared for high volume contents, 50 vol% of reinforcement. Electrical contact resistivity on humidity sensing was a good indicator for monitoring as for multifunctional applications. Work of adhesion using contact angle measurement was studied to correlate acid-base surface energy between carbon fiber and CNF composites, and will study furher for interfacial adhesion force by micromechanical test.

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Study on the Improvement of Epoxy Property for Aluminum Conductor Composite Core (복합재료 중심인장선용 에폭시 물성 개선 연구)

  • Heo, Seok-Bong;Kang, Junyoung;Youn, Young-Gil;Goh, Munju;Kim, Nam Hoon
    • Composites Research
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    • v.32 no.6
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    • pp.349-354
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    • 2019
  • The Aluminum conductor composite core consists of fast-curing thermosetting epoxy used as reinforcements and carbon fiber and glass fiber used as matrix. In this study, we have investigated fast curing epoxy cured products used for composite core(Aluminum Conductor Composite Core, ACCC). Tetrafunctional epoxy(PA 806) was used as a multifunctional epoxy, along with two kinds of curing agents, MNAn(5-Methyl-5-norbornene-2,3-dicarboxylic anhydride) and HHPA(Hexahydrophthalic Anhydride), to make an epoxy cured product and their properties were evaluated. Optimum conditions are confirmed by varying the content of curing accelerator in the selected epoxy and curing agent.

AltMV TGB1 Nucleolar Localization Requires Homologous Interaction and Correlates with Cell Wall Localization Associated with Cell-to-Cell Movement

  • Nam, Jiryun;Nam, Moon;Bae, Hanhong;Lee, Cheolho;Lee, Bong-Chun;Hammond, John;Lim, Hyoun-Sub
    • The Plant Pathology Journal
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    • v.29 no.4
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    • pp.454-459
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    • 2013
  • The Potexvirus Alternanthera mosaic virus (AltMV) has multifunctional triple gene block (TGB) proteins, among which our studies have focused on the properties of the TGB1 protein. The TGB1 of AltMV has functions including RNA binding, RNA silencing suppression, and cell-to-cell movement, and is known to form homologous interactions. The helicase domains of AltMV TGB1 were separately mutated to identify which regions are involved in homologous TGB1 interactions. The yeast two hybrid system and Bimolecular Fluorescence Complementation (BiFC) in planta were utilized to examine homologous interactions of the mutants. Helicase motif I of AltMV TGB1 was found to be critical to maintain homologous interactions. Mutations in the remaining helicase motifs did not inhibit TGB1 homologous interactions. In the absence of homologous interaction of TGB1, subcellular localization of helicase domain I mutants showed distinctively different patterns from that of WT TGB1. These results provide important information to study viral movement and replication of AltMV.

The Effect of chemical crosslinking in alkaline solution on fibrillation tendency and dyeability of lyocell fiber (알칼리 수용액에서의 화학적 경화를 통한 라이오셀 섬유의 피브릴화 경향 및 염색성에 미치는 영향)

  • Lee, Soo;Kim, Jin-Woo;Jin, Seok-Hwan
    • Journal of the Korean Applied Science and Technology
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    • v.27 no.2
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    • pp.168-174
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    • 2010
  • In this research, an effective method for reducing the fibrillation of lyocell fibers, which are spun from a solution of cellulose in N-methyl morpholine-N-oxide(NMMO), through consecutive chemical treatments. Undried solution-spun cellulosic fiber was firstly treated with 10 to 30 wt% of multifunctional crosslinking agents, such as ethylene glycol poly(3-chloro-2-hydroxypropyl) ether, and then dipped into alkaline solution to introduce epoxy functions. Finally steam condition was applied to occur a chemical crosslinking in order to reduce the fibrillation on the surface of fibers. Fibrillation was also reduced significantly by adding extra $Na_2SO_4$ in NaOH solution. In addition, Antifibrilllated lyocell fibers show the slightly higher dyeability(4 %) to Cibacron Blue without serious reduction of mechanical properties.

The Development of High Performance Nano-composites with Carbon Nanotube (카본나노튜브를 이용한 고성능 나노복합재료의 개발 동향)

  • Lee, Min-Kyung;Bae, Soo Bin;Park, Jong Kyoo;Lee, Seung Geol
    • Textile Coloration and Finishing
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    • v.26 no.2
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    • pp.71-78
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    • 2014
  • This review paper is a state of the art report of the development of high performance nano-composites with carbon nanotube. We investigate the research and development (R&D) trends of high performance nano-composites with carbon nanotube by analyzing technical trends in research institutes and industry. We report the R&D and technology trends for the properties and applications of fabrication of hybrid composites with aligned carbon nanotubes, multifunctional fiber/carbon nanotube composites. We discuss the specific topics including unidirectional carbon nanotube, carbon nanotube forests, transfer-printing carbon nanotube technology, deposition of carbon nanotube by electrophoresis, vapor grown carbon fiber (VGCF), cup-stacked carbon nanotube, bucky paper and carbon nanotube yarns in this review paper.