• Title/Summary/Keyword: multicomponent system

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Solubility of Mixed Lanthanide Hydroxide and Oxide Solid Solutions

  • Moniruzzaman, Mohammad;Kobayashi, Taishi;Sasaki, Takayuki
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.19 no.3
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    • pp.353-366
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    • 2021
  • The solubilities of different multicomponent lanthanide oxide (Ln2O3) solid solutions including binary (Ln1 and Ln2 = La, Nd, Eu, or Tm), ternary (Ln1, Ln2, and Ln3 = La, Nd, Eu, or Tm), and higher systems (Ln = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu) were studied after aging for four weeks at 60℃. Our recent study revealed that the phase transformations in binary ((La, Nd) and (La, Eu)) and ternary (La, Nd, Eu) systems are responsible for the formation of (La, Nd)(OH)3, (La, Eu)(OH)3, and (La, Nd, Eu)(OH)3 solid solutions, respectively. The variations in the mole fractions of La3+, Nd3+, and Eu3+ in the sample solutions of these hydroxide solid solutions indicated that a thermodynamic equilibrium might account for the apparent La, Nd, and Eu solubilities. Conversely, the binary and ternary systems containing Tm2O3 as the heavy lanthanide oxide retained the oxide-based solid solutions, and their solubility behaviors were dominated by their congruent dissolutions. In the higher multicomponent system, the X-ray diffraction patterns of the solid phases, before and after contact with the aqueous phase indicated the formation of a stable oxide solid solution and their solubility behavior was explained by its congruent dissolution.

A Comprehensive Groundwater Modeling using Multicomponent Multiphase Theory: 1. Development of a Multidimensional Finite Element Model (다중 다상이론을 이용한 통합적 지하수 모델링: 1. 다차원 유한요소 모형의 개발)

  • Joon Hyun Kim
    • Journal of Korea Soil Environment Society
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    • v.1 no.1
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    • pp.89-102
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    • 1996
  • An integrated model is presented to describe underground flow and mass transport, using a multicomponent multiphase approach. The comprehensive governing equation is derived considering mass and force balances of chemical species over four phases(water, oil, air, and soil) in a schematic elementary volume. Compact and systemati notations of relevant variables and equations are introduced to facilitate the inclusion of complex migration and transformation processes, and variable spatial dimensions. The resulting nonlinear system is solved by a multidimensional finite element code. The developed code with dynamic array allocation, is sufficiently flexible to work across a wide spectrum of computers, including an IBM ES 9000/900 vector facility, SP2 cluster machine, Unix workstations and PCs, for one-, two and three-dimensional problems. To reduce the computation time and storage requirements, the system equations are decoupled and solved using a banded global matrix solver, with the vector and parallel processing on the IBM 9000. To avoide the numerical oscillations of the nonlinear problems in the case of convective dominant transport, the techniques of upstream weighting, mass lumping, and elementary-wise parameter evaluation are applied. The instability and convergence criteria of the nonlinear problems are studied for the one-dimensional analogue of FEM and FDM. Modeling capacity is presented in the simulation of three dimensional composite multiphase TCE migration. Comprehesive simulation feature of the code is presented in a companion paper of this issue for the specific groundwater or flow and contamination problems.

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Regulation of the Phagocyte Respiratory Burst Oxidase by Protein Interactions

  • Lambeth, J. David
    • BMB Reports
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    • v.33 no.6
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    • pp.427-439
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    • 2000
  • The activity of the phagocyte respiratory burst oxidase is regulated by complex and dynamic alterations in protein-protein interactions that result in the rapid assembly of an active multicomponent NADPH oxidase enzyme on the plasma membrane. While the enzymatic activity has been studied for the past 20 years, the past decade has seen remarkable progress in our understanding of the enzyme and its activation at the molecular level. This article describes the current state of knowledge, and proposes a model for the mechanism by which protein-protein interactions regulate enzyme activity in this system.

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Adsorption Behaviors of Cesium and Strontium in Multicomponent System

  • Lee, Hoo-Kun;Park, Geun-Il;Ro, Sung-Gy;Park, Hyun-Soo
    • Proceedings of the Korean Nuclear Society Conference
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    • 1997.05b
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    • pp.274-279
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    • 1997
  • Breakthrough curves for separation of cesium and strontium binary components from aqueous solutions in fixed bed by chabazite and 13X were experimentally obtained and simulated the breakthrough curves for binary component adsorption. It is shown that agreements between model predictions and experimental data are relatively good although some deviations are observed. From engineering point of view, the simple model used here can be applied to simulate adsorption breakthrough curves satisfactorily.

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Quantitative Analysis of High-Temperature Mullitization from a Multicomponent Oxide System (다성분 산화물 요업체의 고온 물라이트화 반응 정량분석)

  • Shin, Hyun-Ho;Kim, Chool-Soo;Kim, Chang-Wook;Chang, Soon-Nam;Sung, Wan;Chang, Dong-Hwan;Kang, Suk-Won;Choi, Suk-Hong
    • Journal of the Korean Ceramic Society
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    • v.35 no.1
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    • pp.5-10
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    • 1998
  • Mullitization in a multicomponent oxide system(alumina-kaolin-quartz-feldspar-talc) was studied as a function of sintering temperature from 1200 to 1500$^{\circ}C$ based upon a quantitative X-ray diffraction analysis. In the present study mullite grew as wiskers and its formation reaction showed characteristic there stages as follows In the first stage(1255-1295$^{\circ}C$) an appreciable mullitization(nucleation) occurred while corun-dum dissolution into glass (increasing glass content ) limited the rate of the reaction. At 1295-1335$^{\circ}C$ (second state) the reaction was significantly enhanced with a considerable glass consumption and with no appreciable change in corundum content. Finally (above 1335$^{\circ}C$) the reaction rate was attenuated re-markably with an apparent decrease in glass consumption rate. The impingement of mullite whiskers by oth-er whiskers and crystals was speculated to cause mullite growth in thickness direction with a slow growth rate resulting in the diminished reaction rate in the final stage.

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Determination of Optimal Replacement Period for A Multicomponent System Consider with Failure Types (고장형태(故障形態)를 고려(考慮)한 다부품장비(多部品裝備)의 최적교환시기(最適交換時期) 결정(決定))

  • Lee, Seung-Jun;Gang, Chang-Uk;Hwang, Ui-Cheol
    • Journal of Korean Society for Quality Management
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    • v.19 no.2
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    • pp.117-124
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    • 1991
  • In this paper, it is assumed that a system is composed of an essential unit and a nonessential unit. During the running of the system, an essential unit is replaced at periodic replacement time T or at nth failure of essential unit whichever occurs first. Nonessential unit is replaced at its failure and at the replacement of essential unit. This paper derive optimal replacement period which minmises the total expected cost for replacement. The unimodality of totoal maintenance cost function is proved under the assumption that hazard rate of each component is continuous and monotone increasing failure rate(IFR). Based on this condition, it is shown that the optimal replacement period is finite and unique.

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Development of Computer Code for Simulation of Multicomponent Aerosol Dynamics -Uncertainty and Sensitivity Analysis- (다성분 에어로졸계의 동특성 묘사를 위한 전산 코드의 개발 -불확실성 및 민감도 해석-)

  • Na, Jang-Hwan;Lee, Byong-Whi
    • Nuclear Engineering and Technology
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    • v.19 no.2
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    • pp.85-98
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    • 1987
  • To analyze the aerosol dynamics in severe accidents of LMFBR, a new computer code entitled MCAD (Multicomponent Aerosol Dynamics) has been developed. The code can treat two component aerosol system using relative collision probability of each particles as sequences of accident scenarios. Coagulation and removal mechanisms incorporating Brownian diffusion and gravitational sedimentation are included in this model. In order to see the effect of particle geometry, the code makes use of the concept of density correction factor and shape factors. The code is verified using the experimental result of NSPP-300 series and compared to other code. At present, it fits the result of experiment well and agrees to the existing code. The input variables included are very uncertain. Hence, it requires uncertainty and sensitivity analysis as a supplement to code development. In this analysis, 14 variables are selected to analyze. The input variables are compounded by experimental design method and Latin hypercube sampling. Their results are applied to Response surface method to see the degree of regression. The stepwise regression method gives an insight to which variables are significant as time elapse and their reasonable ranges. Using Monte Carlo Method to the regression model of LHS, the confidence level of the results of MCAD and their variables is improved.

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Synthesis of Monolithic Gel to Bulk glass-Ceramic in Multicomponent Li2O-Al2O3-SiO2 System (Sol-Gel법에 의한 Li2O-Al2O3-SiO2계 괴상겔 및 결정화유리의 합성)

  • 양중식;작화제부
    • Journal of the Korean Ceramic Society
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    • v.25 no.5
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    • pp.541-551
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    • 1988
  • The purpose of this investigation was to prepare multicomponent monolithic Li-Al-Si gels of composition(mol%) 16.67 Li2O-16.67 Al2O3-66.67 SiO2 and to convert the gels to monolithic glass-ceramic at low temperature without melting. The hydrolysis, DTA, TGA, TMA, SEM, pore distribution, density and the activation energy for crystallization of the glass-ceramic formation with rawmaterials of which tetraethl orhosilicate of networkforming cation(Si) is partially hydrolyzed, aluminum isoproxide and lithium methoxide prepared by Li-metal react with methanol were studied. The results were as follows : 1) Monolithic gels which were added with additional water, resulting in a total water content 2.5 to 3.0 times the stoichiometric amount required to fully hydrolyze the alkoxides. 2) Specimens were dried to form crylinders 60mm in length and 40mm in diameter in about 800 hrs at 5$0^{\circ}C$. 3) $\beta$-eucryptite crystals and $\beta$-spodumene crystals were detected in samples heated above 75$0^{\circ}C$. 4) Within the temperature and range of 25-50$0^{\circ}C$ and 1,00$0^{\circ}C$ the thermal expansion coefficient for crystallized samples were shown as 2.6-5.7$\times$10-7/$^{\circ}C$ and 7.4-12.5$\times$10-7/$^{\circ}C$, respectively. 5) The activation energy for the crystal growth was 11.01kcal/mol at 794$^{\circ}C$ to 85$0^{\circ}C$.

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Theory of Imaging And Diffraction (TEM 관련 이론해설 (3): 영상 형성이론과 회절이론)

  • Lee, Hwack-Joo
    • Applied Microscopy
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    • v.33 no.3
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    • pp.169-178
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    • 2003
  • In this review, theoretical approaches of imaging and diffraction in electron microscopy are introduced which allows the diffraction patterns and images to be treated with equal facility and emphasized the relationships between them. The coherent wave optics, incoherent wave imaging theory were introduced. The idea of Abbe theory was also introduced. Varoius phase contrast theories in small angle approximation were derived including the wave theory on Multi-component system.

Nucleotide Binding Component of the Respiratory Burst Oxidase of Human Neutrophils

  • Park, Jeen-Woo;Ahn, Soo-Mi
    • BMB Reports
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    • v.28 no.3
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    • pp.275-280
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    • 1995
  • The respiratory burst oxidase of neutrophils is a multicomponent enzyme, domant in resting cells, that catalyzes the reduction of oxygen to $O_{2}^{-}$ at the expense of NADPH. In the resting neutrophil, some of the components of the oxidase, including proteins p47 and p67, are in the cytosol, while the rest are in the plasma membrane. Recent evidence has suggested that at least some of the cytosolic oxidase components exist as a complex. The cytosolic complex with a molecular weight of ~240 kDa was found to bind to blue-agarose and 2',5'-ADP-agarose, which recognize nucleotide requiring enzymes. In order to identify the nucleotide binding component of the cytosolic complex we purified recombinant p47 and p67 fusion proteins using the pGEX system. Pure recombinant p47 was retained completely on 2',5'-ADP-agarose, whereas pure recombinant p67 did not bind to these affinity beads. On the basis of these results, we infer that p47 may contain the nucleotide binding site.

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