• 한국의류산업학회지
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• 제5권3호
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• pp.283-288
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• 2003

Large quantity of metal mordant in natural dyeing has been used. For environmental reason, there is a need to reduce the amount of metal mordant and suggest the optimum amount of metal mordant in dyeing process. In this study, the relationship between mordant concentration and dyeing property was investigated. Various metal mordant concentrations of AI, Cu, Fe, Sn, were studied (from 1 to 5%). After treatment of mordant on cotton fabric, the concentration of metal ion in used mordant solution was quantified. There was no significant difference of the tone of color in mordant concentration from 1% to 5%, Therefore, there is no need to increase mordant concentration over 1%. chitosan treated cotton fabric showed a significant increase in dyeing affinity compared to untreated cotton fabric (the value of ${\Delta}E$ was 20). chitosan increased dye affinity significantly in the presence of mordant. It can be suggested that chitosan itself can replace metal mordants in the future.

• 한국의류학회지
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• 제25권1호
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• pp.3-12
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• 2001

The dyeing powder drawn out from Dryopteris crassirhizoma by water was concentrated. Using this powder, the silk and the cotton fabrics were dyed and they measured with the K/S value, surface color, mordant quantity in order to evaluate the dyeability, antimicrobial and deodorant properties. The colorant of Dryopteris crassirhizoma was proved flavonoids by FT-IR spectrum. The K/S values of silk were much higher than those of cotton, the color yield of the silk and cotton fabric were most efficient the postmordanting method. The surface colors on the dyed fabric depended heavily upon mordants used or mordanting methods. For all cases, the value of the dyed fabric was generally dark. The chroma produced clear for the Al-mordant of silk and the Cu-mordant of cotton in the 3% concentration of mordants, the color difference was distinct when using the Fe-mordant. The K/S values of cationized cotton were much higher than cotton. The color fastness was significantly improved when mordants were added, In the case of the light fastness, Fe and Cu-mordants improved more than 1 level. The Cu-mordant showed the greatest antimicrobial and deordarant activity on both of the silk and the cotton.

• 한국염색가공학회지
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• 제11권5호
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• pp.30-37
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• 1999

The extracts drawn out from Artemisia princeps by water was concentrated. Using this concentrate the silk and the cotton fabrics were dyed, and they were measured with the K/S value, surface color and mordant quantity in order to evaluate the dyeability and the antimicrobial activity. The results are as follows; 1. The K/S value of the silk fabric was much higher than that of the cotton fabric. And the color yield of the dyed silk fabric was most efficient for the premordanting method. 2. The surface colors on the dyed fabric depended heavily upon mordants used or mordanting methods. For all cases, the value of the dyed fabric was generally dark. For the Cr-mordant among various mordants, the chroma produced clear and the color difference was distinct when using the Fe-mordant. 3. On the other hand the amount of absorbed mordant in the silk fabric was larger than that of the cotton fabric. And the Cu-mordant was most efficient. 4. The color fastness was significantly improved when mordants were added. Cr-mordant improved best in all of the dry cleaning, wet cleaning and perspiration fastness. Iron and abrasion fastness showed over 4-5 grade regardless of any mordant. And light fastness was best in Cu-mordant. 5. The Cu-mordant showed the greatest antimicrobial activity in both of mordant treat silk and cotton fabrics.

• 한국의류학회지
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• 제23권6호
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• pp.788-799
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• 1999

This study was performed to investigate the effect of mordants on the dyeability colorfastness to light and to laundering and biological properties of mordanted and natural-dyed cotton and silk substrates. Natural red dyes were extracted from Caesalpinia Sappan L. (Sappan wood) and Rubia Akane Nakai (Madder) by boil water Five different compounds of Al, Cr, Cu, Fe and Sn were used as mordanting agents. The result of this study are sumarized as follows ; 1. In the of the fabrics mordanted and dyed with sappan wood K/S value increases and λmax shifts to the longer wavelength as mordant concentration increases. Color of the fabrics dyed with sappan wood and madder change to redder bluer and lighter after mordanting. 2. As the number of repetition of dyeing-mordnating process increase the color of the dyed fabrics tend to be redder bluer and darker. Mordanted dyes with Al and Sn make chroma increase. The quantity of mordant absorbed in the silk fabric increase as mordant concentration increase. More Fe is absorbed in silk than Cr is. 3. After being exposed to light the fabrics dyed with sappan wood and madder change to less red Fe and Cu mordanting yeild better colorfastness to light than others does. Natural-dyed fabrics exposed to light tend to be faded and whitened in CIELAB chromaticity co-ordinates. So we might trace back the original color of ancient faded fabrics by changes in color of natural dyes. 4. After washing the colors of natural dyes change to more blue, Fe and Cu mordanting give better colorfastness to wash than others do. 5. The soil-burial cotton is more susceptible to mildew and rot than the silk is. Antimicrobial activity of the natural-dyed cotton can be enhanced by Cu and silk can be enhanced by Cu and Cr mordanting respectively.

• 복식
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• 제36권
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• pp.109-119
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• 1998

For the purpose of standardization and practicability of natural dyeing, the mordanting and dyeing properties of Caseaslpinia Sappan, L. and Brazilin were studied. Appropriate extraction, dyeing and mordanting condition of Caeaslpinia Sappan, L. were determined, and the effect of mordanting method on dye up-take adn color fastness of dyed fabric was investigated. The most absorbance of Caeaslpinia Sappan, L. solution was 445nm, Brazilin was 448nm. The color of bazilin solution was affected by pH 7~9. The optimum temperature to extract Caesalpinia Sappan, L. was 10$0^{\circ}C$ adn dyeing solution for 1 hour. In case mordants concentration, the most absorbance was 0.3%. In case mordanting test, the best and proper temperature to quantities of absorbed mordants in silk was 8$0^{\circ}C$ and the most quantities of absorbed mordants in silk was mordant treatment by Cu. Effective dyeing time to silk was 60min. Effective mordanting temperature was 8$0^{\circ}C$, and its time was 30min. K/S value of dyeing fabrics was recoginazed by mordanting treat-ment, specially Fe, Sn, Al, Cu. K/S value of pre-mordanting was higher than post-mordanting. After soaping treatment K/S value of pre- and post-mordanting silk was decreased and 0.1%(W/V) quantity of mordant was sufficient for treatment. In the case of Caeaslpinia Sappan, L. fastness was increased by mordanting treatment. Mordants and mordanting treatment method affected the amount of absorption and color change of dyed silk.