• Journal of the Korean Wood Science and Technology
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• v.23 no.2
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• pp.77-82
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• 1995

With the aim to utilize pine wood(Pinus densiflora Sieb. et Zucc.) as an interior building materials, such as flooring material, monoethylene glycol(MEG) resin solution was impregnated into greenwood. Specimens of three different qualities, that is, normal wood, resinous wood and compression wood, were prepared. Distribution of resin element(phosphorus) in MEG resin solution-impregnated woods and preservative effectiveness against brown rot fungi(Tyromyces palustris and Serpula lacrymans) of these woods were investigated. The results were as follows: 1. The concentration of phosphorus into cell walls of resinous wood and compression wood was lower compared to that of normal wood. This shows that the quality of wood has an influence on the penetration of MEG resin solution into the wood. It was shown from a leaching test that MEG resin could be leached out easily from the cell walls. 2. The resinous wood and compression wood, even without MEG resin solution impregnation had high decay resistance. For normal wood, significant improvement of preservative effectiveness was observed after impregnation of MEG resin solution. It was shown that MEG resin was leached out from the woods after leaching test, resulting in the reduction of preservative effectiveness. From this result, suitability of MEG resin solution-impregnated woods as an interior materials was recognized.

• Korean Chemical Engineering Research
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• v.46 no.5
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• pp.903-914
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• 2008

This study was undertaken for the production capacity expansion and energy saving through entire process simulation and optimization for the commercial process of manufacturing monoethylene glycol as a staple from ethylene oxide. Aspen $Plus^{TM}$(ver. 2006) was employed in the simulation and optimization work. The multicomponent vapor-liquid equilibria involved in the process were calculated using the NRTL-RK equation. As for the binary interaction parameters required for a total of 91 binary systems, those for 8 systems were self-supplied by the simulator, those for 28 systems were estimated through regression of the VLE data in the literature, and the remainder were estimated with the estimation system built in the simulator. Subsequent to ascertaining the accuracy of the generated parameters through comparison between actual and simulated process data, sensitive variables highly affecting the process were searched and selected using sensitivity analysis tool in the simulator. The optimum operating conditions minimizing the total heat duty of the process were investigated using the optimization tool based on the successive quadratic programming in the simulator.

• Corrosion Science and Technology
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• v.16 no.4
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• pp.161-166
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• 2017

The qualitative composition of active components of the corrosion inhibitor CGW-85567 was studied. It was found that С18:2 and С18:1 imidazolines and the corresponding imidazolin-amides are the major components. The HPLC/MS technique was developed for their determination in the water solutions of monoethylene glycol (MEG). Industrial application of the inhibitor showed that MEG solution retained high concentration of the inhibitor for a long time after ceasing its addition into pipelines. Low values of the partition coefficients (0.010-0.014) of imidazolines in the system "water solution of MEG (concentration of MEG 62-85% v/v) - gas condensate" have allowed to pass on from the technology of continuous pumping of the inhibitor into protected pipelines to the periodic dosing technology. Taking into account a long time of circulation in the system and high temperatures during MEG regeneration process possible degradation products of the inhibitor were studied. N, N-dimethyl-dodecanamine-1, and N, N-dimethyl-tetradecanamine-1 were identified as major degradation products of the corrosion inhibitor CGW-85567.

• Journal of the Korean Wood Science and Technology
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• v.48 no.1
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• pp.41-49
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• 2020

Jabon (Anthocephalus cadamba) is a fast-growing wood species that is widely utilized for light construction and other purposes in Indonesia. The objectives of the current study were to determine the effects of monoethylene glycol (MEG) and SiO₂ nanoparticles (nano SiO₂) impregnation treatment on the dimensional stability and density of jabon wood and to identify the characteristics of impregnated jabon wood. Wood samples were immersed in water (as untreated), MEG, 0.5% MEGSiO₂, then impregnated by applying 0.5 bar of vacuum for 60 min, and then applying 2.5 bar of pressure for 120 min. The results showed that impregnation with MEG and Nano SiO₂ had a significant effect on the dimensional stability of jabon wood. Polymers can fill cell walls in wood indicated by increasing weight percentgain, antiswelling efficiency, bulking effect, and density, then decreasing in water uptake value. Jabon wood morphology by using SEM showed that MEGSiO₂ polymers can cover part of the pitsin the wood vessel wall of jabon. This finding was reinforced by EDX results showing that the silicon content was increased due to the addition of SiO₂ nano. The XRD diffraction pattern indicated that MEGSiO₂ treatment increased the degree of crystallinity in wood samples. Overall, treatment with 0.5% MEGSiO₂ led to the most improvement in the dimensional stability of 5-year-old jabon wood in this study.

• Elastomers and Composites
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• v.52 no.1
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• pp.1-8
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• 2017

Hydrolysis resistance and mechanical property changes of polyketone (POK)/glass fiber (GF) composites were investigated for GF concentrations varying between 30 and 50%. The hydrolysis resistance of GF filled POK and polyamide66 (PA66, hydrolysis resistant grade) composites were compared. As shown by the experimental results, increasing the immersion time of the composites in a monoethylene glycol (MEG)/water solution at $120^{\circ}C$ had no impact or resulted in slightly decreased mechanical properties such as the tensile strength, tensile modulus, and strain at break in case of POK composites, whereas the mechanical properties of PA66 composites showed a significant drop. Increasing GF concentrations increased the tensile strength, tensile modulus, flexural strength, and flexural modulus of POK composites; however, impact strength did not show significant changes. Hydrolysis mechanisms of POK and PA66 are discussed.

• Clean Technology
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• v.29 no.2
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• pp.79-86
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• 2023

The homogeneous catalyst, Ru-MACHO-BH, selectively performs hydrogenation reactions only on the carbonyl group of α, β-unsaturated aldehyde compounds with extremely high reactivity and selectivity. However, the hydrogenation of α, β-unsaturated aldehydes involves a heterogeneous Diels-Alder reaction, resulting in the formation of significant amounts of byproducts, such as dimers. In this study, we used the Ru-MACHO-BH catalyst (Carbonyl hydrido (tetrahydroborato) [bis (2-diphenyl phosphino ethyl) amino] ruthenium(II)) to selectively hydrogenate the carbonyl group of a specific type of α, β-unsaturated aldehyde called methacryl aldehyde, leading to the synthesis of methallyl alcohol. Simultaneously, we applied diols to inhibit the formation of byproducts. The results demonstrate that monoethylene glycol can significantly reduce the formation of diols. Based on these results, we effectively suppressed the formation of dimers containing vinyl groups in methacryl aldehyde by using hydroquinone, which can efficiently inhibit the chemical interaction of vinyl groups. Consequently, the conversion rate of methacryl aldehyde was increased. Ultimately, by reducing the amount of the expensive homogeneous catalyst Ru-MACHO-BH to 1/10, we achieved a selectivity of over 90% and a yield of over 80% for the desired product, methallyl alcohol. These results provide a method to minimize yield reduction while reducing the usage of expensive catalysts, thereby improving cost-effectiveness. We expect that the reaction could be applied to various kinds of selective hydrogenation and has been successfully run on an industrial scale.