• Korean Journal of Environmental Agriculture
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• v.23 no.4
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• pp.245-250
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• 2004

An analytical method was developed to determine monocrotophos residues in apple, citrus, and soil using high-performance liquid chromatography (HPLC) with ultraviolet absorption detection. Monocrotophos was extracted with acetone from apple, citrus and moist soil samples. The extract was concentrated, added with saline water, and subjected to n-hexane washing to remove nonpolar co-extractives. Dichloromethane partition was then followed to recover monocrotophos from the aqueous phase. Silica gel column chromatography was employed to further purify the extract prior to HPLC determination. Reverse-phase HPLC using an oct-adecylsilyl column was successfully applied to separate and quantitate the monocrotophos residue in sample extracts at the wavelength of 230 nm. Overall recoveries of monocrotophos from fortified samples averaged $95.3{\pm}2.1%$ (n=6), $970{\pm}0.7%$ (n=6), and $92.8{\pm}4.3%$ (n=12) for apple, citrus, and soil, respectively. The proposed method was quite reproducible and sensitive enough to replace the troublesome gas-liquid chromatographic analysis for monocrotophos residues.

• Journal of Environmental Science International
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• v.8 no.4
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• pp.503-507
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• 1999

To study the residue of organophosphorus pesticides in the ocean environment on the Cheju island, EPN[O-ethyl-O-4-nitrophenyl phenylphosphonothioate] and monocrotophos [Dimethyl-1-methyl-2-methyl carba-moylvinylphosphate] of organophosphorus pesticides are surveyed on coastal environment of Cheju city and Wimi in May and October 1996. The qualified limit detection of EPN and monocrotophos are 0.005ng/mL and 0.006ng/mL in the water by GC-FPD, respectively. The qualified limit detection of EPN and monocrotophos are 0.010ng/g and 0.012ng/g in the solid such as sediment and sea organism by GC-FPD, respectively. EPN and monocrotophos are not detected in seawater and sedimnet. Moreover EPN and monocrotophos are neither detected in seaweed cava (Ecklonia cava), Agar (Gelidium amansii), turban sell(Batillus cornutus) and sea urchin(Anthocidaris Crassispina). EPN, monocrotophos used in the farm on the Cheju island are not residued in the coastal environment in the Cheju island.

• Advances in Traditional Medicine
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• v.7 no.3
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• pp.304-310
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• 2007

Monocrotophos was administered orally to adult male albino mice at dose level of 3.0 mg/kg body weight/day/mice for 50 days. The treatment has found to affect spermatogenesis as well as the endocrine functions of the testis as indicated by gravimetric, histopathological and biochemical changes. The treatment has caused degenerative changes in the seminiferous tubules and Leydig cells of the testis and regression of the epididymis, seminal vesicle, vas deferens, prostate, Cowper's gland and levator ani. Similarly, cauda epididymal sperm count and sperm motility have shown significant reduction. There was a significant reduction in the protein, glycogen, sialic acid, acid and alkaline phosphatase and increase in cholesterol in the testis of monocrotophos treated mice compared with the control. The causative factors for these changes due to monocrotophos administration were discussed.

• Animal cells and systems
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• v.7 no.2
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• pp.165-168
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• 2003

The present studies investigate the induced effects of two pesticides lambda cyhalothrin (pyrethroid) and monocrotophos (organophosphate) on Rana cyanophlyctis (common skittering frog). Two different concentrations i.e. 0.1 and 1％ were used and cholinesterase activity was observed in liver, kidney and brain of these frogs. It was decreased upto 34.6 and 46.3％ in liver, 25.08 and 57.1％ in kidney and 31.64 and 50.7％ in brain under the effect of lambda cyhalothrin. In the case of monocrotophos treatment, cholinesterase decreased upto 37.7 and 57.7％ in liver,57.5 and 67.5％ in kidney and 47.6 and 65.9％ in brain, respectively.

• Korean journal of applied entomology
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• v.26 no.3 s.72
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• pp.159-163
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• 1987

The toxicity of the mixture at 1 to 1 ratio among the insecticides, BPMC, carbofuran, diazinon and monocrotophos to the brown planthopper (BPH), Nilaparvata lugens and green leafhopper (GLH), Nephotettix virescens were tested and compared to their toxicities of individual insecticides. Among the mixtures, carbofuran combinations with BPMC and diazinon showed synergistic effect in toxicity to BPH. There was also synergistic action in toxicity with mixture of BPMC plus monocrotophos to GLH. Other combinations were independent in toxic action to both insects.

• Korean Journal of Veterinary Service
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• v.30 no.4
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• pp.545-550
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• 2007

The toxicity of organophosphate arises from disruption of the nervous system due to the inhibition of cholinesterase enzymes, leading to death. Six dead mallards were found at Ansung where is one of the most popular wintering sites for migratory birds in Korea, and requested for diagnosis to Gyeonggi Veterinary Service on January of 2007. Some examinations including polymerase chain reaction (PCR) could not find any evidence of specific disease condition. However, the contents of gastrointestinal tracts of the birds contained residues of monocrotophos ranged from 31.3ppm to 294.3ppm by gas chromatography and mass spectrometry. It can be supposed that monocroptophos was responsible for the death of mallards by this results.

• Korean journal of applied entomology
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• v.18 no.2 s.39
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• pp.111-116
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• 1979

The experiments were carried out to evaluate the effectiveness of some insecticides in the control of the pine gall midges (Thecodiplosis japonensis Uchida et Inouye) when the low-volume of the insecticides were applied by the mist foliar sprayer. The insecticides, Salithion $(24\%\;Ec)$, Omethoate $(Folimat^{(R)}\;50\%\;Ec)$, Monocrotopos $(Azodrin^{(R)}24\%\;Ec)$, Acephate $(Ortran^{(R)}\;50\%\;Wp)$, Metalkamate $(Bux^{(R)}24\%\;Ec)$. BPMC $(Bassae^{(R)}50\%\;Ec)$ and MIPC $(Mipcin\;50\%\;Wp)$ were tested with 100, 200 and 400 times of water solution on the basis of single application at the six different intervals. Salithion was the most effective for the pressure of the gall formation by the pine gall midges and Omethoate, Monocrotophos and Metalkamate were relativey effective and others no effective. The most reliable concentration of the insecticides was 100 times of water solution, and the feasible timing of insecticide application on the basis of single application would be from May 9 to July 1 with Salithion, June 6 with Metalkamate and June 20 with Omethoate and Monocrotophos. The number of pine needles with the larval injured signs (no larvae in the needles) excluded the gall-formed needles were relatively higher in the treatments of Omethoate, Salithion and Monocrotophos than other insecticides. The treatments of Omethoate, Salithion and Monocrotophos caused the lower larval population in the gall than other insecticides.

• 월간산업보건
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• s.163
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• pp.36-38
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• 2001

• Environmental Analysis Health and Toxicology
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• v.17 no.4
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• pp.341-346
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• 2002

To investigate the residue of organophosphorus pesticides such as Monocrotophos［Dimethyl-1-methyl-2-methyl carbamoylvinylphosphate］and EPN［O-ethyl-O-4-nitrophenyl phenylphosphonothioate］in the coastal environment of Cheju island, samples of sea organism, water and sediment were collected at the Sackdaldong and Daepodong near the Jungmoon golf course in July and Aug. 1997. The qualified detection limit of mono-crotophos and EPN by GC -FPD were 0.024 ng/g and 0.020 ng/g in the sea organism, respectively Neither Monocrotophos nor EPN was detected in seaweed cava (Ecklonia cava), Agar (Gelidium amansii), turban sell (Batillus cornutus) and sea urchin (Anthocidaris Crassispina). They were not detected in seawater and sediment, either. These results showed that the coastal area near the Jungmoon golf course in the Cheju island was not polluted by the organophosphorus pesticides such as Monocrotophos and EPN.

• Journal of the Korean Chemical Society
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• v.57 no.3
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• pp.382-388
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• 2013

The present paper focuses on the synthesis, characterization and application of nanophotocatalyst for degradation of quinalphos and monocrotophos. Novel heterostructured ZnO/$TiO_2$ photocatalyst ($Z_9T$) was prepared and characterized with X-ray diffraction (XRD), SEM and UV-vis diffuses reflectance spectroscopy. The average crystalline size of synthesized $Z_9T$ was found to be 21.48 nm. The pesticides were degraded in the presence of nanophotocatalysts i.e., $TiO_2$, ZnO, $TiO_2$/ZnO mixed in various proportions and heterostructured nanophotocatalyst synthesized by Sol-Gel method. The batch experiments were performed by adding photocatalyst to 100 ml of pesticide solution and suspension was subjected to irradiation under UV light. In case of mixed catalyst, the maximum degradation of monocrotophos and quinalphos has been observed when ZnO and $TiO_2$ were in the ratio of 7:3 and 8:2 respectively. The degradation efficiency with synthesized heterostructured nanophotocatalyst ($Z_9T$) was found to be comparable with $TiO_2$.