• 제목/요약/키워드: molecular gas

검색결과 868건 처리시간 0.025초

플라즈마 반응기구조에 따른 코로나방전 및 NO-NO$_2$ 전환특성에 관한 실험적 연구 (Experimental Study on the Effect of Plasma Reactor Type on Corona Discharge and NO-NO2 Conversion Characteristics)

  • 박용성;전광민
    • 한국자동차공학회논문집
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    • 제10권6호
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    • pp.65-71
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    • 2002
  • Characteristics of corona discharge of the different types of the plasma reactors which are cone-hole and cone-plate is investigated experimentally. The discharge starts at lower voltage for the cathode corona than the anode corona and spark occurs at higher voltage for the cathode corona. And the cathode corona makes more stable discharge than the anode corona. The effect of the base gas in corona discharge for different O$_2$/N$_2$ concentrations is related with the gas molecular weight. The discharge for the smaller molecular weight gas occurs easier than for the high molecular weight gas. The discharge current decreases with the increase of oxygen concentration and it increases more sharply for anode corona than for cathode corona as discharge voltage increases after corona onset voltage. NO-NO$_2$ conversion increases with the energy density of corona discharge and the addition of O$_2$ in a base N$_2$ gas.

A Study on the Concentration Characteristics of Atmospheric Polycyclic Aromatic Hydrocarbons (PAHs) in Chongju

  • Lee, Hak-Sung;Kang, Byung-Wook;Kwon, Dong-Hyuk;Yeo, Hyun-Gu;Chun, Man-Young
    • Journal of Korean Society for Atmospheric Environment
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    • 제19권E2호
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    • pp.89-97
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    • 2003
  • Ambient polycyclic aromatic hydrocarbons (PAHs) were measured during the winter and summer of 2002 in Chongju. A filter pack and polyurethane foam (PUF) system was employed to collect simultaneously the particulate and gas phase PAHs. The samples were then analyzed using a gas chromatograph equipped with mass spectrometer detectors (GC/MSD). A total of 29 samples were collected and 11 PAH species were identified. The lower molecular weight PAH compounds (3∼4 rings) dominated the total PAH mass. The higher molecular weight PAH compounds (5∼6 rings) were less abundant. The PAHs were showed to exhibit seasonal variations. The concentrations of all com-pounds were significantly higher in winter than summer. The lower molecular weight PAHs were mostly found in the gas phase whereas the heavier ones were mainly associated with particulate phase. Vehicle emissions are likely to be the primary contributor of PAHs in Chongju. This study also demonstrated that it is necessary to perform simultaneously particulate and gas phase measurements to determine the accurate concentrations of ambient PAHs.

The ISM properties under ICM pressure in the cluster environment : NGC4330, NGC4402, NGC4522, NGC4569

  • 이범현;정애리
    • 천문학회보
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    • 제37권2호
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    • pp.85.2-85.2
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    • 2012
  • The interstellar medium (ISM) of galaxies in the galaxy cluster can well be affected by the intracluster medium (ICM). Among many suggested environmental processes, ram pressure stripping can effectively remove gas through the interaction with the ICM. In fact, Cluster galaxies are lower in HI gas mass compared to their field counterparts, and in recent high resolution HI imaging studies, many galaxies in dense environments have been found to be ram pressure stripped in HI. However, it is still under debate whether the ICM pressure can also remove dense molecular gas from the galactic disk, which plays more important role in star formation and hence galaxy evolution. To answer this question, we have obtained high resolution 12/13 CO (2-1) data from the Sub Millimeter Array (SMA) of four galaxies at various HI stripping stages to study how the molecular gas properties change as the galaxy experiences the ICM pressure. We investigate the physical properties of molecular gas with 12/13 CO images. By comparing with other wavelength data, i.e. data(optical, HI, $H{\alpha}$, etc), we discuss how and in which timescale galaxies can migrate from the blue cloud to the red sequence due to ram pressure stripping.

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볼츠만 방정식에 의한 CF4 분자가스의 전자이동속도 특성에 관한 연구 (The Study of Character of Electron Drift Velocity in CF4 Molecular Gas by the Boltzmann Equation)

  • 송병두;하성철
    • 한국전기전자재료학회논문지
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    • 제17권11호
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    • pp.1252-1257
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    • 2004
  • This paper describes the information for quantitative simulation of weakly ionized plasma. In previous paper, we calculated the electron transport coefficients by using two-term approximation of Boltzmann equation. But there is difference between the result of the two-term approximation of the Boltzmann equation and experiments in pure CF$_4$ molecular gas and in CF$_4$+Ar gas mixture. Therefore, In this paper, we calculated the electron drift velocity (W) in pure CF$_4$ molecular gas and CF$_4$+Ar gas mixture (1 %, 5 %, 10 %) for range of E/N values from 0.17~300 Td at the temperature was 300 K and pressure was 1 Torr by multi-term approximation of the Boltzmann equation by Robson and Ness. The results of two-term and multi-term approximation of the Boltzmann equation have been compared with each other for a range of E/N.

D-space-controlled graphene oxide hybrid membrane-loaded SnO2 nanosheets for selective H2 detection

  • Jung, Ji-Won;Jang, Ji-Soo
    • 센서학회지
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    • 제30권6호
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    • pp.376-380
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    • 2021
  • The accurate detection of hydrogen gas molecules is considered to be important for industrial safety. However, the selective detection of the gas using semiconductive metal oxides (SMOs)-based sensors is challenging. Here, we describe the fabrication of H2 sensors in which a nanocellulose/graphene oxide (GO) hybrid membrane is attached to SnO2 nanosheets (NSs). One-dimensional (1D) nanocellulose fibrils are attached to the surface of GO NSs (GONC membrane) by mixing GO and nanocellulose in a solution. The as-prepared GONC membrane is employed as a sacrificial template for SnO2 NSs as well as a molecular sieving membrane for selective H2 filtration. The combination of GONC membrane and SnO2 NSs showed substantial selectivity to hydrogen gas (Rair / Rgas > 10 @ 0.8 % H2, 100 ℃) with noise level responses to interfering gases (H2S, CO, CH3COCH3, C2H5OH, and NO2). These remarkable sensing results are attributed mainly to the molecular sieving effect of the GONC membrane. These results can facilitate the development of a highly selective H2 detector using SMO sensors.

From Gas Phase Clusters to Nanomaterials: An Overview of Theoretical Insights

  • Kim, Kwang-S.
    • Bulletin of the Korean Chemical Society
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    • 제24권6호
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    • pp.757-762
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    • 2003
  • Since theoretical investigations of gas phase clusters enable the evaluation of intrinsic molecular properties and intermolecular interactions, one can predict the macroscopic properties of bulk matter, from a microscopic determination of the properties of individual atoms, molecules, or clusters. Based on the insights obtained from theoretical investigations of the properties of a large number of cluster systems (ranging from simple water clusters to large π-systems), we have investigated the properties of various novel molecular systems including endo/exohedral fullerenes, nanotori, nonlinear optical materials, ionophores/receptors, polypeptides, enzymes, organic nanotubes, nanowires, and electronic and nano-mechanical molecular devices. The present minireview highlights some of the interesting results obtained in the course of our extensive theoretical investigations of clusters and nanomaterials.

분자체를 이용한 LNG 액화 플랜트 탈수 공정의 효율성 향상에 관한 연구 (Study on the Improvement of Efficiency in Dehydration Process of LNG Liquefaction Plant Using Molecular Sieve)

  • 박종화;유돈상;조대명
    • 한국수소및신에너지학회논문집
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    • 제35권1호
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    • pp.105-113
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    • 2024
  • The natural gas dehydration process plays a central role in liquefying LNG. This study proposes two natural gas dehydration process systems applicable to liquefied natural gas (LNG) liquefaction plants, and compares and analyzes energy optimization measures through simulation. The fuel gas from feed stream (FFF) case, which requires additional equipment for gas circulation, disadvantages are design capacity and increased energy. On the other hand, the end flash gas (EFG) case has advantages such as low initial investment costs and no need for compressors, but has downsides such as increased power energy and the use of gas with different components. According to the process simulation results, the required energy is 33.22 MW for the FFF case and 32.86 MW for the EFG case, confirming 1.1% energy savings per unit time in the EFG case. Therefore, in terms of design pressure, capacity, device configuration, and required energy, the EFG case is relatively advantageous. However, further research is needed on the impact of changes in the composition of regenerated gas on the liquefaction process and the fuel gas system.

메탄가스 분리용 탄소분자체 특성 연구 (Characterization of Carbon Molecular Sieve for Separating CH4 Gas)

  • 이범석;김택남;김윤종
    • 한국재료학회지
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    • 제14권2호
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    • pp.157-162
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    • 2004
  • The object of this research is to develop a carbon molecular sieve(below CMS) which can separate selectively to convert mixture gases spout at waste landfill into fuel. And this research is meaningful from the viewpoint of a quality improvement of CH$_4$ gas and an utilization of by-product. CMS was prepared using coconut shell powder as starting material and the effects of activators, temperature and modifier on the reaction were investigated in this research. Also, pore diameter, surface area of CMS and adsorption rate were measured and studied by cahn balance and ASAP2010. Its specific surface area and pore distribution were controlled easily at 800^{\circ}C and adsorption rate was very good. The CMS prepared in this research is shown to be able to separate landfill gases very effectively.