• Title/Summary/Keyword: molecular gas

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AKARI near-infrared spectral observations on the shocked H2 gas of a supernova remnant IC 443

  • Shinn, Jong-Ho;Koo, Bon-Chul;Seon, Kwang-Il;Lee, Ho-Gyu
    • The Bulletin of The Korean Astronomical Society
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    • v.35 no.1
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    • pp.69.1-69.1
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    • 2010
  • IC 443 is famous for its interaction with nearby molecular clouds and intense H2 emission lines in infrared. Therefore, it has been studied extensively for the understanding of molecular shocks. We observed H2 mission lines toward the shock-cloud interaction regions of IC 443, known as clumps B, C, and G. The observations were performed with the InfraRed Camera (IRC) onboard a satellite AKARI over 2.5-5.0 um, where previous space observations, e.g. Infrared Space Observatory (ISO) and Spitzer, do not cover. Our AKARI observations provide spectra of sequential pure-rotational and ro-vibrational H2 emission lines. For the clumps C and G, combining with previous mid-infrared observational results, we found that the H2 level populations show a significant separation between v=0 and v=1 levels; v=1 levels are under-populated than v=0 levels, therefore, the population cannot be described by two temperature LTE model, as many people have analyzed for the shocked H2 gas. We also applied the thermal admixture model, dN(H2; T)~T^(-b) dT, with varying ortho-to-para ratios according to the temperature, to describe the level population, and obtained plausible ranges of the H2 gas density and power-law index b.

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Three-dimensional Rarefied Flows in Rotating Helical Channels (헬리컬 채널내부의 3차원 희박기체유동)

  • Hwang, Y.K.;Heo, J.S.
    • Proceedings of the KSME Conference
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    • 2000.04b
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    • pp.625-630
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    • 2000
  • Numerical and experimental investigations are peformed for the rarefied gas flows in pumping channels of a helical-type drag pump. Modern turbomolecular pumps include a drag stage in the discharge side, operating roughly in $10^{-2}{\sim}10Torr$. The flow occurring in the pumping channel develops from the molecular transition to slip flow traveling downstream. Two different numerical methods are used in this analysis: the first one is a continuum approach in solving the Navier-Stokes equations with slip boundary conditions, and the second one is a stochastic particle approach through the use of the direct simulation Monte Carlo(DSMC) method. The flow in a pumping channel is three-dimensional(3D), and the main difficulty in modeling a 3D case comes from the rotating frame of reference. Thus, trajectories of particles are no longer straight lines. In the Present DSMC method, trajectories of particles are calculated by integrating a system of differential equations including the Coriolis and centrifugal forces. Our study is the first instance to analyze the rarefied gas flows in rotating frame in the presence of noninertial effects.

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Characteristics and Processing Effects of $ZrO_2$ Thin Films grown by Metal-Organic Molecular Beam Epitaxy (금속 유기 분자 빔 에피택시로 성장시킨 $ZrO_2$ 박막의 특성과 공정변수가 박막 성장률에 미치는 영향)

  • Kim, Myung-Suk;Go, Young-Don;Hong, Jang-Hyuk;Jeong, Min-Chang;Myoung, Jae-Min;Yun, Il-Gu
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07a
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    • pp.452-455
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    • 2003
  • [ $ZrO_2$ ] dielectric layers were grown on the p-type Si (100) substrate by metalorganic molecular beam epitaxy(MOMBE). Zrconium t-butoxide, $Zr(O{\cdot}t-C_4H_9)_4$ was used as a Zr precursor and Argon gas was used as a carrier gas. The thickness of the layers was measured by scanning electron microscopy (SEM) and the properties of the $ZrO_2$ layers were evaluated by X-ray diffraction, high frequency capacitance-voltage measurement. and HF C-V measurements have shown that $ZrO_2$ layer grown by MOMBE has a high dielectric constant (k=18-19). The growth rate is affected by various process variables such as substrate temperature, bubbler temperature, Ar, and $O_2$ gas flows.

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Molecular Diffusion of Water in Paper(II)-Water-diffusion theory on pore structure of paper- (종이내 수분확산(제2보)-종이의 공극구조에 의한 수분확산 이론-)

  • Yoon, Sung-Hoon;Jeon, Yang
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.30 no.3
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    • pp.46-56
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    • 1998
  • The objective of this study was to investigate the relationship between water vapor diffusion properties and the pore structure of paper. Gas-phase molecular diffusivity of water vapor through pores was determined based on the kinetic theory of gas. A mathematical model was derived to characterize the dimensional changes of the pore caused by the fiber-swelling mechanism. A modified-Fickean diffusion model was designed to simulate the water-vapor diffusion phenomena in porous paper web. Structural characterisocs of paper pores including the tortuosity and the shape factor was studied on a theoretical basis of Knudsen flow diffusion. Results are summarized as follows: 1. The theoretical water vapor diffusivity in gas-phase was 0.092$cm^2$ /min, 2. Porosity was inversely proportional to the degree of wet-swelling of paper, 3. Solid-phase water-diffusivity of fiber was 1.2 $ \times 10^{-5}cm^2/min$, 4. Modified diffusion model was fairly consistent to the experimental data (from part I), and 5. The Fickean pore tortuosity, ranging from 1,000 to 2,500, was in inverse proportion to the porosity of paper, and the Knudsen shape factor and length-angle factor for micro-pores in paper were 0.5~3.5 and about 340, respectively.

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Characteristics of Low-power Microwave Induced Plasma Emission Spectrum and Detection of $CO_2$ (저출력 마이크로파 유도 플라스마 방출스펙트럼의 특성과 $CO_2$ 분석)

  • Noh, Seung Man;Park, Chang Joon;Kim, Young Sang
    • Journal of the Korean Chemical Society
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    • v.40 no.4
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    • pp.235-242
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    • 1996
  • A surfatron-type microwave induced plasma (MIP) cavity has been constructed, which can be easily interfaced with a gas chromatograph. Various plasma gases such as He, Ar and N2 were used to generate the MIP and small amounts of CO2 gases were injected through the MIP to obtain characteristic spectrum of each plasma gas and to study feasibility of the MIP as a soft ionization source. Since He and Ar plasmas have high metastable state energy, it was not possible to detect sample gas in molecular state. With N2 plasma, however, a strong emission of molecular ions could be detected owing to its low metastable state energy.

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Transformation of dissolved organic matter in a constructed wetland: A molecular-level composition analysis using pyrolysis-gas chromatography mass spectrometry

  • Park, Jongkwan;Choi, Mijin;Cho, Jaeweon;Chon, Kyongmi
    • Environmental Engineering Research
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    • v.23 no.4
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    • pp.390-396
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    • 2018
  • This study investigated the transformation of dissolved organic matter (DOM) in a free-water surface flow constructed wetland. Pyrolysis gas chromatography-mass spectrometry (Py-GC/MS) coupled with preparative high-performance liquid chromatography (prep-HPLC) was used to analyze the compositions of biopolymers (polysaccharides, amino sugars, proteins, polyhydroxy aromatics, lipids and lignin) in DOM according to the molecular size at three sampling points of the water flow: inflow, midflow, and outflow. The prep-HPLC results verified the decomposition of DOM through the decrease in the number of peaks from three to one in the chromatograms of the sampling points. The Py-GC/MS results for the degradable peaks indicated that biopolymers relating to polysaccharides and proteins gradually biodegraded with the water flow. On the other hand, the recalcitrant organic fraction (the remaining peak) in the outflow showed a relatively high concentration of aromatic compounds. Therefore, the ecological processes in the constructed wetland caused DOM to become more aromatic and homogeneous. This indicated that the constructed wetland can be an effective buffer area for releasing biochemically stable DOM, which has less influence on biological water quality indicators, e.g., biochemical oxygen demand, into an aquatic ecosystem.

Properties of Pressure-Sensitive Rubber Adhesive in a Heat Shrinkable Sheet for the Protection of Welded Part of Gas Pipe Line (가스 배관 용접부 방식용 열 수축 쉬-트의 고무계 점착제 물성)

  • Song Sung-Ku;Hwang Kyu-Suk;Kim Wonho;Chung Kyung-Young;Bae Jong-Woo;Choi Heung-Hwan;Lee Seong-Min;Shin Sung-Sik
    • Journal of the Korean Institute of Gas
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    • v.2 no.3
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    • pp.1-11
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    • 1998
  • To increase peel strength, low temperature properties and flowability of pressure sensitive adhesives(PSA) used in a heat shrinkable sheet, these properties were evaluated by changing each components in type and content. In this study, Isobutylene-co-Isoprene Rubber (IIR) which has good wetherability was selected as a base polymer. Instead of rosin ester, petroleum resin was selected as a tackifier because of superior peel strength. By decreasing petroleum resin contents, flowability of PSA was decreased. High molecular weight of polybutene was better than low molecular weight for the peel strength of PSA. Large particle size of carbon black showed better properties than small one in peel strength and brittleness temperature. By adding calcium carbonate, the cost of compound was able to be reduced. But it must be used with carbon black.

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