• Title/Summary/Keyword: moisture stability

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Synthesis and Characterization of the Thermally Stable Ho(hfa)3(tme)

  • Kang, Seong-Joo
    • Bulletin of the Korean Chemical Society
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    • v.25 no.8
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    • pp.1207-1210
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    • 2004
  • Holmium $\beta$ -diketonate complexes, Ho(hfa)$_3$(tme), has been prepared and characterized by IR, TGA, MS, and single-crystal X-ray analyses. This complex is air- and moisture-stable and most importantly has good volatility and thermal stability. Holmium atom binds to nine oxygen atoms, contributed by six oxygen atoms of three hfa ligands and three oxygen atoms of the tme ligand. The coordination polyhedron of Ho can be described as a distorted tricapped trigonal prism. Crystal data for $Ho(hfa)_3(tme)$; orthorhombic $P2_12_12_1$, a = 15.415(4), b = 13.17(2), c = 17.291(3) $\AA$, V = 3496(1) ${\AA}^3$.

Characteristics of Lightning Impulse Current of ZnO Block for Transmission Line Arrester with External Gap (송전선로에 사용되는 갭형 피뢰기 소자의 뇌임펄스 전류특성)

  • Cho, Han-Goo;Yoo, Dae-Hoon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.458-459
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    • 2007
  • This paper describes the characteristics of lightning impulse current of ZnO block for transmission line arrester with external gap. The ageing parameters of lightning arresters are impulse current, moisture ingress, temperature ageing and so on. Especially it is important to estimate the change of electrical characteristics by impulse current. Total energy applied to the ZnO arrester each time is $4/10{\mu}s$, 30kA and $2/20{\mu}s$, 10kA impulse current. Before and After the test, the residual voltage variation of varistors passed was below 5%. According to the test, it is thought that the ZnO arrester shows good stability with impulse current test.

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Modeling of Drying Cylinders in Paper Plants (제지공장 가열 실린더의 모델링)

  • Kwak, Ki-Young;Yeo, Young-Gu;Kim, Young-Gon;Choi, Kyung-Seok;Kang, Hong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.35 no.4
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    • pp.57-67
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    • 2003
  • The purpose of the present study is to identify the drying cylinder model in paper plants and to analyze characteristics of process responses for changes in input variables. The model developed in this work is based on actual plant operation data and the steam pressure applied to the cylinder behaves as one the main variables. It is found that heat transfer coefficients from the condensate to the canvas could be represented as empirical relations based on heat conductivities and operation date. The effectiveness of the cylinder model is demonstrated by the measured moisture contents and web temperature. Using transfer functions derived from the cylinder model stability of the drying process is analyzed.

Synthesis and Characterization of Volatile and Thermally Stable Europium β-Diketonate Complexes

  • 강성주;정영숙
    • Bulletin of the Korean Chemical Society
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    • v.18 no.1
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    • pp.75-80
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    • 1997
  • Preparation and properties of Eu(hfa)3·L (Hhfa = hexafluoroacetylacetone, L = bis(2-methoxyethyl)ether, diglyme, and 2, 2':6', 2"-terpyridine, tpy), which are potential CVD precursors for europium, were investigated. The reaction of the Eu2O3 with Hhfa in the presence of tridentate neutral ligand yielded the nine-coordinated Eu(hfa)3·L. Eu(hfa)3·diglyme is air- and moisture-stable and most importantly has good volatility and thermal stability. Eu(hfa)3·tpy shows no sublime intact. The complex Eu(hfa)3·diglyme has been characterized by an X-ray structure determination; monoclinic P21/n, a=10.252(1), b=16.051(6), c=19.392(8) Å, β=96.10(2)°, V=3173(2) Å3. The europium atom in Eu(hfa)3·diglyme adopts a square-antiprismatic geometry with the ninth coordinating oxygen atom capping one of the square faces. All the adducts have been characterized by IR, TGA/DTA.

The Analysis of Forest Fire Danger Rating Using Haines Index (Haines Index를 이용한 산불위험도 분석)

  • Lee, Si-Young;Jung, Kwang-Woo
    • Journal of agriculture & life science
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    • v.44 no.6
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    • pp.69-78
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    • 2010
  • Haines index which include the rating of atmosphere instability and dryness indicated the potential of the forest fire danger. In this study, the relationships between forest fire occurrence and Haines index were analyzed. The probability of forest fire occurrence was the highest in April and HI 5, 6 and the dryness of atmosphere was higher than the atmosphere instability. Therefore, It was proved that HI affected on the forest fire occurrence and propagation.

Furfurylation Effects on Discoloration and Physical-Mechanical Properties of Wood from Tropical Plantation Forests

  • HADI, Yusuf Sudo;HERLIYANA, Elis Nina;PARI, Gustan;PARI, Rohmah;ABDILLAH, Imam Busyra
    • Journal of the Korean Wood Science and Technology
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    • v.50 no.1
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    • pp.46-58
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    • 2022
  • Wood from tropical plantation forests has lower physical and mechanical properties than mature wood. Furfuryl alcohol (FA) impregnation into the wood could help to enhance hydrophobic properties, dimensional stability, and structural strength. Furfurylation was applied to specimens of the following four fast-growing tropical wood species: jabon (Anthocephalus cadamba), sengon (Falcataria moluccana), mangium (Acacia mangium), and pine (Pinus merkusii). The discoloration and physical and mechanical properties were subsequently measured, and the results showed that furfurylated wood had a darker color and better physical and mechanical properties than untreated wood. Specifically, the furfurylated wood had higher density, modulus of elasticity, and hardness and lower moisture content, water absorption, swelling, and shrinkage. The furfurylation significantly enhanced physical and mechanical properties.

Study on Press-drying of Italian Poplar Board and its Effect on Improvement of Wood Property (이태리포푸라재(材)의 건조성(乾燥性) 및 성질개선(性質改善)에 관(關)한 연구(硏究))

  • Jung, Hee Suk
    • Journal of Korean Society of Forest Science
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    • v.37 no.1
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    • pp.17-30
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    • 1978
  • Press drying was used on italian poplar (Populus euamericana) to find the profitable means of drying. This study was designed to investigate the process of platen drying considering core temperature, drying time, current moisture content, drying rate, shrinkage and recovery, and green volume specific gravity, equilibrium moisture content and dimensional stability of press dried material and air dried material, The drying tests were conducted using 1.5 centimeter thick material at platen temperature of $175^{\circ}C$. The results were summarized as follows. 1. Core temperature was divided into three stages of drying characterized by period initial heating, plateau temperature and rising core temperature. Plateau temperature was 114 to $119^{\circ}C$. 2. The following predicting equations of drying time(y) in different core temperatures were developed for initial thickness($x_1$), initial moisture content ($x_2$) and final moisture content ($x_3$) 3. The predicting equaltion of current moisture content(u) was log u=4.658-0.060t as funtion of drying time(t) and that of drying rate(r) was log r=-2.797-0.049t. Current moisture content and drying rate of air drying were shown in figure 2. 4. The predicting equation of shrinkage in thickness direction(y) was log y=1.933+0.038t as function of drying time(t), and that of expansion in width direction was $y=-0.692+0.043t-0.001t^2$. 5. Thickness shrinkage was increased more than proportional at to pressure increase. Width shrinkage and thickness recovery was greatest at 35psi. 6. Green volume specific gravity of press dried material was 25% greater than that of air dried material. But equilibrium moisture content of press dried material was less 24% than that of air dried material. Antishrinkage efficiency of press dried material were obtained 27.7%.

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Moisture Sorption Characteristics of Powdered Soybean Curd (분말(粉末) 두부의 수분흡착(水分吸着) 특성(特性))

  • Kim, Dong-Man;Chang, Kyu-Seob;Yoon, Han-Kyo
    • Korean Journal of Food Science and Technology
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    • v.12 no.4
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    • pp.292-298
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    • 1980
  • In order to improve the storage stability of powdered soybean curd, moisture sorption characteristics of the curd stored at specific relative humidity and temperature were investigated. The results obtained are summarized as follows; 1. When the fresh soybean curd (2cm thickness) was dried in a hot air drier at $55^{\circ}C$, it took 18 hrs to reduce its moisture content from 85% to 8.8%, and drying rate was very high during the first 5 hrs. 2. Equilibrum moisture content (E.M.C.) of powdered soybean curd by freeze drying was higher than that of sample by got air drying, but the particle size did not influence E. M. C. 3. The monolayer value of freeze dried powder of high E. M. C was higher than that of the hot air dried(8.30 vs 7.35). 4. The free energy for moisture absorption of freeze dried powder at 11% RH were 1285.1 cal/mole, 1323.5 cal/mole at $15^{\circ}C$ and $30^{\circ}C$, respectively, and the free energy of freeze dried product was lower that of hot air dried product. 5. The moisture sorption rate constant was not affected by particle size, and it showed that the moisture sorption rate decreased as temperature was increased. The rate constant of powder produced by freeze drying were 0.00804 at $15^{\circ}C$ and 0.00696 at $30^{\circ}C$.

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Fundamental Properties of Asphalt Concrete Mixture as Using TDF Fly Ash as Mineral Filler (아스팔트 콘크리트 채움재로 TDF Fly Ash 적용에 따른 아스팔트 혼합물 기초 물성 평가)

  • Choi, Min-Ju;Kim, Hyeokjung;Kim, Yongjoo;Lee, Jaejun
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.37 no.2
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    • pp.497-505
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    • 2017
  • TDF (Tire derived fuel) Fly ash is an industrial by-product when scraped tire was used a fuel source at the power plant. TDF Fly ash has been classified as domestic waste at the workplace so far and has not been appropriately utilized. We conducted a fundamental physical property test of asphalt mixture to investigate the possibility of using TDF Fly ash as a mineral filler of asphalt mixture for exploring new usage strategies. TDF Fly ash meets KS F 3501 asphalt mixture mineral filler criteria. And the optimal asphalt binder amount was determined to be 4.5% by Marshall design. Mineral filler content was determined at 3% and analyzed by comparing using mineral filler as stone powder. The basic physical property test of the asphalt mixture was evaluated to the provision indicated in "Production and Construction Guidelines for Asphalt Mixture" published by the Ministry of Land, Infrastructure and Transport. In the test, Marshall stability test, dynamic immersion test, tensile strength ratio test, wheel tracking test were carried out. As a result of the experiment, Marshall stability and dynamic stability satisfied the standards, and confirmed the stability and Dynamic immersion and tensile strength ratio test that TDF Fly ash is more effective for scaling and moisture resistance than stone dust. Therefore, in this research, it is expected that multilateral utilization of TDF Fly ash, and a positive effect can be also expected.

Stability Evaluation of Vitamin-C Inclusion Complexes Prepared using Supercritical ASES Process (초임계 ASES 공정으로 제조된 Vitamin-C 포접복합체의 안정성 평가)

  • Yang, Jun-Mo;Kim, Seok-Yun;Han, Ji-Hyun;Jung, In-Il;Ryu, Jong-Hoon;Lim, Gio-Bin
    • KSBB Journal
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    • v.21 no.2
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    • pp.157-163
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    • 2006
  • A supercritical fluid process, called aerosol solvent extraction system(ASES), is especially suitable to the pharmaceutical, cosmetic and food industries due to its environmentally-friendly, non-toxic and residual solvent-free properties. In particular, the application of the ASES process to the processing of thermo-labile bioactive compounds has received attention of many scientists and engineers because of its low-temperature operating conditions. Unstable substances such as Vitamin-C and Vitamin-A can be effectively protected from degradation during the preparation process, because the ASES process is free from oxygen and moisture. In this study, Vitamin-C was formulated with 2-hydroxypropyl-${\beta}$-cyclodextrin (HP-${\beta$-CD) for enhancement of Vitamin-C stability and bioavailability using the ASES process. To investigate the influence of the preparation process on the stability of Vitamin-C, Vitamin-C/HP-${\beta}$-CD inclusion complexes were prepared using both conventional solvent evaporation method and ASES process, and stored in a 50 mM phosphate buffer solution of pH 7.0 at $25^{\circ}C$ for 24 hours. From the experimental results, the stability of the Vitamin-C/HP-${\beta}$-CD inclusion complex prepared from the ASES process was found to be much higher than that of pure Vitamin-C and the Vitamin-C/HP-${\beta}$-CD inclusion complex prepared by the solvent evaporation method. The stability of Vitamin-C was observed to increase with the decrease of temperature at a constant pressure or with the increase of pressure at a constant temperature.