• Bulletin of the Korean Chemical Society
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• v.27 no.10
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• pp.1542-1548
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• 2006

Maleimide modified epoxy compounds were prepared by reacting N-(4-hydroxyphenyl) maleimide (HPM) with diglycidylether of bisphenol-A. Triphenylphosphine was used as catalyst and methylethylketone as solvent. The resulting compound possessed both the oxirane ring and maleimide group. The curing reaction of the maleimide epoxy compound with amine curing agents such as 1-(2-aminoethyl) piperazine (AEP) and 5-amino-1,3,3-trimethylcyclohexane methylamine isophorone diamine, IPDA) were studied. Incorporation of maleimide groups in the epoxy resin provides cyclic imide structure and high cross-linking density to the cured resins. The cured samples were found to have good thermal stability, chemical resistance (acid/alkali/solvent) and water absorption resistance.

• 한국생물공학회:학술대회논문집
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• 2003.04a
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• pp.635-638
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• 2003

For the acute assessment on biological toxicity of wastewater, surface plasmon resonance(SPR) based cell viability detection was performed using gold surface-confined cell as a result of adhesion-modifying chemicals. Escherichia coli O157:H7 (E. coli O157:H7) was investigated after exposure to EDTA. Cells were immobilized on gold coated slide glass for SPR analysis by the method of cross-linking carboxyl group on the bacterial surface with amine group of poly-L-lysine that had been coupled to the gold surface modified by a self-assembled monolayer of 11-mercaptounde canoic acid (11-(MUA)). Reflective intensity of each flow step was changed with respect to confect of ethylenediaminetetraacetic acid (EDTA) disodium salt and phosphate-buffered saline (PBS) solution. The proposed detection technique can be used for biological toxicity test.

• Journal of Integrative Natural Science
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• v.4 no.3
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• pp.182-186
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• 2011

Chemical modification of porous silicon surface has been investigated to have different physical surface properties. Porous silicon modified with dodecyl functionality exhibits hydrophobic feature, however the oxidation of porous silicon to modify with hydroxyl group displays hydrophilic properties. Surface characterization for both dodecyl and hydroxyl derivatized porous silicon was investigated by FT-IR spectroscopy. To determine the surface coverage, the amine functionalized surface was reduced by dithiothreitol (DTT) and the released 2-thiopyridone was quantified by UV/vis spectroscopy.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2003.10a
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• pp.111-114
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• 2003

Thermosets are highly cross-linked polymers with a three-dimensional molecular structure. The network structure gives rise to mechanical properties, however, one major drawback of thermosets, which also results from their network structure, is their poor resistance to impact and to crack initiation. In this study, to solve this problem, the reactive thermoplastics such as amine terminated polyetherimide (ATPEI), ATPEI-CTBN-ATPEI(ABA) triblock copolymer, CTBN-ATPEI(AB) diblock copolymer, and carboxyl group modified ATPEI was synthesized, after that blended with epoxy resin, and the carbon fiber reinforced composites were fabricated. The impact load, energy, and delamination were investigated by using drop weight impact test and C-scan test. As a results, the ABA/epoxy blend system showed good impact properties.

• Journal of the Korean Chemical Society
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• v.32 no.5
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• pp.409-415
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• 1988

In this study, an aniline modified Bakelite-A resine was synthesized by polymerizing phenol, formaldehyde and aniline. Structural properties of the polymer were examined by IR spectroscopy, elemental analysis and vapour pressure osmometry. By visible spectroscopy, it was found that nitrogens of amine groups in the polymer are strongly coordinated to Ni(Ⅱ). Also a nitrate ion-selective PVC membrane electrode based on the polymer-Ni(Ⅱ) complex as ion carrier was preparaed. The electrode gave a linear response with a Nernstian slope within the concentration range $10^{-1}$ M∼$10^{-4}$M $KNO_3$.

• Textile Coloration and Finishing
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• v.7 no.2
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• pp.1-8
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• 1995

Polymer cationic agent was prepared by the initial polymerization of epichlorohydrin followed by amination with diethyl-amine. Cotton fibre treated with the polymer (6∼8% o.w.f.) is highly cationic and exhibit increased substantivity for anionic dyes. The modified substrate could be dyed with direct dyes without salt or a little salt from dye bath. The increased concentration of cationic agents resulted in an increase the colour yield. Futhermore, treated cotton has an electropositive surface charge. Adsorption of direct dye can be attributed to both van der waals force and electrostatic attraction.

• Textile Coloration and Finishing
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• v.7 no.2
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• pp.70-76
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• 1995

The polyepichlorohydrine(poly(ECH)) was prepared by the condensation polymerization of epichlorohydrine. The cationic agent was prepared from poly(ECH) by amination of poly(ECH) with dimethyleneamine. Pretreatment of cellulosic fabric with the poly(ECH)amine produced a modified fabrics that could be dyed under neutral condition with reactive dye using small amount of the salt. Colour yield of cellulosic fabric were increased by increasing salt concentraction. cationic agent concentration. The optimum condition for colour yield was the concentration of cationic agent 5%(o.w.f), that of NaCl 4g/l, and that of $Na_{2}CO_{3}$5g/l. The dyeing of treated fabrics exhibits improved colour yield and high wash fastness.

• Bulletin of the Korean Chemical Society
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• v.33 no.6
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• pp.2043-2046
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• 2012

• Journal of the Korean Chemical Society
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• v.57 no.3
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• pp.361-364
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• 2013

A modified synthetic approach to the synthesis of heterocyclic food mutagens, 2-amino-1-methyl-6-phenylimidazo[4,5-b]pyridine (PHIP) and 2-amino-1,6-dimethylimidazo[4,5-b]pyridine (DMIP) is reported. This route highlights an optimized palladium catalysed Buchwald cross-coupling of 2-halo-1-methyl-imidazo[4,5-b]pyridine with benzophenoneimine followed by acidic hydrolysis to yield compound 7. Using finely tailored conditions, Suzuki cross-coupling reactions with highly efficient catalytic systems were performed as the final step on 8 to introduce the aryl group and methyl group on the heterocyclic core.

• Archives of Pharmacal Research
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• v.23 no.3
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• pp.202-205
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• 2000

A convenient pathway for synthesis of trans-metanicotine analogues was developed. trans-Metanicotine, a subtype(${\alpha}4{\beta}2$)-selective ligand for neuronal nicotinic acetylcholine receptor, is under clinical phase for Alzheimer's disease. Zn-mediated allylation of allyl bromide and acetaldehyde followed by Heck reaction with 3-bromopyridine gave 5-pyridin-3-yl-pent-4-en-3-ol (2). Tosylation of 5-pyridin-3-yl-pent-4-en-3-ol followed by substitution reaction with methylamine in sealed tube gave methyl-(1-methyl-4-pyridin-3-yl-but-3-enyl)-amine (4) in good yields. Thus, trans-metanicotine analogues modified at the $\alpha$-position of the methylamino group with various functional groups can be obtained in 4 steps.