• Title/Summary/Keyword: modification coefficient

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Calculation of the Activity Coefficients of Ions in Weak Electrolyte Solutions (묽은 전해질용액에서 이온의 활동도계수 계산)

  • Lee, Man-Seung;Son, Seong Ho
    • Resources Recycling
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    • v.27 no.5
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    • pp.9-13
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    • 2018
  • The equilibrium constant of a chemical reaction is related to the standard Gibbs free energy change. Since equilibrium constant is defined as the ratio of the activities of the chemical species, it is necessary to consider the non-ideal behavior of the solutes as ionic strength of the solution increases. In this paper, the derivation of Debye-$H{\ddot{u}}ckel$ limiting law and its modification by which the activity coefficient of an ion can be calculated was explained. Moreover, the method to obtain the activity coefficient of an ion from the experimentally determined mean activity coefficients of an electrolyte was explained.

Reynolds number effects on twin box girder long span bridge aerodynamics

  • Kargarmoakhar, Ramtin;Chowdhury, Arindam G.;Irwin, Peter A.
    • Wind and Structures
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    • v.20 no.2
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    • pp.327-347
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    • 2015
  • This paper investigates the effects of Reynolds number (Re) on the aerodynamic characteristics of a twin-deck bridge. A 1:36 scale sectional model of a twin girder bridge was tested using the Wall of Wind (WOW) open jet wind tunnel facility at Florida International University (FIU). Static tests were performed on the model, instrumented with pressure taps and load cells, at high wind speeds with Re ranging from $1.3{\times}10^6$ to $6.1{\times}10^6$ based on the section width. Results show that the section was almost insensitive to Re when pitched to negative angles of attack. However, mean and fluctuating pressure distributions changed noticeably for zero and positive wind angles of attack while testing at different Re regimes. The pressure results suggested that with the Re increase, a larger separation bubble formed on the bottom surface of the upstream girder accompanied with a narrower wake region. As a result, drag coefficient decreased mildly and negative lift coefficient increased. Flow modification due to the Re increase also helped in distributing forces more equally between the two girders. The bare deck section was found to be prone to vortex shedding with limited dependence on the Re. Based on the observations, vortex mitigation devices attached to the bottom surface were effective in inhibiting vortex shedding, particularly at lower Re regime.

An experimental study on the characteristics of the swirl ratio distribution with an intake port geometry (흡기포트 형상에 따른 선회비 분포특성에 관한 실험적 연구)

  • Lee, Ji-Geun;Ju, Bong-Cheol;No, Byeong-Jun;Gang, Sin-Jae
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.21 no.6
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    • pp.725-734
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    • 1997
  • The effect of helical intake port geometry on in-cylinder swirl flow characteristics was studied. Two helical intake ports were selected to change swirl ratio, mean flow coefficient with the variation of valve lifts, valve eccentricity ratios and axial distance. The measurements were made by using an impulse swirl meter. The port B modified to increase the swirl ratio( $R_{s}$) had the tendency of the increased non-dimensional rig swirl ( $N_{r}$) distribution in comparison with that of the port A. And the $N_{r}$ distribution was remarkably improved at low valve lifts. The modification of the geometry to increase the swirl ratio ( $R_{s}$) in helical intake port resulted in the decrease of the mean flow coefficient ( $C_{f(mean)}$) regardless of valve eccentricity ratio ( $N_{y}$). And also non-dimensional rig swirl ( $N_{r}$) in the high valve lift affected the calculation of swirl ratio considerably.onsiderably.

Initial stiffness and moment capacity assessment of stainless steel composite bolted joints with concrete-filled circular tubular columns

  • Wang, Jia;Uy, Brian;Li, Dongxu
    • Steel and Composite Structures
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    • v.33 no.5
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    • pp.681-697
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    • 2019
  • This paper numerically assesses the initial stiffness and moment capacity of stainless steel composite bolted joints with concrete-filled circular tubular (CFCT) columns. By comparing with existing design codes including EN 1993-1-8 and AS/NZS 2327, a modified component method was proposed to better predict the flexural performance of joints involving circular columns and curved endplates. The modification was verified with independent experimental results. A wide range of finite element models were then developed to investigate the elastic deformations of column face in bending which contribute to the corresponding stiffness coefficient. A new design formula defining the stiffness coefficient of circular column face in bending was proposed through regression analysis. Results suggest that a factor for the stiffness coefficient of endplate in bending should be reduced to 0.68, and more contribution of prying forces needs to be considered. The modified component method and proposed formula are able to estimate the structural behaviour with reasonable accuracy. They are expected to be incorporated into the current design provisions as supplementary for beam-to-CFCT column joints.

Modification of Thin Film Friction and Wear Models with Effective Hardness

  • Kim, Chang-Lae;Kim, Hae-Jin
    • Tribology and Lubricants
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    • v.36 no.6
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    • pp.320-323
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    • 2020
  • Thin film coatings are commonly exploited to minimize wear and optimize the frictional behavior of various precision mechanical systems. The enhancement of thin film durability is directly related to the performance maximization of the system. Therefore, a fine approach to analyze the thin film wear behavior is required. Archard's equation is a representative and well-developed law that defines the wear coefficient, which is the probability of creating wear particles. A ploughing model is a commonly used model to determine the friction force during the abrasive contact. The equations demonstrate that the friction force and wear coefficient are inversely proportional to the hardness of the material. In this study, Archard's equation and ploughing models are modified with an effective hardness to minimize the gap between the experimental and numerical results. It is noted that the effective hardness is the hardness variation with respect to the penetration depth owing to the substrate effect. The nanoindentation method is utilized to characterize the effective hardness of Cu film. The wear coefficient value considering the effective hardness is more than three times higher than that without considering the effective hardness. The friction force predicted with the effective hardness agreed better with the results obtained directly from the friction force detecting sensor. This outcome is expected to improve the accuracy of friction and wear amount predictions.

Strength Demand Calculation for Retrofitting Unreinforced Masonry Buildings Based on the Displacement Coefficient Method and the Preliminary Seismic Evaluation Procedure (변위계수법 및 약산식 내진성능평가에 기초한 비보강 조적조 건물의 내진보강 요구강도 산정)

  • Seol, Yun Jeong;Park, Ji-Hun;Kwak, Byeong Hun;Kim, Dae Ho
    • Journal of the Earthquake Engineering Society of Korea
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    • v.26 no.1
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    • pp.31-38
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    • 2022
  • Based on the nonlinear static analysis and the approximate seismic evaluation method adopted in "Guidelines for seismic performance evaluation for existing buildings, two methods to calculate strength demand for retrofitting individual structural walls in unreinforced masonry buildings are proposed." The displacement coefficient method to determine displacement demand from nonlinear static analysis results is used for the inverse calculation of overall strength demand required to reduce the displacement demand to a target value meeting the performance objective of the unreinforced masonry building to retrofit. A preliminary seismic evaluation method to screen out vulnerable buildings, of which detailed evaluation is necessary, is utilized to calculate overall strength demand without structural analysis based on the difference between the seismic demand and capacity. A system modification factor is introduced to the preliminary seismic evaluation method to reduce the strength demand considering inelastic deformation. The overall strength demand is distributed to the structural walls to retrofit based on the wall stiffness, including the remaining walls or otherwise. Four detached residential houses are modeled and analyzed using the nonlinear static and preliminary evaluation procedures to examine the proposed method.

Aerodynamic modification of setback distance at half height of the tall building to minimize the wind effect

  • Bairagi, Amlan Kumar;Dalui, Sujit Kumar
    • Wind and Structures
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    • v.35 no.3
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    • pp.193-211
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    • 2022
  • The present study focuses on aerodynamic parameters behaviors and control on the single and double side setback building models at the buildings mid-height. The study is conducted by computational fluid dynamics (CFD) simulation. This study estimates the face wise pressure coefficient on single side setback buildings with a setback range of 20%-50% and double side setback buildings with setbacks ranging from 10%-25%. The polynomial fitted graphs from CFD data predict the Cp on different setback model faces within permissible limit ±13% error. The efficient model obtained according to the minimum drag, lift, and moment consideration for along and across wind conditions. The study guides the building tributary area doesn't control the drag, lift, and moment on setback type buildings. The setback distance takes a crucial role in that. The 20% double side setback model is highly efficient to regulate the moment for both along and across wind conditions. It reduces 17.5% compared to the 20% single side setback and 14% moment compared to the 10% double side setback models. The double side setback building is more efficient to control 4.2% moment than the single side setback building

A Study on the Development of Low Reynolds Number k-$\varepsilon$ Turbulence Model (저레이놀즈수 k-$\varepsilon$난류모형 개선에 관한 연구)

  • 김명호;신종근;최영돈
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.16 no.10
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    • pp.1940-1954
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    • 1992
  • Fine grid computations were attempted to analyze the turbulent flows in the near wall low Reynolds number region and the numerical analyses were incorporated by a finite-volume discretization with full find grid system and low Reynolds number k-.epsilon. model was employed in this region. For the improvement of low Reynolds number k-.epsilon. model, modification coefficient of eddy viscosity $f_{\mu}$ was derived as a function of turbulent Reynolds number $R_{+}$ and nondimensional length $y^{+}$ from the concept of two length scales of dissipation rate of turbulent kinetic energy. The modification coefficient $f_{\epsilon}$ in .epsilon. transport equation was also derived theoretically. In the turbulent kinetic energy equation, pressure diffusion term was added in order to consider low Reynolds number region effect. The main characteristics of this low Reynolds number k-.epsilon. model were founded as : (1) In high Reynolds number region, the present model has limiting behavior which approaches to the high Reynolds number model. (2) Present low Reynolds number k-.epsilon. model dose not need additional empirical constants for the transport equations of turbulent kinetic energy and dissipation of turbulent kinetic energy in order to consider wall effect. Present low Reynolds number turbulence model was tested in the pipe flow and obtained improved results in velocity profiles and Reynolds stress distributions compared with those from other k-.epsilon. models.s.s.

A Numerical Study on the Effect of the Cylinder Shape Modification on the Forced Convection Around a Circular Cylinder (실린더 형상 변화가 실린더 주위 강제대류에 미치는 영향에 관한 수치적 연구)

  • Kim, Min-Ho;Ha, Man-Yeong;Yoon, Hyun-Sik;Lee, Jin-Wook
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.23 no.10
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    • pp.670-677
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    • 2011
  • Direct numerical simulation are performed in order to investigate the effect of the circular cylinder shape on the forced convection around a circular cylinder at the Reynolds number of 300 and Prandtl number of 0.71. Three-dimensional characteristics of fluid flow and heat transfer around the smooth, wavy and torsional cylinders are investigated. A wavy cylinder has the sinusoidal variation in the cross sectional area along the spanwise direction with the wave length of ${\pi}/3$ and wavy amplitude of 0.1. A torsional cylinder has the twisted elliptic cross section with a torsional period of ${\pi}/2$ and an axis ratio of 1.35 corresponding to the major axis of 1.15 and the minor axis of 0.85. The value of time-and surface-averaged drag coefficient for the smooth cylinder is similar to that for the wavy cylinder, but larger than that for the torsional cylinder. The time and surface-averaged lift coefficient for the smooth cylinder is larger than that for the wavy and torsional cylinders. The time-averaged local heat transfer rate for the wavy and torsional cylinders shows different distribution along the circumferential direction, compared to that for the smooth cylinder because of the shape change in the spanwise direction for the cases of the wavy and torsional cylinders.

Studies on the Functional Properties of Modified Soy Protein Isolate (변형대두 단백질의 기능 특성에 관한 연구)

  • Kim, Young-Sug;Hwang, Jae-Kwan;Cho, Eun-Kyung;Lee, Shin-Young;Pyun, Yu-Ryang
    • Korean Journal of Food Science and Technology
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    • v.17 no.5
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    • pp.383-388
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    • 1985
  • Soy protein isolate was acylated with succinic anhydride and acetic anhydride. The functional properties are markedly improved by acylation of the $\varepsilon$-amino groups. Acylation of the available amino groups shifted the isoelectric point from 4.5 to 4.0 and enhanced the solubility between pH 4.0-6.0. In the 0.03M-$CaCl_2$ solution the solubility of the modified soy protein is much larger than that of the unmodified protein above the isoelectric point. The emulsion properties and foaming properties also improved by the modification and the effects of pH on the properties paralleled its effect on protein solubility. The changes of reduced viscosity with concentration followed Huggin's equation and by modification the intrinsic viscosity of the soy protein increased and the interaction coefficient decreased.

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