• 접착 및 계면
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• 제20권4호
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• pp.155-161
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• 2019

공액분자 나노구조체 계면에서의 전하이동 이방성을 이해하는 것은 유기전계효과트랜지스터(OFET)에서 구조-물성 상관관계를 규명하는데 중요하다. 본 연구에서는 대표적인 코페이셜 적층구조를 가진 6,13-bis(triisopropylsilylethynyl) pentacene (TIPS-pentacene) 유기반도체 단결정과 산화물 계면에서 전하이동도 이방성을 연구하였다. 용매치환공정을 이용해 유기단결정을 산화실리콘 절연체 표면에 성장시키고 유기단결정/산화물 계면에서 전하이동을 유도할 수 있도록 OFET 소자를 완성하였다. TIPS-pentacene OFET에서 최고/최저 전하이동도 이방성은 5.2로 관찰되었다. TIPS-pentacene의 전하이동을 담당하는 공액부의 최인접부와의 상호작용을 분석한 결과, HOMO 준위 커플링과 전하의 호핑 궤도가 전하이동도 이방성에 기여하는 것으로 밝혀졌다. HOMO 준위 커플링에 기반한 전하이동도 이방성의 정량적 예측은 실험결과와 유사하게 나타났다.

• Bulletin of the Korean Chemical Society
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• 제33권3호
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• pp.795-802
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• 2012

Geminate electron-hole recombination in organic solids in the presence of a donor-acceptor heterojunction is studied by computer simulations. We analyze how the charge-pair separation probability in such systems is affected by energetic disorder of the media, anisotropy of charge-carrier mobilities, and other factors. We show that in energetically disordered systems the effect of heterojunction on the charge-pair separation probability is stronger than that in idealized systems without disorder. We also show that a mismatch between electron and hole mobilities reduces the separation probability, although in energetically disordered systems this effect is weaker compared to the case of no energetic disorder. We demonstrate that the most important factor that determines the charge-pair separation probability is the ratio of the sum of electron and hole mobilities to the rate constant of recombination reaction. We also consider systems with mobility anisotropy and calculate the electric field dependence of the charge-pair separation probability for all possible orientations of high-mobility axes in the donor and acceptor phases. We theoretically show that it is possible to increase the charge-pair separation probability by controlling the mobility anisotropy in heterojunction systems and in consequence to achieve higher efficiencies of organic photovoltaic devices.

• BMB Reports
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• 제33권6호
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• pp.541-547
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• 2000

Fluorescence polarization of 1,6-diphenyl-1,3,5-hexatriene (DPH) was used to evaluate the effects of chlorpromazine HCl on the range of the rotational mobility of bulk bilayer structure of the synaptosomal plasma membrane vesicles (SPMV) isolated from a bovine brain. In a dose-dependent manner, chlorpromazine HCl increased the anisotropy (r), limiting anisotropy ($r_{\infty}$) and order parameter (S) of DPH in the membranes. Cationic 1-[4-(trimethylammonio)-phenyl]-6-phenylhexa-1,3,5-hexatriene (TMA-DPH) and anionic 3-[p-(6-phenyl)-1,3,5-hexatrienyl]-phenylpropionic acid (PRO-DPH) were utilized to examine the range of transbilayer asymmetric rotational mobility of the neuronal membranes. The anisotropy (r) of TMA-DPH in the inner monolayer was 0.034 greater than the value of PRO-DPH in the outer monolayer of the membranes. Both cationic TMA-DPH and anionic PRO-DPH were also used to examine the transbilayer asymmetric effects of chlorpromazine HCl on the range of rotational mobility of the membranes. Chlorpromazine HCl have a decreasing effects on the rotational mobility of the bulk bilayer structures and have a greater decreasing effect on the mobility of the inner monolayer as compared to the outer monolayer of the membranes. It has been proven that chlorpromazine HCl exhibit a selective rather than nonselective fluidizing effect within the transbilayer domains of the SPMV.

• The Korean Journal of Physiology and Pharmacology
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• 제4권1호
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• pp.41-46
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• 2000

Using fluorescence polarization of 12-(9-anthroyloxy)stearic acid (12-AS) and 2-(9-anthroyloxy)stearic acid (2-AS), we evaluated the differential effects of local anesthetics on differential rotational rate between the surface (in carbon number 2 and its surroundings including the head group) and the hydrocarbon interior (in carbon number 12 and its surroundings) of the outer monolayer of the total lipid fraction liposome extracted from synaptosomal plasma membrane vesicles. The anisotropy (r) values for the hydrocarbon interior and the surface region of the liposome outer monolayer were $0.078{\pm}0.001$ and $0.114{\pm}0.001,$ respectively. This means that the rate of rotational mobility in the hydrocarbon interior is faster than that of the surface region. In a dose-dependent manner, the local anesthetics decreased the anisotropy of 12-AS in the hydrocarbon interior of the liposome outer monolayer but increased the anisotropy of 2-AS in the surface region of the monolayer. These results indicate that local anesthetics have significant disordering effects on the hydrocarbon interior but have significant ordering effects on the surface region of the liposome outer monolayer.

• The Korean Journal of Physiology and Pharmacology
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• 제4권5호
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• pp.409-415
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• 2000

Fluorescence polarization of 1,6-diphenyl-1,3,5-hexatriene (DPH) was used to evaluate the effects of dopamine HCl on the range of the rotatioanl mobility of bulk bilayer structure of the synaptosomal plasma membrane vesicles (SPMV) isolated from whole bovine brain. In a dose-dependent manner, dopamine decreased the anisotropy $({\gamma}),$ limiting anisotropy $({\gamma}{infty})$ and order parameter (S) of DPH in the membranes. These indicate that dopamine increased the rotational mobility of the probe in the neuronal membranes. Cationic 1-[4-(trimethylammonio)-phenyl]-6-phenylhexa-1,3,5-hexatriene (TMA-DPH) and anionic 3-[p-(6-phenyl)-1,3,5-hexatrienyl]-phenylpropionic acid (PRO-DPH) were utilized to examine the range of transbilayer asymmetric rotational mobility of the neuronal membranes. Dopamine had a greater increasing effect on the mobility of the inner monolayer as compared to the outer monolayer of the neuronal membranes. It has been proven that dopamine exhibits a selective rather than nonselective fluidizing effect within the transbilayer domains of the SPMV.

• BMB Reports
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• 제33권3호
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• pp.279-284
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• 2000

Using fluorescence probes, 2-(9-anthroyloxy) stearic acid (2- AS) and 12-(9-anthroyloxy) stearic acid (12-AS), we determined the differential effects of local anesthetics (tetracaine-HCI, bupivacaine-HCI, lidocaine-HCI, prilocaine-HCI and procaine-HCI) on the differential rotational rate between the surface (in carbon number 2 and its surroundings including the head group) and the hydrocarbon interior (in carbon number 12 and its surroundings) of the outer monolayer of the total phospholipid fraction liposome that is extracted from synaptosomal plasma membrane vesicles. The anisotropy (r) values for the hydrocarbon interior and the surface region of the liposome outer monolayer were$0.051{\pm}0.001$ and $0.096{\pm}0.001,$ respectively. This means that the rate of rotational mobility in the hydrocarbon interior is faster than that of the surface region. Local anesthetics in a dosedependent manner decreased the anisotropy of 12-AS in the hydrocarbon interior of the liposome outer monolayer, but increased the anisotropy of 2-AS in the surface region of the monolayer. These results indicate that local anesthetics have significant disordering effects on the hydrocarbon interior, but have significant ordering effects on the surface region of the liposome outer monolayer.

• 한국통신학회논문지
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• 제19권10호
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• pp.1849-1860
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• 1994

본 논문은 비정질 회토류 천이 급속 박막내에서의 자벽 역학(Magnetic domain wall dynamics)을 란다우 리프쉬츠 길버트 (Landau Lifshitz Gilbert) 방정식을 이용한 수치적 해석을 수행하여 연구하였다. 박막을 이차원 정방형 격자($30\times30$)로 나누고, 각 격자 셀(Cell)에 쌍극자간 존재한다고 상정하여, 이들 쌍극자간의 상호 교환 작용과 자기 이방성, 외부 인가 자계, 그리고 감자계의 영향이 고려되었다. 단축 자기 이방성이 존재하고 역방향의 자화가 존재한다고 가정된 상태에서 자벽이 형성되는 시간과 자벽의 두께를 알아보았다. 또한 외부 자계의 인가에 따른 자벽 이동을 연구하였다. 시뮬레이션 결과, 감자계를 고려했을 때 자벽 형성 시간이 상당히 빨라졌고, 평균 자벽의 이동도(Mobility)는 약간 증가되었다.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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• pp.1107-1110
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• 2006

We investigate the effect of processing temperature of gate insulator and optical anisotropy on organic thin-film transistors (OTFTs). The insulator film which was processed lower temperature than solvent boiling temperature can lead more aligned pentacne molecules compare to higher processed insulator film. It finally gives rise to the big increase of carrier mobility in OTFTs, although there are little difference at the seriously affecting properties to device performance, for example roughness of gate insulator film.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1988년도 추계학술대회 논문집
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• pp.47-49
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• 1988

This paper discusses dynamic properties of bubble garnet thin films. The dynamic properties considered are Gilbert damping parameters, saturation velocity, and wall mobility. The parameters are evaluated to facilitate the search for desirable garnet thin film compositions. Given bubble diameter and Q-value, the computer prints out all compositions which meet the desired requirements. The computer model determines magnetization, anisotropy, damping, velocity, mobility among others from the film compositions. The computer modeling program is described by an algorithm detailing its operation.

• 한국재료학회지
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• 제5권8호
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• pp.1040-1044
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• 1995

Sm의 농도가 각각 0.3, 0.4, 0.6인 세종류인(YSmLuCa)$_3$(FeGe)$_{5}$ $O_{12}$ 가넷트 박막을 LPE법으로 비자성재료인 Gd$_3$Ga$_{5}$ $O_{12}$(GGG)기판상에 성장시켜, 버블 자성재료의 자기적 성질을 조사하였다. 공명폭 ΔH는 4$\pi$Ms의 증가에 따라 증가하였고 Sm 농도의 감소에 따라 감소한다. 수직 자기 이방성에너지 Ku는 Sm증가에 따라 증가하며 같은 Sm농도에서는 4$\pi$Ms의 증가에 따라 증가한다. 자벽 이동도는 4$\pi$Ms의 증가에 따라 증가하며 Sm의 증가에 따라 감소한다. Ms.ΔH의 곱이 일정한 사실로 부터 새로운 자기손실인자 Eι을 구할 수 있으며 이는 Sm의 농도에 의존한다.ι을 구할 수 있으며 이는 Sm의 농도에 의존한다.