• Bulletin of the Korean Chemical Society
• /
• v.15 no.1
• /
• pp.45-52
• /
• 1994

We present a theoretical study of the non-symmetrical A/BC polymeric system. The polymer blends consist of two phases, a pure polymeric phase A on one side and a mixture of polymers B as a compatibilizer and C on the other. The adsorption of homopolymer B to the interface improves the interfacial adhesion between two phases. By employing the functional integral techniques, we derive the mean-field equations and solve them numerically to obtain the interfacial properties including the concentration profiles in the limit of infinite molecular weight for the polymers. Thecalculations of the interfacial properties are performed for typical values of the Flory X parameters and the volume fraction of polymer B in the asymptotic mixture phase. The interfacial adsorption of polymer B and the degrees of the specific interaction between the polymers play an important role in modification of the interfacial properties.

• Computers and Concrete
• /
• v.10 no.1
• /
• pp.19-33
• /
• 2012

The performance of a concrete is significantly influenced by its mixture proportion and the coating thickness on aggregate surface. The concrete in this study is designed by estimating the blending ratio of aggregate using a densified mixture design algorithm (DMDA) based on an ideal grading curve and estimating the paste volume as the sum of the amount of paste needed to provide an assigned coating paste thickness. So as to obtain appropriate concrete amount, and thus can accurately estimate the property of concrete. Deduction of this mix design formula is simple and easy understanding, and meanwhile to obtain result is fast. This estimation model of mix design is expected to reward to industry and effectively upgrade concrete quality.

• Journal of ILASS-Korea
• /
• v.2 no.4
• /
• pp.47-53
• /
• 1997

By using a premixed laminar burner, the effect of mixture component on laminar burning velocity($S_L$) was investigated. The following was made clear ; (1)As the humidity$(H_2O)$, $CO_2$ and Ar in mixture is increased, $S_L$ decreased in proportion to quantity of those dilution gases. (2) The heat reaction theory says that mean thermal conductivity $(\lambda_m)$, specific heat $(C_{pm})$ of mixture and adiabatic flame temperatures $(T_b)$ affect $S_L$. As a result of theoretical analysis, the effect of $\lambda_m\;and\;C_{pm}$ on $S_L$ is less than 1/25 of the effect of $T_b$, so the effect of $\lambda_m\;and\;C_{pm}$ can be ignored. (3) From experimental results, it was confirmed that $\ln(S_L)$ is proportional to $(1/T_b)$, that is, the effect of $H_2O$ on $S_L$ is mainly caused by changes of $T_b$. This conclusion was verified by the fact increases of $H_2O,\;CO_2$ and Ar decrease the intensity of radiation typical $C_2$, CH, and OH in the same manner.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2005.07a
• /
• pp.405-406
• /
• 2005

A theoretical investigation of the solid-phase mechanochemical synthesis of nano-sized target product on the basis of dilution of the initial powdered reagent mixture by another product of an exchange reaction is presented. On the basis of the proposed 3-mode particle size distribution in mechanically activated mixture, optimal molar ratios of the components in mixture are calculated, providing the occurrence of impact-friction contacts of reagent particles and excluding aggregation of the nanosized particles of the target reaction product. Derivation of kinetic equations for mechanochemical synthesis of nanoscale particles by the final product dilution method in the systems of exchange reactions is submitted. On the basis of obtained equations the necessary times of mechanical activation for complete course of mechanochemical reactions are designed. Kinetics of solid phase mechanosynthesis of nano-TlCl by dilution of initial (2NaCl + $Tl_2SO_4$) mixture with the exchange reaction product (diluent, $zNa_2SO_4$, $z=z^*=11.25$) was studied experimentally. Some peculiar features of the reaction mechanism were found. Parameters of the kinetic curve of nano-TlCl obtained experimentally were compared with those for the model reaction KBr + TlCl + zKCl = (z + 1) KCl + TlBr ($z=z_l^*=13.5$), and for the first time the value of mass transfer coefficient in a mechanochemical reactor with mobile milling balls was evaluated. Dynamics of the size change was followed for nanoparticle reaction product as a function of mechanical activation time.

• Journal of ILASS-Korea
• /
• v.26 no.4
• /
• pp.212-218
• /
• 2021

The present study aims to develop the Surface Plasmon Resonance (SPR) imaging system facilitating the real-time measurement of the concentration of evaporating binary mixture droplet (BMD). We introduce the theoretical background of the SPR imaging technique and its methodology for concentration measurement. The SPR imaging system established in the present study consists of a LED light source, a polarizer, a lens, and a band pass filter for the collimated light of a 589 nm wavelength, and a CCD camera. Based on the Fresnel multiple-layer reflection theory, SPR imaging can capture the change of refractive index of evaporating BMD. For example, the present study exhibits the visualization process of ethylene glycol (EG)-water (W) BMD and measures real-time concentration change. Since the water component is more volatile than the ethylene glycol component, the refractive index of EG-W BMD varies with its mixture composition during BMD evaporation. We successfully measured the ethylene glycol concentration within the evaporating BMD by using SPR imaging.

• Steel and Composite Structures
• /
• v.28 no.5
• /
• pp.541-557
• /
• 2018

This paper presents the influence of carbon nanotubes (CNTs) waviness and aspect ratio on the vibrational behavior of functionally graded nanocomposite sandwich annular sector plates resting on two-parameter elastic foundations. The carbon nanotube-reinforced (CNTR) sandwich plate has smooth variation of CNT fraction along the thickness direction. The distributions of CNTs are considered functionally graded (FG) or uniform along the thickness and their mechanical properties are estimated by an extended rule of mixture. In this study, the classical theory concerning the mechanical efficiency of a matrix embedding finite length fibers has been modified by introducing the tube-to-tube random contact, which explicitly accounts for the progressive reduction of the tubes' effective aspect ratio as the filler content increases. Effects of CNT distribution, volume fraction, aspect ratio and waviness, and also effects of Pasternak's elastic foundation coefficients, sandwich plate thickness, face sheets thickness and plate aspect ratio are investigated on the free vibration of the sandwich plates with wavy CNT-reinforced face sheets. The study is carried out based on three-dimensional theory of elasticity and in contrary to two-dimensional theories, such as classical, the first- and the higher-order shear deformation plate theories, this approach does not neglect transverse normal deformations. The sandwich annular sector plate is assumed to be simply supported in the radial edges while any arbitrary boundary conditions are applied to the other two circular edges including simply supported, clamped and free.

• Journal of the Korean Chemical Society
• /
• v.9 no.4
• /
• pp.215-221
• /
• 1965

The significant liquid structure theory is extended to binary mixture, benzene-ethylenechloride system. The partition function, applicable throughout the temperature range in which Raoult's law is satisfied is derived. The thermodynamic quantities such as total and partial pressures, molar volumes and mixing entropies are calculated from the partition function at the temperatures $293.15^{\circ},\;323.14^{\circ}\;and\;357.15^{\circ}K.$ The theoretical values, thus calculated, are found to agree with the experimental data in the literatures.

• Earthquakes and Structures
• /
• v.13 no.5
• /
• pp.509-518
• /
• 2017

The objective of the present paper is to investigate the bending behavior with stretching effect of carbon nanotube-reinforced composite (CNTRC) beams. The beams resting on the Pasternak elastic foundation, including a shear layer and Winkler spring, are considered. The single-walled carbon nanotubes (SWCNTs) are aligned and distributed in polymeric matrix with different patterns of reinforcement. The material properties of the CNTRC beams are estimated by using the rule of mixture. The significant feature of this model is that, in addition to including the shear deformation effect and stretching effect it deals with only 4 unknowns without including a shear correction factor. The single-walled carbon nanotubes (SWCNTs) are aligned and distributed in polymeric matrix with different patterns of reinforcement. The material properties of the CNTRC beams are assessed by employing the rule of mixture. The equilibrium equations have been obtained using the principle of virtual displacements. The mathematical models provided in this paper are numerically validated by comparison with some available results. New results of bending analyses of CNTRC beams based on the present theory with stretching effect is presented and discussed in details. the effects of different parameters of the beam on the bending responses of CNTRC beam are discussed.

• Journal of the Korean Geotechnical Society
• /
• v.26 no.4
• /
• pp.5-14
• /
• 2010

Three years of frost heave field experiments were conducted to evaluate a method for reducing heave using a recycled tire powder-soil mixture. By mixing Tomakomai soil with 20% recycled tire powder, frost heave amount was drastically decreased. The results of the field experiment confirm that recycled tire powder is an excellent material for use in controlling the total amount of heave. The restraining effect of a recycled tire powder-soil mixture is qualitatively analyzed based on amount of frost heave, frost heave ratio, thermal conductivity, permeability and segregation potential theory.

• Proceedings of the Korean Society For Composite Materials Conference
• /
• 2001.05a
• /
• pp.135-140
• /
• 2001

A post-tensioned reinforced concrete slab bridge is analyzed by specially orthotropic laminate theory. Symmetrically reinforced slab with tension and compression steel is considered for convenience of analysis. Each longitudinal and transverse steel layer is regarded as a lamina, and material constants of each lamina is calculated by the use of the rule of mixture. This bridge is under uniformly distributed vertical loads, and axial loads and end moments due to post-tensioning. In this paper, finite difference method is used for numerical analysis of this bridge. Theory and analysis method of specially orthotropic laminate plates used in this paper can be used for design of new bridges, and maintenance and repair of old bridges.