• Title/Summary/Keyword: mixture process

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Selection of Optimum Ratio of 3 Components (Ir-Sn-Sb) Electrode using Design of Mixture Experiments (혼합물 실험계획법을 이용한 3성분(Ir-Sn-Sb) 전극의 최적비율 선정)

  • Park, Young-Seek
    • Journal of Environmental Science International
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    • v.25 no.5
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    • pp.737-744
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    • 2016
  • For electrolysis process using an insoluble electrode, electrochemical performance was greatly affected by the manufacturing method and procedure, such as the firing temperature, pre-treatment, type of precursor solution, coating method, electrode material, etc. Components of the electrode therein is one of the most important factors in electrochemical reaction. To achieve such characteristics, a appropriate ratio of the electrode material should be carefully chosen. The aim of this research was to apply experimental design method in the optimization of electrode component for the maximum generation of oxidants in electrochemical oxidation process. Mixture design, especially expanded simplex lattice design, in DOME (design of mixture experiments) with Design Expert - commercial software - was used to analyze the data. Analysis of variance (ANOVA) showed a high coefficient of determination ($R^2$) value of 0.9470, thus ensuring a satisfactory adjustment of the $3^{rd}$ order special cubic regression model with the experimental data. The application of response surface methodology (RSM) yielded the following regression equation, which is an empirical relationship between the TRO generation concentration and independent variables(mol ratio of 3 electrode components) in a real unit: TRO generation concentration $(mg/L)=TRO\;conc.=98.25{\times}[Ir]+49.71{\times}[Sn]+95.29{\times}[Sb]-16.91{\times}[Ir]{\times}[Sn]-29.47{\times}[Ir]{\times}[Sb]-22.65{\times}[Sn]{\times}[Sb]+703.19{\times}[Ir]{\times}[Sn]{\times}[Sb]$. The optimized formulation of the 3 component electrode for an high TRO (total residual oxidants) generation was acquired at mol ratio of Ir 0.406, Sn 0.210, Sb 0.384 (desirability d value, 1).

Numerical Analysis of Ignition and Flame Propagation in the Air/Fuel Spray Mixture (공기/연료분무 혼합기의 점화 및 화염전파 해석)

  • ;;Kim, Sung-Jun
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.12
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    • pp.3352-3359
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    • 1995
  • An Eulerian-Lagrangian method is employed to simulate the ignition process and the flame propagation through the air/fuel spray mixture in a closed constant-volume combustor. The spray mixture is ignited by providing a hot wall at the end of the combustor or by firing the electric spark. The investigated parameters involve the initial droplet size, overall equivalence ratio, initial fuel vapor concentration, distance between the hot wall and the nearest droplet, and the ignition energy. Numerical results clearly show the existence of the optimum spray condition for minimizing the ignition energy and the ignition delay time as well as the critical dependence of ignition upon the distance of the heat source to the nearest droplet.

A Study on the Characteristics of Gasoline Engine Performance Equipped with Perforated Throttle Valve (다공 스로틀밸브 장착 가솔린기관의 성능 특성에 관한 연구)

  • Cho, B.O.;Lee, C.S.
    • Journal of ILASS-Korea
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    • v.1 no.2
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    • pp.50-56
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    • 1996
  • In an fuel injection type gasoline engine, atomization of fuel droplet and mixture formation process are very important to understand engine combustion efficiency, and also has influence directly on the decision of engine performance and pollutant emission. In this study, perforated throttle valve instead of solid type throttle valve was developed and equipped to an SPI engine to promote secondary atomization and good droplet-air mixture formation. From the engine performance lest. it was verified that the case of perforated valve kas more advantages in each experimental parameters such as in cylinder gas pressure, mass burnt ratio, fuel consumption rate, and pollutant emission characteristics than that of solid one equipped. No matter what the same perforated valve, there are some distinct results in engine performance characteristics according to the perforate ratio.

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Performance Experiment and Exergy Analysis of an Automotive Air-conditioning System (자동차용 에어컨 성능실험과 액서지 해석)

  • 오상한;윤종갑;원성필
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.12 no.4
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    • pp.363-370
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    • 2000
  • Experiments have been peformed, using pure refrigerant R134a and a zeotropic refrigerant mixture R290/R600a(60%/40%) and their performances have been analyzed by the first and second laws(exergy method) of thermodynamics. From the experimental results, variations of compressor speed and air temperature have a great effect on the performance of the system. The sum of exergy losses in compressor and evaporator is about 60% of total exergy loss, using refrigerant R134a, so it is necessary to improve the performance of compressor and evaporator. According to the experimental results using refrigerant mixture of R290/R600a(60%/40%), the exergy losses in heat exchange processes are decreased but the exergy loss in throttling process is increased. The performance of the system has been improved by 20∼30% compared with that of R134a and exergy losses have been also reduced.

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Premature Stiffening of Cement Paste Associated with AFm Formation

  • Chung, Chul-Woo;Lee, Jae-Yong
    • Journal of the Korea Institute of Building Construction
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    • v.11 no.1
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    • pp.83-90
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    • 2011
  • The purpose of this research is to investigate the effect of AFm formation on the stiffening process of cement paste. High and low alkali sulfate clinkers were used for the experiments. The flow and stiffening behavior of cement paste was investigated using modified ASTM C403 penetration resistance test and oscillatory shear rheology. X-ray powder diffraction (XRD) was used for phase identification associated with stiffening of the paste. It was found from the results that low alkali clinker mixture produced very strong premature stiffening whereas high alkali clinker mixture did not cause premature stiffening. This is because of the large amount of alkali sulfate present in the clinker. Addition of calcium and sodium chloride to the high alkali clinker mixture caused faster stiffening and set.

ANALYSIS OF DIRECT INJECTION SI STRATIFIED COMBUSTION IN HYDROGEN LEAN MIXTURE - COMBUSTION PROMOTION AND COOLING LOSS BY HYDROGEN -

  • Shudo, Toshio;Tsuga, Koichiro
    • International Journal of Automotive Technology
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    • v.2 no.3
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    • pp.85-91
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    • 2001
  • Characteristics of methane direct-injection spark-ignition stratified combustion in lean hydrogen mixture were analyzed both in a single cylinder engine and in a constant volume combustion chamber. Combustion pressure and Instantaneous combustion chamber wall temperature during the combustion process were measured with a thin-film thermocouple and used in analyses of combustion and cooling loss. Results in this research show that the premixed hydrogen increases cooling loss to combustion chamber wall while achieving combustion promotion, and the combustion system is effective especially in lean mixture conditions. Analysis of flame propagation was also done with Schlieren photography in the constant volume combustion chamber.

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Densification of Metal Injection Molding Parts Made of Ball Milled W-20%Cu Powders (볼밀링한 W-20wt%Cu 분말로 제조된 금속사출성형 부품의 조밀화)

  • 김순욱;류성수;문인형
    • Journal of Powder Materials
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    • v.7 no.4
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    • pp.228-236
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    • 2000
  • An investigation was carried out on the possibility whether the ball-milling process of low energy could successfully improve the packing density and flowability for MIM application in W-20wt%Cu system. In this study, W-20wt%Cu powder mixture was prepared by ball-milling. W powder was not fractured by low mechanical impact energy used in the present work during the critical ball-milling time, but the ductile Cu powder was easily deformed to the 3 dimensional equiaxed shape, having the particle size similar to that of W powder. The ball-milled mixture of W-20wt%Cu powder had the more homogeneous distribution of each component and the higher amount of powder loading for molding than the simple mixture of W-Cu powder with an irregular shape and a different size. Accordingly, the MIM W(1.75)-20wt%Cu powder compacts were able to be sintered to the relative density of 99% by sintering at $1400^{\circ}C$ for one hour.

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Fuel Stratification Process in a Lean Burn Internal Combustion Engine by Using Planar Laser Induced Fluorescence (PLIF를 이용한 희박연소엔진에서의 연료 성층화에 관한 연구)

  • 정경석
    • Transactions of the Korean Society of Automotive Engineers
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    • v.11 no.3
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    • pp.7-12
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    • 2003
  • Mixture formation in the cylinder of a lean bum engine has been observed by Laser Induced Fluorescence technique. XeCl laser (308nm) was used to produce a laser sheet. 3-pentanone has been added to iso-octane fuel to produce fluorescence, the intensity of which is proportional to the concentration of the fuel. The laser sheet was introduced through the piston window and the fuel distribution in the vertical plane was observed through a side window. Comparison has been made for the cases of selected fuel injection timing as 0, 360, 405, and 450 CA. For the case of 0 and 360 CA injection, uniform fuel distribution in the combustion chamber has been obtained at the ignition time which is favorable for the high load mode. And the late injection cases, 405 and 450 CA, revealed the stratified formation of rich mixture around the spark plug. That extends the lean misfire limit and reduces cyclic variation in the low load mode.

A Numerical Study on Stratified Charge Formation and Combustion Processes (성층급기 연소현상에 관한 수치적 연구)

  • Lee, Suk-Young;Huh, Kang-Y.
    • Transactions of the Korean Society of Automotive Engineers
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    • v.15 no.5
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    • pp.86-96
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    • 2007
  • A direct-injection stratified-charge(DISC) engine has been considered as a promising alternative in spite of high unburned hydrocarbon emission levels during light load operation. In this paper investigation is made to characterize formation and combustion processes of stratified mixture charge in a simple constant volume combustion chamber. Both experimental and numerical analyses are performed for fluid and combustion characteristics with 3 different induction types for rich, homogeneous and lean mixture conditions. The commercial code FIRE is applied to the turbulent combustion process in terms of measured and calculated pressure traces and calculated distributions of mean temperature, OH radical and reaction rate. It turns out that the highest combustion rate occurs for the rich state condition at the spark ignition location due to existence of stoichiometric mixture and timing.

A Study on the Injection Characteristics of Biodiesel Fuels Injected through Common-rail Injection System (커먼레일식 분사시스템에서 바이오디젤연료의 분사특성에 관한 연구)

  • Seo, Young-Taek;Suh, Hyun-Kyu;Lee, Chang-Sik
    • Transactions of the Korean Society of Automotive Engineers
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    • v.15 no.5
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    • pp.97-104
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    • 2007
  • The object of this work is to analyze the macroscopic spray performance and atomization characteristics between diesel and biodiesel fuels. In this study, the effects of mixture ratios of biodiesel fuel on the spray tip penetration, fuel injection rate, spray cone angle, and the atomization characteristics such as droplet size, droplets distribution, and spray arrival time according to the axial distance were investigated at various injection parameters. It is revealed that the injection rate is more affected by injection pressure than mixture ratio. And, the spray development process is closely matched between diesel and biodiesel fuels. However, the droplet atomization characteristics of biodiesel shows deteriorated results as the mixture ratio of biodiesel increased because of the high viscosity and density.