• Journal of Environmental Science International
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• v.13 no.3
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• pp.319-325
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• 2004

An experimental study on the preparation of monolithic porous polymers by environmentally friend process in supercritical carbon dioxide has been carried out. Polymerization mixture composed of a cross-linking monomer, initiator and functional co-polymer was charged in the reactor with sapphire window. After the system was purged with a flow of $CO_2$ for 15 min, the reactor was pressurized with liquid $CO_2$ up to 100 bars. The reactor was isolated from and placed back to the system via quick connector for shaking until the mixture had become fully homogeneous. The reactor was then heated and pressurized to the required reaction conditions and left overnight. After cooling and $CO_2$ evacuation, the polymer was removed from the reactor as dry, white, continuous monoliths. The effect of experimental conditions on the physical properties of porous polymer was systematically examined, and it was found that monomer content had a major effect on the physical properties of the polymers.

• 한국연소학회:학술대회논문집
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• 2007.05a
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• pp.37-44
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• 2007

A nickel foam, one of metal foams was seleced as a catalyst support instead of conventional ceramic materials. $Al_2O_3$ was coated on the surface of nickel foam to increase the surface area. $Al_2O_3$ coating process was based on sol-gel process. SEM image was obtained and $Al_2O_3$ coverage was confirmed. Combustion experiments were carried out using SUS combustor and $H_2$/air mixture. Temperatures were measured with different equivalence ratios and $H_2$ flow rates. $H_2$ conversion rates were calculated by the analysis of product gas using gas chromatography. Catalytic combustion of $H_2$ was complete and stable with Pt/$Al_2O_3$ coated nickel foam and influences of water vapor were confirmed during the beginning of combustion.

• 한국연소학회:학술대회논문집
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• 2007.05a
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• pp.155-160
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• 2007

This study was conducted to find out the chlorine removal characteristics of waste plastic mixture by pyrolysis process with thermogravimetric analysis(TGA) and a lab-scale pyrolyzer. The material used as plastic wastes were PE (Poly-ethylene), PP (Poly-prophylene), and PVC (Poly Vinyl Chloride). Experimental procedure were composed of three steps; 1st step: TGA of PVC, PP and PE, 2nd step: chlorine removal rate of PVC in a lab-scale pyrolyzer, 3rd step: chlorine removal rate of PVC-PE and PVC-PP mixture in a pyrolyzer. Through the results of TGA, we can estimate the basic pyrolysis characteristics of each plastic, and then we can also derive the design parameters and operating conditions of the lab-scale pyrolyzer. The results can be used as primary data for designing a system to produce RPF (Refuse Plastic Fuel), a waste incinerator and a pyrolysis/gasification process.

• Journal of the Korean Ceramic Society
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• v.17 no.3
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• pp.121-128
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• 1980

In order to obtain the fundamental data for the preparation of ferroxplana $Zn_2Y(Ba_2Zn_2Fe_{12}O_{22})$, which is useful for GHz-band communication, the optimum coprecipitation condition of $Zn(NO_3)_2-6FeCl_3$ in $NH_4OH$ solution and the formation process of the hexagonal ferrite were investigated. By the hot-petroleum-drying and calcining the coprecipitated hydroxide mixture $Zn(OH)_2 +Ba(OH)_2+ 6Fe(OH)_3$, the fine and uniform powder was obtained , whose phase composition and microstructure were studied by X.R.D. and electron microscope. In results, it was found that $Zn_2Y$, BaM and $Zn_2W$ were the representative phases in calcined specimens whose activation energies of crystal growth were about 3, 8, 2.5, $5.4{\times}10^4$ J/mole , respectively. The sintered specimens would be appreciated as useful magnetic cores for the high frequency communication.

• Journal of Power System Engineering
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• v.18 no.3
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• pp.5-13
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• 2014

In order to control emissions from engine, it is necessary to understand the mixture formation process of diesel spray. In this study, analysis of diesel fuel(n-Tridecane, $C_{13}H_{28}$) spray under a high temperature and pressure was performed by a general-purpose program, ANSYS CFX release 11.0, and the results of these are compared with experimental results of diesel fuel spray using the Exciplex Fluorescence Method. The simulation results of diesel spray is analyzed by using the combination of Large-Eddy Simulation(LES) and Lagrangian Particle Tracking(LPT), and then injection pressure was selected as an analysis parameter. Consequently, it was found that the experimental results and the numerical results are consistent with each other, and then in order to investigate the behavior characteristics of evaporative diesel spray, the effectiveness of the use of CFX of commercial code is definitely validated.

• Journal of ILASS-Korea
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• v.23 no.2
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• pp.90-95
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• 2018

The goal of this study is to experimentally observe the autoignition phenomena of a diesel/1-butanol mixture droplet in ambient pressure and $700^{\circ}C$ condition. A volume ratio of 1-butanol in the fuel was set to 25, 50 and 75%. A single droplet was installed at the tip of fine thermocouple, and the electric furnace dropped down to make elevated temperature condition. Droplet behavior during the experiment could be divided into 3 stages including droplet heating, puffing and autoignition/combustion. Puffing process intensively observed for the case of 1-butanol volume ratio of 25 and 50%, but did not occur at 75%. Increase of 1-butanol volume ratio hindered rise of the droplet temperature and delayed ignition. In addition, puffing process also affected on autoignition, so the ignition delay of 1-butanol volume ratio of 50% was became longer than that of 75% case.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1998.06a
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• pp.49-52
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• 1998

Preparation of hexagonal strontium-ferrite by modified spray co-roasting(MSC:H) which is expected to shorkn the length of the process and to elevate the magnetic properties of hard ferrite was studied. We prapared $Fe_2O_3/SrCO_3$ mixture powders by MSCR after stirring ionized $FeCI_2$ in distilled water with solid state $SrCO_3$. And then calcined the mixture powders up to $1150^{\circ}C$ for Sr-ferrite powders It is possible to prepare hexaferrite powders with high saturation magnetization (Ms > 69 emu/g) , coercivity (Hc > 4000 Oe) The nlagnetic values of saturation magnetization iire higher than those achieved by the conventional technique.

• Clean Technology
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• v.24 no.1
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• pp.15-20
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• 2018

Hexafluoropropyleneoxide ($C_3F_6O$, HFPO) is highly expensive and it may be used as a raw material for the synthesis of various fluorine based compounds. Currently, extractive distillation method has gained considerable attention to collect the HFPO from a mixture of HFPO / hexafluoropropylene ($C_3F_6$, HFP). Optimized operating conditions are studied using a theoretical method for the extraction process. Among available solvents for the purification process, the use of 1,1-dichloro-1-fluoroethane exhibits a high purity of HFPO as a top product and minimize the required heat duty. Since the boiling point of the solvent increases as the pressure in the column increases, the enhanced extractive capability of the solvent led to the high purity of HFPO at the high pressure.

• Resources Recycling
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• v.9 no.6
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• pp.3-8
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• 2000

A reaction between the depolarizing mixture in the spent manganese batteries and ($NH_4$)$_2$$SO_4$was carried out to find a new process for the extraction of Mn component from the spent manganese batteries. The optimum conditions were as follows : the reaction temperature $425^{\circ}C$, ($NH_4$)$_2$$SO_4$weight ratio to the depolarizing mixture in the spent manganese batteries 12.0, reaction time 60 min. Under above conditions manganese was extracted 93.5%.

• Bulletin of the Korean Chemical Society
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• v.31 no.6
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• pp.1633-1637
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• 2010

The UV-vis absorption spectrum of protoporphyrin IX shows a very sharp and strong absorption maximum peak at 398 nm in acetonitrile-water mixture solution (1:1 v/v). When divalent metal ions such as $Cu^{2+}$, $Zn^{2+}$, and $Ca^{2+}$ ion were added to protoporphyrin IX, metal protoporphyrin IX complexes were thereby produced. Cu-protoporphyrin IX complexes have the largest formation constant ($K_f$) among them. The fluorescence intensity of protoporphyrin IX was diminished by the presence of $Cu^{2+}$, $Zn^{2+}$, $Ca^{2+}$, $Mn^{2+}$, and $Ni^{2+}$ ions as quenchers. However, $Mg^{2+}$, $Mn^{2+}$, and $Ni^{2+}$ ions are hardly combined with protoporphyrin IX. $Mg^{2+}$ ion does not take part in the fluorescence quenching process of protoporphyrin IX in acetonitrile-water mixture solution. According to the Stern-Volmer plots, fluorescence quenching by $Cu^{2+}$, $Zn^{2+}$, and $Ca^{2+}$ ions involves static quenching, which is due to complex formation. On the contrary, dynamic quenching has a large influence on the overall quenching process, when $Mn^{2+}$ and $Ni^{2+}$ ions were added to protoporphyrin IX in acetonitrile-water mixture solution.