• Title/Summary/Keyword: mixed metal

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LC VCO using dual metal inductor in $0.18{\mu}m$ mixed signal CMOS process

  • Choi, Min-Seok;Jung, Young-Ho;Shin, Hyung-Cheol
    • Proceedings of the IEEK Conference
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    • 2006.06a
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    • pp.503-504
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    • 2006
  • This paper presents the design and fabrication of a LC voltage-controlled oscillator (VCO) using 1-poly 6-metal mixed signal CMOS process. To obtain the high-quality factor inductor in LC resonator, patterned-ground shields (PGS) is placed under the symmetric inductor to reduce the effect from image current of resistive Si substrate. Moreover, due to the incapability of using thick top metal layer of which the thickness is over $2{\mu}m$, as used in many RF CMOS process, the structure of dual-metal layer in which we make electrically short circuit between the top metal and the next metal below it by a great number of via materials along the metal traces is adopted. The circuit operated from 2.63 GHz to 3.09 GHz tuned by accumulation-mode MOS varactor. The corresponding tuning range was 460 MHz. The measured phase noise was -115 dBc/Hz @ 1MHz offset at 2.63 GHz carrier frequency and the current consumption and the corresponding power consumption were about 2.6 mA and 4.68 mW respectively.

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Antioxidant Effect of Onion Skin Extract (양파껍질 추출물의 항산화 및 상승효과)

  • 손종연;손흥수;조원대
    • Korean journal of food and cookery science
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    • v.14 no.1
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    • pp.16-20
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    • 1998
  • The antioxidant and synergistic effect of methanol extracts of onion skin were investigated by measuring peroxide value. The inhibitory effects of the extracts against metal catalyzed oxidation were also studied. The antioxidant activity of methanol extract (0.02%) of onion skin was stronger than that of mixed tocopherol or ascorbic acid (0.02%), but weaker than that of BHT (0.02%). However, the methanol extract at the concentration of 0.04% exhibited strong antioxidant effect, comparable to that of BHT (0.02%). The methanol extract showed very strong synergistic effect with the mixed tocopherol. The methanol extracts at the concentration of 0.03% and 0.04% acted as metal deactivator in the presence of FeC1$_3$. As a metal deactivator, methanol extract of onion skin appeared to be more effective than citric acid.

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Tailoring Molecular Precursors for Multicomponent Oxides

  • Hubert-Pfalzgraf, Liliane G.
    • The Korean Journal of Ceramics
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    • v.6 no.4
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    • pp.370-379
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    • 2000
  • Simple ways to build up mixed-metal molecules which can act as potential single-source precursors to multimetallic oxides are reviewed. Emphasis is given to Lewis acid-base reactions between metal alkoxides M(OR)/sub n/, and between metal alkoxides and more accessible oxide precursors, carboxylates M(O₂CR)/sub n/ and β-diketonates M(β-dik)/sub n/. Characterization of the precursors is achieved in the solid state (single crystal X-ray diffraction, FT-IR) and by multinuclear NMR in solution. The reactions proceed toward the formation of aggregates in which the different metals display their usual coordinations numbers, often six for transition metals, as shown. Strategies for fixing the stoichiometry between the metals are developed. The reactivity of the MM species (dissociation, effects of chemical modifiers, of other metallic species, hydrolytic or non-hydrolytic condensation, etc.) will be indicated. Transformations into oxides are illustrated on precursors for titanates or niobates.

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MnZn Ferrite Preparation by Coprecipitation Method (공침법에 의한 MnZn Ferrite 분말제조 연구)

  • 엄태형;고성만;서동수;양준환;박균하
    • Journal of the Korean Ceramic Society
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    • v.30 no.6
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    • pp.478-484
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    • 1993
  • The influence of reaction conditions on the MnZn ferrite coprecipitation process were investigated using mixed metla sulfate solution and ammonium oxalate. In order to minimize the metallic ion losses and to control the particle size, the optimum reaction conditions were as follows; reaction temperature $25^{\circ}C$, metal sulfate concentration 0.3M, molar ratio of ammonium oxalate/mixed metal sulfate 1.1:1. The production yield was as high as 97.6% of theoretical yield at optimum reaction condition.

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A Densification Model for Mixed Metal Powder Under Cold Compaction (냉간압축하에서 혼합 금속분말의 치밀화 모델)

  • Jo, Jang-Hyeok;Jo, Jin-Ho;Kim, Gi-Tae
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.24 no.10 s.181
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    • pp.2628-2636
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    • 2000
  • Densification behavior of mixed copper and tool steel powder under cold compaction- was investigated. By mixing the yield functions proposed by Fleck et al. and by Gurson for pure powder in terms o f volume fractions and contact numbers of Cu powder, new mixed yield functions were employed for densification of powder composites under cold compaction. The constitutive equations were implemented into a finite element program (ABAQUS) to compare with experimental data and with calculated results from the model of Kim et al. for densification of mixed powder under cold isostatic pressing and cold die compaction. Finite element calculations by using the yield functions mixed by contact numbers of Cu powder agreed better with experimental data than those by volume fractions of Cu powder.

Competitive Solvent Extraction of the Mixture of Alkali Metal and Alkaline Earth Metal Cation containing Crown Ether Carboxylic Acid and Crown Ether Phosphonic Acid (크라운에테르 카르복시산과 크라운에테르 포스포닉산을 포함한 알칼리 금속과 알칼리 토금속 양이온 혼합물의 경쟁적 용매추출)

  • Chung, Yeong-Jin
    • Journal of the Korean Applied Science and Technology
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    • v.22 no.3
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    • pp.219-227
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    • 2005
  • Competitive solvent extraction of the mixure of alkali metal and alkaline earth cation from water into organic solvent containing the crown ether carboxylic acid and anlogous crown ether phosphonic acid was investigated as follows. The lipophilic group is found to strongly influence to the selective extraction in the mixed systems from only alkali metal cation for sym-(n-decyldibenzo)-16-crown-5-oxyacetic acid $\underline{1}$ to mostly alkaline earth metal cation for sym-bis[4(5)-tert-butylbenzo]-16-crown-5-oxyacetic acid $\underline{3}$. Monoethyl sym-(n-decyldibenzo)-16-crown-5-oxymethylphosphonic acid $\underline{2}$. and monoethyl-sym- bis]4(5)-tert-butylbenzo]-16-crown-5-oxymethylphosphonic acid $\underline{4}$ showed good selectivity for $Na^+$ over $Mg^{2+}$, the second extracted ion. Structural variation in the crown ether phosphonic acid somewhat was influenced to the extraction selectivity in the mixed systems. when variation of the ionized group is influenced in the mixed systems, the selectivity of $Na^+$ as the second extracted ion was much better crown ether carboxylic acid $\underline{1}$ than crown ether phosphonic acid $\underline{2}$, while the efficiency of $Na^+$ extraction was better $\underline{2}$ (83% total loading) than $\underline{1}$ (32%).

Continuous Ion Exchange Characteristics of Ni, Co and Ag Ions in Acidic-Oxidizing Conditions (산성-산화성 분위기에서 니켈(Ni), 코발트(Co) 및 은(Ag) 이온의 연속식 이온교환 특성)

  • Kim, Young H.;Yang, Hyun S.;Kim, Woong K.
    • Applied Chemistry for Engineering
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    • v.10 no.2
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    • pp.218-224
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    • 1999
  • Continuous ion exchange characteristics of the synthetic coolant contained Ni, Co and Ag ions of low concentration in acidic-oxidizing conditions have been studied to suggest the guideline for the optimum operation of mixed-bed demincralizer during the shutdown period of a pressurized water reactor (PWR). In the effect of the form of cation resins on the removal capacity of metal ions, the performance of a $H^+$-form resin was about 6% higher than that of a $Li^+$-form resin. Mixed-bed of cation and anion resins in comparison with nonmixed-bed of them, had no affected on the removal capacity of metal ions but very slightly increased the slope of breakthrough curves of metal ions. In the effect related to acidic-oxidizing conditions of the coolant, the addition of boric acid very slightly decreased the slope of breakthrough curves of metal ions, while the addition of hydrogen peroxide slightly decreased the removal capacity of metal ions.

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The Solidification of the Heavy Metal Ion by Using DSP Cement (DSP 시멘트를 이용한 중금속 이온의 고화)

  • 소정섭;최상홀
    • Journal of the Korean Ceramic Society
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    • v.33 no.8
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    • pp.889-894
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    • 1996
  • This study was subjected to the stabilization of heavy metals using DSp cement. Heavy metal Cr and Pb ions were mixed with cement paste and hydration behavior and leaching property by heavy metal were exami-ned. It was found that, Cr ion accelerated the early hydration of the cement and has no accelerating effect in later hydration period. However Pb ion retarded the hydration of the cement for a early hydration periods. As a result of leaching test the quantity of leachant has a very low value and the influence of leached heavy metal effected on the environments is very weak.

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Redox Characteristics of $MO/Al_2O_3-ZrO_2$ [M=Ni and Cu] Mixed Metal Oxides ($MO/Al_2O_3-ZrO_2$ [M=Ni 및 Cu] 혼합 금속 산화물의 환원-산화 특성)

  • Ryu, Jae-Chun;Kim, Young-Ho;Park, Chu-Sik;Hwang, Gab-Jin;Kim, Jong-Won
    • Transactions of the Korean hydrogen and new energy society
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    • v.16 no.1
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    • pp.49-57
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    • 2005
  • [ $MO/Al_2O_3-ZrO_2$ ](M=Ni and Cu) mixed metal oxides were prepared using sol-gel method in order to investigate the applicability to the 2-step thermo-chemical water splitting process and their redox behaviors were studied by temperature programmed reaction(TPR) from room temperature to 900$^{\circ}C$ under 5% $H_2$/Ar for the reduction and $H_2O$/Ar for the oxidation, respectively. From the results, peaks of the reduction and the oxidation on temperature were shifted with the change of crystalline phases due to the addition of $Al_2O_3$ and $ZrO_2$. The intensities of the peaks were also increased with the increase of contents of NiO or CuO that could be considered as active species. In addition, based on the observation of SEM images before and after the redox test, it seemed that $Al_2O_3-ZrO_2$ added prevented high temperature sintering of active metal components such as Ni (or Cu) on the surface and played a role of dispersing the active species homogeneously in solid solution of mixed oxides.

Comparative Reaction Characteristics of Methane Selective Catalytic Reduction with CO Generation Effect in the N2O Decomposition over Mixed Metal Oxide Catalysts (MMO 촉매 하에서 N2O 분해에 대한 메탄 SCR 반응 및 CO 생성 효과의 비교 연구)

  • Park, Sun Joo;Park, Yong Sung
    • Applied Chemistry for Engineering
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    • v.19 no.6
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    • pp.624-628
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    • 2008
  • Nitrous oxide ($N_2O$), known as one of the major greenhouse gases, is an important component of the earth's atmosphere, and gives rise to precursor of acid rain and photochemical smog. For the removal of $N_2O$ and other nitrogen oxides, the SCR reaction system with various reductants is widely used. This study is based on the results of experimental and theoretical examinations on the catalytic decomposition of sole nitrous oxide ($N_2O$) and selective catalytic reduction of $N_2O$ with $CH_4$ in the presence of oxygen using mixed metal oxide catalysts obtained from hydrolatcite-type precursors. When $CH_4$ is fed together with a reductant, it affects positively on the $N_2O$ decomposition activity. At an optimum ratio of $CH_4$ to $O_2$ mole ratio, the $N_2O$ conversion activity is enhanced on the SCR reaction with partial oxidation of methane.