• Economic and Environmental Geology
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• v.52 no.5
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• pp.485-497
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• 2019

The Jade Investiture Books in Joseon Dynasty shows diverse facies with various petrographic characteristics to green and white based on color. In lithologically, the green rocks are jade composed of calcite and serpentine, and the white ones are marbles consisting mainly in crystalline calcite. As a result of X-ray diffraction of jade rocks, the more green in color, the more increased intensity of serpentine appears. Therefore, the grade of jade is correlated with contents of serpentine. The Jade Investiture Books owned by the National Palace Museum of Korea are subdivided with 104 (41.3%) books made by only jade rocks, 98 (38.9%) books made by only marbles, and 50 (19.8%) books mixed with jade rocks and marbles. Among the mixed ones, 47 (18.6%) books consisted mainly of the marbles. This result shows the superior marble books occupy more than half of the total books. The Jade Investiture Books made in early Joseon Dynasty are composed of high grade jade. However, the grade of jade had decreased as the kings changed in process of time, and the composition of marble had increased in reverse proportion of jade. The quality of letter pigments, metal accessories and fabrics also had decreased with jade. These trends are reflected in the aspect of society such as weakening royal authority, national power and finance with the course of time. The jade of the books has different mineralogical characteristics from some modern jade produced in Chuncheon nephrite and Buyeo precious serpentine in Korea. Meanwhile, there is ancient literature that described quarries from Namyang in Hwaseong of Gyeonggi province. This area has a wide distribution of gneiss, limestone and limesilicate rocks are interbedded between muscovite schist. The limesilicate rocks contain diopside, which produced serpentine through alteration. It has possibility to make the Jade Investiture Books using these small amounts of jade through mining activity.

• Economic and Environmental Geology
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• v.52 no.5
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• pp.449-457
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• 2019

We present the K-Ar age-dating results of the bulk and the less than $0.1{\mu}m$ fraction of the fault gouges collected from some major faults in the Gyeongsang basin. We try to determine the timings of fault activation based on the mineralogical characteristics, and to interpret the spatio-temporal variability of the major fault events during the Cenozoic Era by considering together with the previous results. We propose at least the 3-times of major fault events at about 50 Ma, and just after 30 Ma and 20 Ma in the Gyeongsang basin, which were inferred from the combined approach of the K-Ar ages and the clay mineralogy of the bulk fault gouges and the <$0.1{\mu}m$ fractions. The fault activation timings of the Yangsan fault tend to be younger in the northern part than in the southern part. In particular, the inferred fault events just after 30 Ma and 20 Ma are mainly detected in the Ocheon fault and the related faults, and the fault in the Gyeongju area. The fault activation timings of the major faults can be revised accurately by using illite-age-analysis(IAA) method. These geochronological determinations of the multiple events of the major faults in the Gyeongsang basin are crucial to establish the tectonic evolution in the southeastern part of the Korean Peninsula during the Cenozoic Era.

• The Journal of the Petrological Society of Korea
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• v.13 no.2
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• pp.47-63
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• 2004

This study focuses on the petrography and petrochemical characteristics of the volcanic and plutonic rocks in Gadeog island, Busan, Korea. Based on textural and mineralogical characteristics, intermediate volcanic rocks can be divided into andesitic lava flows (porphyritic and massive andesites) and andesitic pyroclastics. Felsic volcanic rocks are composed of rhyolite, rhyolitic welded tuff, and tuff breccia. Plutonic rocks are intruded rhyolite and andesitic rocks, and composed of hornblende granodiorite which contains lots of mafic magma enclaves. Volcanic rocks are composed of andesite, dacite and rhyolite having a range in SiO$_2$ from 59 to 78wt.%. The volcanic rocks belong to the calc-alkaline rock series. Plutonic rocks have a range in SiO$_2$ from 63 to 69wt.%. This compositional variations correspond to those of Cretaceous volcanic and plutonic rocks in the southeastern Gyeongsang basin. The trace element composition and rare earth element patterns of the volcanics, which are characterized by high LREE/HFSE ratios and enrichment in LREE, suggest that they are typical of calc-alkaline volcanic rocks produced in the subduction environment around continental arc. We concluded that volcanic and plutonic rocks in Gadeog Island were evolved from orogenic andesitic magma which was produced by partial melting of the mantle wedge in the subduction environment.

• Korean Journal of Soil Science and Fertilizer
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• v.19 no.3
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• pp.205-210
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• 1986

A soil micromorphological study of clayey terrace soils in Yeongnam area was carried out to investigate the soil genetic features and to distinguish the soil parent materials. Dominant plasmic fabrics in the terrace soils were vosepic, mosepic, insepic, and masepic of sepic fabrics but the Geugrag and Upyeong in Yeongil sequence have an asepic fabrics. Embedded grain cutans in the terrace soils were characterized by having porphyroskelic related distribution. Among pedological features of the B horizons of the terrace soils, the argillic cutans of ferriargillans and glaebules of manganiferrous concretions were the dominant in mineralogical composition, and the papules are abundant in the most terrace soils indicating that the soils are generally old. The substrata of the Bancheon in Yeongcheon and Upyeong in Yeongil area were so different from the terrace deposits in plasmic fabrics that these soils were believed to be composed of bisequum profiles. Because of having the free grain cutans, it was considered that the substrata of Bancheon in Yeongcheon and Upyeong in Yeongil area might have a period of soil formation before deposition of the terrace materials.

• Korean Journal of Soil Science and Fertilizer
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• v.32 no.4
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• pp.446-451
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• 1999

This study was carried out to investigate some mineralogical characteristics of Artificial Granular Zeolite (AGZ) and effect of AGZ on purification and alleviation of rice seedling damages of mine wastewater containing heavy metals. AGZ had mainly representative Na-P1 peaks and some $C_3S$ peaks of Portland cement in X-ray diffractogram. Differential thermal analysis represented that AGZ had weak endothermic peak around $130^{\circ}C$ and new deep endothermic peak around $750^{\circ}C$ as compared to powdery artificial zeolite. The ranking of heavy metals removals by AGZ, was lead> copper> cadmium> zinc in the synthetic wastewater. Root growth of rice seedling was greatly inhibited in the mine wastewater, and died after all. As AGZ treated into the mine wastewater with the ratio 1 : 50 (W : V) for one day or 1 : 100 for 4 days, the concentrations of heavy metals in the mine wastewater were decreased to below the critical concentration for agricultural use. And rice seedlings were grew with little damages in the purified water by AGZ.

• Korean Journal of Mineralogy and Petrology
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• v.34 no.2
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• pp.121-131
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• 2021

Magnesium (Mg) present in carbonate minerals as impurities has been used as a geochemical proxy to infer the environmental conditions where the minerals precipitated. The reliability of Mg geochemical proxies requires fundamental understanding of Mg incorporation into minerals based on accurate speciation of Mg ²⁺ in the crystal structure, which is determined mainly by application of X-ray absorption spectroscopy (XAS). However, high uncertainties are involved in interpreting the XAS spectra of minerals containing trace amount of Mg ²⁺. Because density function theory (DFT) can predict an XAS spectrum for a crystal structure, DFT calculations can reduce the uncertainties in the interpretation of the XAS spectrum. In this study, we calculated ab initio Mg K-edge absorption spectra of Mg silicates and (hydr)oxides based on DFT and analyzed the correlation between the calculated spectra and Mg structural parameters. Our ab initio Mg K-edge absorption spectra well reproduced the key features of the experimental spectra. The absorption-edge positions of the calculated spectra showed the weak positive correlation with the average Mg-O bond distance or Mg effective coordination number. The current study shows that DFT-based core-level spectroscopy method is a powerful tool in providing standard Mg K-edge spectra of diverse Mg minerals and determining the Mg chemical species within carbonate minerals.

• Economic and Environmental Geology
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• v.52 no.4
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• pp.275-290
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• 2019

Geochemical study was conducted to elucidate the origin of fluorine (F) distributed in the rocks within the four areas of Yongyudo and Sammokdo, Incheon, which have been used as the source area of land reclamation for the $3^{rd}$ and $4^{th}$ stage construction sites of the Incheon International Airport. The main geology of the study area is Triassic biotite granite. Fluorine is contained at high levels in biotite granite, mylonite, and dykes (andesite and, basaltic-andesite). Furthermore, the higher concentrations of fluorine in the biotite granite can be contributed to fluorite. The results of microscopic analyses reveal that the fluorite was mostly observed as small vienlets together with quartz. This features support that fluorite was naturally formed due to the secondary process of hydrothermal fluids. In addition, fluorine was investigated to be highly enriched in a large amount of mica within the veins. In the case of mylonite, a high levels of fluorine was contributed to a large amount of sericite. The sericites contained in the mylointe, differently to those of the biotite granite, filled the micro-fractures of quartz formed as a result of mylonitization and included small cataclastic quartz grains. This indicates that fluorine was naturally enriched due to the alteration of hydrothermal fluids filling fractured zones formed by mylonitization. Consequently, the results of petrological and mineralogical study confirm that the fluorine distributed in the rocks within the Yongyudo and Sammokdo originated naturally.

• Economic and Environmental Geology
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• v.51 no.6
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• pp.521-529
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• 2018

This study was conducted to investigate the natural origin of fluorine contained in the rocks within the Eulwangsan area via petrological and mineralogical analyses. The main geology of the Yongyudo Eulwangsan area is Triassic biotite granite. Biotite granite and mylonite are the major rock types containing fluorine at high levels (up to 1,700 and 2,400 mg/kg for biotite granite and mylonite, respectively). In the case of the biotite granite, a high concentration of fluorine can be contributed to fluorite, and the results of microscopic analyses show that the fluorite was observed as small veinlets filling cleavages and micro-fractures within alkali-feldspars and plagioclases, or observed together with quartz in ore veins, indicating the secondary formation of fluorite by hydrothermal fluids. In mylonite, on the other hand, a high fluorine concentration is attributable to sericite. Microscopic analyses revealed that the boundary between sericite and surrounding quartz was not clear, the sericite occurred filling the micro-fractures of quartz and encapsulating small quartz cataclasts. These results indicate that the sericite was also formed as a result of hydrothermal alteration. Consequently, it is speculated that the high fluorine level in the rocks of the Eulwangsan area of Yongyudo is of natural origin due to hydrothermal processes.

• Korean Journal of Heritage: History & Science
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• v.45 no.3
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• pp.194-211
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• 2012

Pung-nap mudcastle has brought wide attention to archaeologists since scientific studies were carried out on the various types of building sites and excavated potteries related to A period of Baekje Kindom when it sat Hansung as the capital. It is identified that clay from Ra-No.19 site of Pung-Nap mudcastle has different from compositions that of residential soil. From archaeological point of view, it is believed that the the soil was a source material for potteries due to the appropriate viscosity and inclusions. Mineralogical and geochemical studies show that the compositions between the source material and randomly chosen two potteries from the same site are similar. Behavior pattern classification of major, trace and rare elements provides also very similar result. Artificial specimen has been made at different temperature in order to estimate firing temperature of the potteries by means of various kinds of instrumental application. As a result of the study, it is believed that the firing temperature of the red and brown pottery was $550{\sim}600^{\circ}C$ and $900{\sim}1,000^{\circ}C$ respectively.

• Korean Journal of Heritage: History & Science
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• v.45 no.1
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• pp.70-85
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• 2012

Uiseong Tamni-ri Five-storied Stone Pagoda is composed of andesitic tuff and partially combined with tuff breccia and fine-grained granite. The andesitic tuff is identical to basement rock of Geumseongsan Mountain based on lithological, mineralogical and geochemical characteristics. The pagoda has suffered physical weathering such as crack and scaling, discoloration and biological colonization with complex reaction. Expecially, dark gray and brown discoloration appeared whole over the surface of the pagoda, and three to five-layered exfoliation and granular disintegration dominantly occurred in the fourth and fifth roof stones. It is assuming that the stone elements of the pagoda are evaluated as third to forth grades (average third grade) of weathering compared to fresh rock in Geumseongsan Mountain. The physical strength of the stone elements shows low values in the south and west sides of the pagoda that corresponds high weathering degree of the west side due to exfoliation, crack and granular disintegration. It is necessary to investigate the pagoda for precise deterioration assessment, monitoring and conservation treatment.