• Title/Summary/Keyword: mineral surface

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터널 건설에 따른 지하수-지표수 상호 작용 및 영향에 관한 연구

  • Kim, Tae-Hee;Kim, Young-Sik;Ha, Gyoo-Chul;Kim, Kue-Young;Koh, Dong-Chan;Yang, In-Jae;Hong, Soon-Taek
    • Proceedings of the Korean Geotechical Society Conference
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    • 2004.03b
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    • pp.839-846
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    • 2004
  • The objective of this study is the evaluation of the tunneling effect on the groundwater-surface water interaction. The designed tunnel line is laid beneath the Gapo-cheon, which runs throughout study area. And, the pre-evaluation of the tunnel-influence on the Gapo-cheon is urgently needed. However, it is very difficult to find out the similar domestic and/or foreign cases. In this study, we would exclude the numerical modeling technique with insufficient data. Instead of the evaluation of the tunneling effect on the groundwater-surface water interaction with the numerical modeling, we monitored the flow rate of surface water at various point. We measured the flow rate of surface water at 5 points. With the results of surface flow, we can conclude that 39% of flow rate in Gapo-cheon is contributed by the groundwater discharge, as baseflow.

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Effects of solution, sorbate, and sorbent chemistries on polycyclic aromatic hydrocarbon sorption to hydrated mineral surfaces

  • Yim, Soobin
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.09a
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    • pp.132-135
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    • 2003
  • Solution chemistry, sorbate chemistry, and sorbent chemistry were widely investigated to find important factors that affect PAH sorption on mineral surfaces and to elucidate its microscopic mechanism. The solution chemistry, pH and ionic strength caused measurable change of HOC sorption reaction to minerals. The detectable change of Ka occurred at a pH region crossing the PZC (Point of Zero Charge) of each mineral. The PAH hydrophobicity, one of sorbate chemistry, was observed to have a strong correlation with PAM sorption to mineral. Mineral surface area was not found to be a predominant factor controlling PAH sorption. The mineral type might be more likely to play a crucial role in controlling the PAH sorption behavior. The CEC (Cation Exchange Capacity) of mineral, representing surface charge density, has meaningful correlation with regression slope of sorption coefficients (log $K_{d}$) versus aqueous activity coefficients (log Υ$_{w}$).).).

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Paleoseismological implications of liquefaction-induced structures caused by the 2017 Pohang Earthquake

  • Gihm, Yong Sik;Kim, Sung Won;Ko, Kyoungtae;Choi, Jin-Hyuck;Bae, Hankyung;Hong, Paul S.;Lee, Yuyoung;Lee, Hoil;Jin, Kwangmin;Choi, Sung-ja;Kim, Jin Cheul;Choi, Min Seok;Lee, Seung Ryeol
    • Geosciences Journal
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    • v.22 no.6
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    • pp.871-880
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    • 2018
  • During and shortly after the 2017 Pohang Earthquake ($M_w$ 5.4), sand blows were observed around the epicenter for the first time since the beginning of instrumental seismic recording in South Korea. We carried out field surveys plus satellite and drone imagery analyses, resulting in observation of approximately 600 sand blows on Quaternary sediment cover in this area. Most were observed within 3 km of the epicenter, with the farthest being 15 km away. In order to investigate the ground's susceptibility to liquefaction, we conducted a trench study of a 30 m-long sand blow in a rice field 1 km from the earthquake epicenter. The physical characteristics of the liquified sediments (grain size, impermeable barriers, saturation, and low overburden pressure) closely matched the optimum ground conditions for liquefaction. Additionally, we found a series of soft sediment deformation structures (SSDSs) within the trench walls, such as load structures and water-escaped structures. The latter were vertically connected to sand blows on the surface, reflecting seismogenic liquefaction involving subsurface deformation during sand blow formation. This genetic linkage suggests that SSDS research would be useful for identifying prehistoric damage-inducing earthquakes ($M_w$ > 5.0) in South Korea because SSDSs have a lower formation threshold and higher preservational potential than geomorphic markers formed by surface ruptures. Thus, future combined studies of Quaternary surface faults and SSDSs are required to provide reliable paleoseismological information in Korea.

미생물 고정화 담체의 물리적 특성

  • 박영식;구기우
    • Journal of Environmental Science International
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    • v.7 no.3
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    • pp.269-274
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    • 1998
  • In order to develop of support medla for bloom reactor, physicochemical properties and attachability of surface of activated carbon, clay mineral, non-clay mineral, and waste mold sand were enamined. Measured physicochemical properties of materials were surface roughness, mean particle size, surface area, hydrophobicity, and surface charge. At a tested materials, activated carbon was the best attachable material and microorganisms were attached $20.1{\times}10^7CFU/cm^2$ at surface, compared with diatomaceous earth which were attached of $9.2{\times}10^7CFU/cm^2$ in our research, surface area and hydrophobicity show- ed more Influence than any other factor on attachment of microorganisms.

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Chemical Properties of Mineral Surfaces and Metal Ion Sorption: A Review (광물표면의 화학적 특성과 금속이온 수착의 고찰: A Review)

  • Yoon, Soh-Joung
    • Economic and Environmental Geology
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    • v.45 no.2
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    • pp.205-215
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    • 2012
  • Metal ions, toxic or potentially toxic to biota and human beings, can be immobilized by sorption onto the mineral surfaces in soils and sediments. This article briefly explains theories regarding the chemical properties of mineral surfaces to sorb metal ions and processes of extended X-ray absorption fine structure (EXAFS) analysis for sorption study, and reviews atomic-scale findings on metal sorption on mineral surfaces. The theoretical understanding on the chemistry of mineral surfaces and metal sorption is fundamental to the proper analysis of the atomic-scale spectroscopy to determine the sorption phases. Atomic-scale findings on metal sorption phases discussed here include co-precipitation, ternary complexation, aging effects, and desorption possibilities, as well as outer-sphere complexation, inner-sphere complexation, and surface precipitation.

Surface Modification Silica Nanoparticles by Aerosol Self Assembly (에어로졸 자기조립에 의한 실리카 나노분말의 표면개질)

  • Kil, Dae-Sup;Jang, Hee-Dong;Chang, Han-Kwon;Cho, Kuk;Kim, Sun-Kyung;Oh, Kyoung-Joon;Choi, Jin-Hoon
    • Korean Journal of Materials Research
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    • v.20 no.2
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    • pp.78-81
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    • 2010
  • Surface modification of silica nanoparticles was investigated using an aerosol self assembly. Stearic acid was used as surface treating agent. A two-fluid jet nozzle was employed to generate an aerosol of the colloidal suspension, which contained 20 nm of silica nanoparticles, surface modifier, and ethyl alcohol. Powder properties such as morphology, specific surface area and pore size distribution were analyzed by SEM, BET and BJH methods, respectively. Surface properties of the silica power were analyzed by FT-IR. The OH bond of the $SiO_2$ surface was converted to a C-H bond. It was revealed that the hydrophilic surface changed to a hydrophobic one due to the aerosol self assembly. Morphology of the surface treated powder was nanostructured with lots of pores having an average diameter of around $2\;{\mu}m$. Depending on the stearic acid concentration (0.25 to 1.0 wt%), the pore size distribution of the particles and the degree of hydrophobicity ranged from 1.5 nm to 180 nm and 29.6% to 50.2%, respectively.

Mono-layer Compositional Analysis of Surface of Mineral Grains by Time-of-Flight Secondary-Ion Mass Spectrometry (TOF-SIMS) (TOF-SIMS를 이용한 광물 표면의 단층조직 분석 연구)

  • Kong Bong Sung;Chryssoulis Stephen;Kim Joo Young
    • Journal of the Mineralogical Society of Korea
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    • v.18 no.2
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    • pp.127-134
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    • 2005
  • Although the bulk composition of materials is one of the major considerations in extractive metallurgy and environmental science, surface composition and topography control surface reactivity, and consequently play a major role in determining metallurgical phenomena and pollution by heavy metals and organics. An understanding of interaction mechanisms of different chemical species at the mineral surface in an aqueous media is very important in natural environment and metallurgical processing. X-ray photoelectron spectroscopy (XPS) has been used as an ex-situ analytical technique, but the material to be analyzed can be any size from $100\;{\mu}m$ up to about 1 cm. It can also measure mixed solids powders, but it is impossible to ascertain the original source of resulting x-ray signals where they were emitted from, since it radiates and scans the macro sample surface area. The study demonstrated the ability of TOF-SIMS to detect individual organic species on the surfaces of mineral particles from plant samples and showed that the TOF-SIMS techniques provides an excellent tool for establishing the surface compositions of mineral grains and relative concentrations of chemicals on mineral species.

CLSM [Confocal Laser Scanning Microscope] Observation of the Surface Roughness of Pressurized Rock Samples During Freeze/Thaw Cycling

  • Kim, Hye-jin;Choi, Junghae;Chae, Byung-gon;Kim, Gyo-won
    • The Journal of Engineering Geology
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    • v.25 no.2
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    • pp.165-178
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    • 2015
  • Physical and chemical weathering degrades rock, affecting its structural properties and thus the stability of stone buildings or other structures. Confocal laser scan microscopy (CLSM) is used here to observe temporal changes in the surface roughness of rock samples under simulated accelerated weathering. Samples were pressurized to 50, 55, or 70 MPa using a pressure frame, and subjected to freeze/thaw cycling controlled by a thermostat. The temperature was cycled from -20℃ to 40℃ and back. After each 20 cycles, CLSM was used to assess the change in surface roughness, and roughness factors were calculated to quantify the progression of the surface condition over time. Variations in cross-section line-roughness parameters and surface-roughness parameters were analyzed for specific parts of the sample surfaces at 5× and 50× magnification. The result reveals that the highest and lowest values of the roughness factors are changed according to elapsed time. Freezing/thawing at high pressure caused larger changes in the roughness factor than at low pressure.

Dispersion Characteristics of Natural Crystalline Graphite Powders by Surface Modification (표면개질에 의한 인상흑연 분체의 분산특성 연구)

  • Kim, Byeong-Gon;Choe, Sang-Geun;Jeong, Heon-Saeng;Han, Sang-Geun;Lee, Jae-Jang
    • Korean Journal of Materials Research
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    • v.11 no.8
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    • pp.679-684
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    • 2001
  • The surface of natural graphite has not only good electrical conductivities and lubrication properties but also has strong hydrophobicity. There are no functional groups and chemical properties on it. It is difficult to join with any other ions and to disperse in aqueous system. In order to increase dispersion ability throughout modification of surface property, it is necessary to let graphite have some function on its surface by the adsorption of surfactant molecules. In this study, using zeta potential adsorbed surfactant molecules(ABDM) on graphite surface and its surface Properties turn hydrophobic into hydrophilic. The dispersing mechanism of graphite particles in aqueous system has been explained using the DLVO theory, It is concluded that the high dispersable graphite suspension of which dispersing stability$(T_{1/2})$ is 44.5 hours at pH 10 and 22.5mV zeta potential can be produced.

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A REVIEW OF THE ROCK MECHANICAL AND ENGINEERING GEOLOGICAL RESEARCH AT GJOVIK OLYMPIC CAVERN (GJOEVIK올림픽 경기장(암반역학 및 지질공학 분야))

  • Barton, N.;By, T.L.;Chryssanthakis, P.;Tunbridge, L.;Kristiansen, J.;Loset, F.;Bhasin, R.K.;Westerdahl, H.;Vik, G.;Myrvang, A.;Hansen, S.E.;Lv, Ming;Stjern, G.;Ruistven, H.;Kjorholt, H.;Lee, M.S.
    • Proceedings of the Korean Geotechical Society Conference
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    • 1993.10b
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    • pp.235-247
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    • 1993
  • The 62 m span Olympic lee Hockey cavern in Gjovik, Norway, is located in jointed gneiss of average RaD = 70% and has a rock cover of only 25 to 50m, thus posing challenging design p problems. The investigations prior to construction included two types of stress measurements, cross-hole seismic tomography, special coe logging, Q-system classification and numerical modelling with UDEC-BB. Predicted maximum deformations were 4 to 8 mm; surprisingly small due to the high horizontal stresses recorded. Extensometer (MPBX) installations from the surface prior to construction, precision surface levelling and MPBX installed from inside the cavern give a combined measure of maximum deformations in the range 7 to 8 mm with the 62 m span fully e excavated, and three adjacent caverns for the Postal Services also completed.

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