• Title/Summary/Keyword: mineral soil

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A Study on Magnetization of Layered Metal Sulfide for the Removal of Cesium Ions from Aqueous Solution (수중 세슘 제거를 위한 층상 황화 금속 물질 자성화 연구)

  • Chul-Min Chon;Jiwon Park;Jungho Ryu;Jeong-Yun Jang;Dong-Wan Cho
    • Journal of Soil and Groundwater Environment
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    • v.28 no.4
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    • pp.1-5
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    • 2023
  • In the fabrication of magnetic adsorbent by incorporating iron species on base materials with layered structure, there can be a potential loss of adsorption capacity from the penetration of dissolved iron species into the structure. This work newly synthesized a magnetic adsorbent by incorporating nano magnetite and glucose into layered metal sulfide via hydrothermal treatment, and tested the removal efficiencies of cesium ions (Cs+) by the adsorbents fabricated under different conditions (final temperature and glucose mass ratio). As a result, the optimal fabrication condition was found to be mass ratio of 1 (layered metal sulfide): 0.1 (nano magnetite): 0.4 (glucose) and final temperature of 160℃. As-prepared adsorbent possessed good adsorption ability of Cs+ (54.8 mg/g) without a significant loss of adsorption capacity from attaching glucose and nano magnetite onto the surface.

Extraction Characteristics and Quantitational Methods for Total Petroleum Hydrocarbons in Soil

  • Jeon, Chi-Wan;Lee, Jung-Hwa;Song, Kyung-Sun;Lee, Sang-Hak;Lee, Jung-Min
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2003.11a
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    • pp.119-122
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    • 2003
  • Quantitation methods of total petroleum hydrocarbons to determinate oil contaminated level in soil were discussed. Extraction characteristics of several pretreatment methods and practical detection limit and reappearances in gas chromatography/mass spectrometry. with each pretreatment method were investigated. The obtained results showed that the newly adopted quantitation method and mechanical shaking extraction method using methanol with extraction solvent are more practical and applicable to real sample than the conventional methods. In applying these methods to gasoline, kerosene, fuel oil which are major source of soil contamination, the practical quantitation limit and % relative standard deviation was able to determine with range of 2.5 - 10 ppm, 5 - 7 %.

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Applicability of the Multi-Channel Surface-soil CO2-concentration Monitoring (SCM) System as a Surface Soil CO2 Monitoring Tool (다채널 지표토양 CO2 농도 모니터링(SCM) 시스템 개발 및 적용성 평가 연구)

  • Sung, Ki-Sung;Yu, Soonyoung;Choi, Byoung-Young;Park, Jinyoung;Han, Raehee;Kim, Jeong-Chan;Park, Kwon Gyu;Chae, Gitak
    • Journal of Soil and Groundwater Environment
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    • v.20 no.1
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    • pp.41-55
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    • 2015
  • Monitoring of $CO_2$ release through the ground surface is essential to confirm the safety of carbon storage projects. We conducted a feasibility study of the multi-channel surface-soil $CO_2$-concentration monitoring (SCM) system as a soil $CO_2$ monitoring tool with a small scale injection test. The background concentrations showed the distinct diurnal variation. The negative relation of $CO_2$ with temperature and the low $CO_2$ concentrations during the day imply that surface-soil $CO_2$ depends on photosynthesis and respiration. After 4.2 kg of $CO_2$ injection (1 m depth for 29 minutes), surface-soil $CO_2$ concentrations increased in the all five chambers, which were located less than 2.8 m of distance from each other. The $CO_2$ concentrations seem to be recovered to the background around 4 hours after the injection ended. To determine the leakage, the data from Chamber 2 and 5 with low increase rates were used for statistical analyses. Coefficient of variation for 30 minutes ($CV_{30min}$.) is efficient to determine a leakage signal, with reflecting the fast change in $CO_2$ concentrations. Consequently, SCM and $CV_{30min}$ could be applied for an efficient monitoring tool to detect $CO_2$ release through the ground surface. Also, this study provides ideas for establishing action steps after leakage detection.

REE Mineralization of Quy Hop Area in Nghe An Province, Northern Vietnam (베트남 북부 네안성 뀌홉지역 희토류 광화작용)

  • Lee, Jae-Ho;Jin, Kwang-Min;Heo, Chul-Ho
    • Journal of the Mineralogical Society of Korea
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    • v.31 no.3
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    • pp.193-213
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    • 2018
  • Soil geochemical exploration to check anomalies related to mineralization was carried out targeting around Quy Hop area within Nghe An province, Northern Vietnam. The interval of sampling are horizontal 250 m with 13 line and longitudinal 300 m with 25 line, resulting in 325 soil samples. Based on the result of soil geochemical exploration, the pitting survey was carried out targeting the grid point with high TREO content, resulting in 73 soil samples within 8 pits. The geology of the survey area are consisted of Ban Chieng biotite granite complex intruding Bu Khang formation comprising of schist, gneiss and limestone. In order to elucidate the source rock of monazite and xenotime confirmed from heavy sand, soil geochemical exploration was carried out. By ICP-MS result of soil samples, total REE oxide content of background amount is about 1.4 times of crustal abundance, depleting the light rare earth (about 0.2 times) and enriching the heavy rare earth (about 1.5 times). By ICP-MS result of pit soil samples, we identified TREO more than 1,000 ppm in 6 pits. It may be considered that REE ore bodies may develop in NE-SW direction, compared with the geochemical results of Quy Chau area.

Clay Mineral Composition of the Soils Derived from Residuum and Colluvium (잔적 및 붕적모재 토양의 점토광물 특성구명)

  • Zhang, Yong-Seon;Sonn, Yeon-Kyu;Jung, Sug-Jae;Lee, Gye-Jun;Kim, Myung-Sook;Kim, Sun-Kwan;Lee, Ju-Young;Pyun, In-Hwan
    • Korean Journal of Soil Science and Fertilizer
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    • v.39 no.5
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    • pp.245-252
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    • 2006
  • This experiment was conducted to investigate the distribution and compositions of clay mineral and to replenish the soil classification system in Korea. Soil layer samples were collected from 26 residuum and colluvium soil series out of 390 soil series in Korea, and then analyzed for soil physical and chemical characteristics, mineral and chemical compositions of clay in B horizon soils. Major clay minerals of residuum and colluvium were illite and chlorite in soils originated from the sedimentary rock such as limestone, shale, sandstone and conglomerate; quartz and kaolin in soils originated from rhyolite, neogene deposits, porphyry and tuff; and kaolin and quartz in the soils originated from granite, granite gneiss and anorthosite. Clay minerals in Korean soils were divided into 4 groups: mixed mineral group(MIX) mainly contained with illite, kaolin and vemiculite; kaolin group(KA) with kaolin and illite; chlorite group(CH) with chlorite and illite; and smectite group(SM) with kaolin, illite and smectite. The most predominant clay mineral group was kaolin group(KA) with kaolin and illite; an mixed mineral group(MIX) with illite, kaolin and vemiculite. Cation exchange capacity (CEC) of clay was low in the soils mainly composed with MIX and KA groups and silica-alumina molar ratio of clay was high in the soils composed with SM group

Analysis of rainfall infiltration characteristics for unsaturated soils using a column test equipment (모형실험장치를 이용한 불포화토의 강우 침투특성 분석)

  • Park, Kyu-Bo;Chae, Byung-Gon;Kim, Kyeong-Su
    • Proceedings of the Korean Geotechical Society Conference
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    • 2010.09a
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    • pp.736-742
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    • 2010
  • This study was conducted to characterize on the relationships of rainfall intensity and infiltration rate of rainfall dependent on unit weight change in the gneissic weathered soil by a column test equipment. In this study, volumetric water content and pore water pressure were measured using TDR sensors and tensiometers at regular time intervals. Rainfall conditions including continuous rainfall and repeated rainfall were selected in order to know the effect of antecedent rainfall. In the condition of rainfall intensity 20mm/h and the unit weights of soil as $1.35g/cm^3$, $1.55g/cm^3$ and $1.61g/cm^3$, average rainfall infiltration rate was $2.814{\times}10^{-3}cm/sec$, $1.969{\times}10^{-3}cm/sec$ and $1.252{\times}10^{-3}cm/sec$ respectively. The higher rainfall intensity and lower unit weight of soil, the faster average infiltration rate. Overflow in the column was happened except rainfall condition of rainfall intensity 20mm and soil unit weight $1.35g/cm^3$. Increasing the soil unit weight, overflowed water was increased and occurrence time was faster.

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Fate and Toxicity of Spilled Chemicals in Groundwater and Soil Environment III: organics (사고 누출 화학물질의 지하수 및 토양 환경 내 거동 및 환경 독성 특성 III: 유기화학물질을 중심으로)

  • Jeong, Seulki;Moon, Hee Sun;Shin, Doyun
    • Journal of Soil and Groundwater Environment
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    • v.24 no.1
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    • pp.1-9
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    • 2019
  • This study presents a technical perspective to the fate characteristics of phenol and m-cresol, which represent some of the most common organic chemicals found in chemical spill accidents, and likely to persist in soil and groundwater due to their highly stable physicochemical properties. Some cases of domestic and foreign chemical accidents linked to phenol and m-cresol contamination were compiled. Due to their low organic carbon-water partitioning coefficient (Koc), phenol and m-cresol tend to migrate into groundwater and remained as dissolved phase. On the other hands, phenol and m-cresol can be readily decomposed by microbes in soil and groundwater under appropriate conditions. Therefore, the fate characteristics of these chemicals are highly contingent on environmental conditions. Thus, if a great quantity of leakage is occurred by chemical accidents, the up-to-date and correct information about fate characteristics taking into account both the chemical and environmental conditions is greatly needed to minimized the potential hazards from these chemicals.