• Particle and aerosol research
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• v.15 no.4
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• pp.127-137
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• 2019

Recently, high electrochemical performance anode materials for lithium ion secondary batteries are of interest. Here, we present silicon-carbon-graphene (Si-C-GR) composites for high performance anode materials of lithium ion secondary battery (LIB). Aerosol process and heat-treatment were employed to prepare the Si-C-GR composites using a colloidal mixture of silicon, glucose, and graphene oxide precursor. The effects of the size of the silicon particles in Si-C-GR composites on the material properties including the morphology and crystal structure were investigated. Silicon particles ranged from 50 nm to 1 ㎛ in average diameter were employed while concentration of silicon, graphene oxide and glucose was fixed in the aerosol precursor. Morphology of as-fabricated Si-C-GR composites was generally the shape of a crumpled paper ball and the Si particles were well wrapped in carbon and graphene. The size range of composites was about from 2.2 to 2.9 ㎛. The composites including silicon particles larger than 200 nm in size exhibited higher performance as LIB anodes such as capacity and coulombic efficiency than silicon particles less than 100 nm, which were about 1500 mAh/g at 100 cycles in capacity and 99% in coulombic efficiency, respectively.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.29 no.11 s.242
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• pp.1229-1238
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• 2005

The objective of the present study was to investigate the efficacy of physical water treatment (PWT) technologies using different catalytic materials and an electronic anti-fouling device in the mitigation of mineral fouling in a once-through flow system with mini-channel heat exchanger. Effects of flow velocity and water hardness on the effectiveness of PWT technologies were experimentally studied. The artificial water hardness varied from 5.0 to 10 mo1/m$^{3}$ as CaCO$_{3}$. For 10 mo1/m$^{3}$ solution, fouling resistance reduced by 13-40$\%$ depending on flow velocity and types of PWT devices. On the other hand, fouling resistance reduced by 21-29$\%$ depending on the PWT devices for 5 mo11m3 solutions. The PWT device using alloy of Cu and Zn as catalyst (CM2) was slightly more effective than the others. SEM photographs of scale produced from the 10 mol/m$^{3}$ solution at 1.0 m/s indicated that calcium carbonate scales without PWT devices were needle-shaped aragonite, which is sticky, dense and difficult to remove. Scales with the PWT devices showed a cluster of spherical or elliptic shape crystals. Both the heat transfer test results and SEM photographs strongly support the efficacy of PWT technologies using catalytic materials and an electronic anti-fouling device in the mitigation of mineral fouling.

• Culinary science and hospitality research
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• v.14 no.3
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• pp.210-222
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• 2008

This study showed that the brown stock, which is the base of demi-glace sauce, extracted by using a high pressure heating extractor is more advantageous than that extracted by the traditional extraction method for the mass production. We compared the former with the latter in terms of minerals and free amino acids. The results of this study are summarized as follows. When mineral contents were compared, the brown stock extracted by high.pressure heating extraction showed the tendency of increase in mineral contents in proportion to heating temperature and heating time, but, from extraction temperature of 140$^{\circ}C$, the contents of K, Mg, Na and P decreased with the increase of extraction time. In addition, mineral contents in the brown stock extracted by high-pressure heating extraction were generally lower than those in brown stock extracted by the traditional extraction method. This result was produced probably because materials were added repeatedly in the traditional method. Amino acids contents in brown stock according to the extraction methods were also examined. They increased with the increase in the number of extractions in the brown stock extracted by the traditional method, and those in the brown stock extracted using a high pressure heating extractor increased with the increase in heating temperature and extraction time. The results of this study are expected to be useful as a practical material for the mass production of brown stock products.

• Korean Journal of Materials Research
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• v.20 no.2
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• pp.78-81
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• 2010

Surface modification of silica nanoparticles was investigated using an aerosol self assembly. Stearic acid was used as surface treating agent. A two-fluid jet nozzle was employed to generate an aerosol of the colloidal suspension, which contained 20 nm of silica nanoparticles, surface modifier, and ethyl alcohol. Powder properties such as morphology, specific surface area and pore size distribution were analyzed by SEM, BET and BJH methods, respectively. Surface properties of the silica power were analyzed by FT-IR. The OH bond of the $SiO_2$ surface was converted to a C-H bond. It was revealed that the hydrophilic surface changed to a hydrophobic one due to the aerosol self assembly. Morphology of the surface treated powder was nanostructured with lots of pores having an average diameter of around $2\;{\mu}m$. Depending on the stearic acid concentration (0.25 to 1.0 wt%), the pore size distribution of the particles and the degree of hydrophobicity ranged from 1.5 nm to 180 nm and 29.6% to 50.2%, respectively.

• Journal of the Korean earth science society
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• v.29 no.7
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• pp.523-530
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• 2008

The phase changes and variations of elemental contents in hematite medicinal mineral were investigated by a traditional processing operation including heating and quenching in vinegar. Hematite was processed at $650^{\circ}C$ and $900^{\circ}C$ through at least 5 processing cycles. Metal extraction tests in water were carried out with the processed hematite. Heating and quenching in vinegar could not change the phase of hematite. The effect of this traditional method was not clear because there were no variational trends between extracted elements and the number of processing cycles at $650^{\circ}C$ and $900^{\circ}C$. However, the traditional processing operation of heating and quenching in vinegar was very effective to change the hematite mineral towards soft and easily crushing medicinal material.

• Journal of the Korea institute for structural maintenance and inspection
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• v.22 no.2
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• pp.16-25
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• 2018

Concrete is a suitable construction material for long-term structure, however, it is needed to understand the calcium leaching damage caused by exposure to underground pure water for a long time. In this paper, it is experimentally investigated that the characteristics of flexural behavior in RC member damaged by calcium leaching degradation. From the test results, when calcium leaching is happened, yielding load and flexural rigidity is reduced, neutral axis depth and displacement is increased. That is, calcium leaching degradation adversely affects RC member performance. And, when the mineral admixture is used in the calcium leaching environment, it is considered that the optimal replacement ratio should be prepared according to the type of mineral admixture.

• Nuclear Engineering and Technology
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• v.53 no.7
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• pp.2418-2425
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• 2021

Monazite is a phosphate mineral that contains thorium (Th) and rare earth elements. The Th concentration in monazite can be as high as 500 ppm, and it has the potential to be used as fuel in the nuclear power system. Therefore, this study aimed to conduct the techno-economic analysis (TEA) of Th extraction in the form of thorium oxide (ThO₂) from monazite. Th can be extracted from monazite through an alkaline fusion method. The TEA of ThO₂ production studied parameters, including raw materials, equipment costs, total plant direct and indirect costs, and direct fixed capital cost. These parameters were calculated for the production of 0.5, 1, and 10 ton ThO₂ per batch. The TEA study revealed that the highest production cost was ascribed to installed equipment. Furthermore, the highest return on investment (ROI) of 21.92% was achieved for extraction of 1 ton/batch of ThO₂, with a payback time of 4.56 years. With further increase in ThO₂ production to 10 ton/batch, the ROI was decreased to 5.37%. This is mainly due to a significant increase in the total capital investment with increasing ThO₂ production scale. The minimum unit production cost was achieved for 1 ton ThO₂/batch equal to 335.79 $/Kg ThO₂.

• Journal of the Mineralogical Society of Korea
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• v.19 no.4 s.50
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• pp.277-289
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• 2006

This study was carried out to find a new material having high removal efficiency for the harmful red tide. C. polykrikoides grow very fast and accumulate into dense and visible patches near the surface of the seawater ('Water bloom'). Some mineral medicines and Hwangto (reddish soil consist of clay minerals and Fe-oxides) were used in this study to remove C. polykrikoides. The pre-determined sprinkling ratio of mineral vs. seawater which contains approximately 5,000 cells/mL of C. polykrikoides was 10 g/L. In order to quantify the removal efficiency, the density of living cells was measured by counting with the Intervals of 0, 10, 30, and 60 minutes after sprinkling. Five Hwangtos feom different localities were examined in this study. It is found that a material with a high concentration of Fe and Al was the most effective to remove C. polykrikoides. After the sprinkling of the Hwangto showing the best removal efficiency in the test, 99% of total algaes were found to be eliminated within 60 minutes. Jeokeokji showed the highest removal efficiency among clay mineral medicines(92% removal efficiency after 60 minutes), and the rests in decreasing order are as follows: Gamto (91%) > Baekseokji (89%) > Hydromica (81%). In addition, Fe-oxide mineral medicine similarly looking as fine-grained earthy Daejaseok showed 100% removal efficiencyafter 30 minutes, and Wooyoeryang, 95% after 60 minutes. It is noted that even little addition (1 g/L) of Daejaseok, 10% of Hwangto concentration into seawater showed the removal efficiency of 100% after 60 minutes. From the results, it could be concluded that the fine-grained earthy Daejaseok was the most effective natural mineral medicine to remove the C. polykrikoides from seawater. Under the microscope the removal mechanism was found to be activated in the following order: adsorption, swelling of chain colony, chain colony crisis and algaecide.

• Clean Technology
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• v.25 no.4
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• pp.289-295
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• 2019

Though the usage of vinyls and plastics produced from fossil fuels has been increasing in the world, the eco-friendly domestic disposal or recycling of waste vinyls has to be executed because the migration or importation of waste vinyls or waste plastics are globally prohibited. Even though the eco-friendly domestic disposal or recycling of waste vinyls and waste plastics should be developed, promising eco-friendly recycling methods are few because there are extraneous substances in waste vinyls and waste plastics. Also, conventional incineration and landfill methods result in secondary contamination and then increase disposal costs. Therefore, the selective elimination of extraneous substances or other materials included in waste vinyls and waste plastics could make valuable recycling or reuse possible. In particular, the novel hybrid process in which crushing and screening are simultaneously conducted in a rotary kiln type reactor can domestically maximize the material recycling or reuse. In this study, the feasibility study for a crushing/screening hybrid process developed in Korea was performed and evaluated in case of thermal recycling (TR) and material recycling (MR). The effect of various subsidies on economic efficiency was especially evaluated by means of domestic recycling plans. The incentive revenues from waste vinyl recycling and the incineration share of waste vinyls affected the net present values and internal rate of returns of the hybrid process.

• Journal of Conservation Science
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• v.36 no.3
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• pp.152-161
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• 2020

The purpose of this study was to compare the chemical properties of white soil and refined clay sediment, which are produced early in the refining process. The characteristics of the white wares made at the kiln site in Goseong-ri, Chuncheon were also examined. Three groups of materials were examined: white wares excavated from the white wares kiln, raw material from white soil collected from the surface, and a refined clay sediment group. There were also three analysis methods, which were a main components analysis, a trace components analysis, and a mineral analysis. The main components analysis found that the white wares clay was in the RO₂4.04~4.28 and the RO + R₂O 0.30~0.31 mole areas, which were similar to the results for the refined clay sediment. However, the refining process used to produce better quality white wares meant that the large differences in the early white soil raw material appeared in the refined sediment. The mineral phase analysis showed that the crystals detected in the early white soil raw materials and refined clay sediment were almost identical. However, quartz and mullite mineral phases, which can occur above a certain temperature, were detected in the excavated white wares clay. Rare earth elements that were not affected by the pottery making process and the weathering of clay materials were found to have the same origin in all three groups.