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Effect of Blood Contamination on the Push-Out Bond Strength and Surface Morphology of Tricalcium Silicate Materials (혈액오염이 Tricalcium Silicate 재료의 압출강도와 표면형태에 미치는 영향)

  • Park, Misun;Kim, Jaehwan;Choi, Namki;Kim, Seonmi
    • Journal of the korean academy of Pediatric Dentistry
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    • v.43 no.1
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    • pp.36-43
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    • 2016
  • The aim of this study was to evaluate the effect of blood contamination on the push-out bond strength and surface morphology of tricalcium silicate materials; Biodentine$^{(R)}$, Theracal$^{(R)}$ and mineral trioxide aggregate. The standardized lumens of root slices prepared from extracted single-root human teeth were filled with Biodentine$^{(R)}$, Theracal$^{(R)}$ and mineral trioxide aggregate by manufacturer's instruction. The specimens were randomly divided into 2 groups (n = 20) for each material and then incubated for 4 days at $37^{\circ}C$; control group (phosphate buffered saline solution) and experimental group (fetal bovine serum). The push-out bond strengths were then measured by a universal testing machine and the surface morphology of each experimental group was analyzed by scanning electron microscope. Biodentine$^{(R)}$ and Theracal$^{(R)}$ showed higher push-out bond strength compared with mineral trioxide aggregate after exposure to fetal bovine serum. A substantial change in the surface morphology of each material was observed after exposure to fetal bovine serum. In conclusion, the push-out bond strengths of Biodentine$^{(R)}$ and Theracal$^{(R)}$ were higher than mineral trioxide aggregate when exposed to blood contamination. Therefore, it is supposed that the use of Biodentine$^{(R)}$ and Theracal$^{(R)}$ is appropriate in the presence of blood.

Attrition and Heat Transfer Characteristics of Fluidized Bed Materials for a Solar Hybrid Process (태양열 하이브리드 공정을 위한 유동층 입자들의 마모 및 열전달 특성 연구)

  • Kim, Hyung Woo;Lee, Doyeon;Nam, Hyungseok;Hong, Young Wan;Seo, Su Been;Go, Eun Sol;Kang, Seo Yeong;Lee, See Hoon
    • Clean Technology
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    • v.26 no.1
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    • pp.65-71
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    • 2020
  • Various solar hybrid energy conversion processes, which have both the advantages of renewable energy sources and fossil energy sources, have been developed in the world because stable and predictable energy supplies, such as electricity and natural gas, are necessary for modern societies. In particular, a solar hybrid energy conversion process based on a dual fluidized bed process concept has been expected as the promising solution for sustainable energy supply via thermochemical conversions, such as pyrolysis, combustion, gasification, and so on, because solar thermal energy could be captured and stored in fluidized bed materials. Therefore, the attrition and heat transfer characteristics of silicon carbide and alumina particles used for fluidized bed materials for the solar hybrid energy conversion process were studied in an ASTM D5757 reactor and a bubbling fluidized bed reactor with 0.14m diameter and 2m height. These characteristics of novel fluidized bed materials were compared with those of sand particles which have widely been used as a fluidized bed material in various commercial fluidized bed reactors. The attrition resistances of silicon carbide and alumina particles were higher than those of sand particles while the average values of heat transfer coefficient in the bubbling fluidized bed reactor were in the range of 125 ~ 152 W m-2K-1.

Mono-layer Compositional Analysis of Surface of Mineral Grains by Time-of-Flight Secondary-Ion Mass Spectrometry (TOF-SIMS) (TOF-SIMS를 이용한 광물 표면의 단층조직 분석 연구)

  • Kong Bong Sung;Chryssoulis Stephen;Kim Joo Young
    • Journal of the Mineralogical Society of Korea
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    • v.18 no.2
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    • pp.127-134
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    • 2005
  • Although the bulk composition of materials is one of the major considerations in extractive metallurgy and environmental science, surface composition and topography control surface reactivity, and consequently play a major role in determining metallurgical phenomena and pollution by heavy metals and organics. An understanding of interaction mechanisms of different chemical species at the mineral surface in an aqueous media is very important in natural environment and metallurgical processing. X-ray photoelectron spectroscopy (XPS) has been used as an ex-situ analytical technique, but the material to be analyzed can be any size from $100\;{\mu}m$ up to about 1 cm. It can also measure mixed solids powders, but it is impossible to ascertain the original source of resulting x-ray signals where they were emitted from, since it radiates and scans the macro sample surface area. The study demonstrated the ability of TOF-SIMS to detect individual organic species on the surfaces of mineral particles from plant samples and showed that the TOF-SIMS techniques provides an excellent tool for establishing the surface compositions of mineral grains and relative concentrations of chemicals on mineral species.

Upstream Risks in Domestic Battery Raw Material Supply Chain and Countermeasures in the Mineral Resource Exploration Sector in Korea (국내 배터리원료광종 공급망 업스트림 리스크와 광물자원탐사부문에서의 대응방안)

  • Oh, Il-Hwan;Heo, Chul-Ho;Kim, Seong-Yong
    • Economic and Environmental Geology
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    • v.55 no.4
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    • pp.399-406
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    • 2022
  • In line with the megatrend of 2050 carbon neutrality, the amount of critical minerals used in clean-energy technology is expected to increase fourfold and sixfold, respectively, according to the Paris Agreement-based scenario as well as the 2050 carbon-neutrality scenario. And, in the case of Korea, in terms of the battery supply chain used for secondary batteries, the midstream that manufactures battery materials and battery cell packs shows strength, but the upstream that provides and processes raw materials is experiencing difficulties. The Korea Institute of Geoscience and Mineral Resources has established a strategy to secure lithium, nickel, and cobalt and is conducting surveys to respond to the upstream risk of these types of battery raw materials. In the case of lithium, exploration has been carried out in Uljin, Gyeongsangbuk-do since 2020, and by the end of 2021, the survey area was selected for precision exploration by synthesizing all exploration data and building a 3D model. Potential resources will be assessed in 2022. In the case of nickel, the prospective site will be selected by the end of 2022 through a preliminary survey targeting 10 nickel sulfide deposits that have been prospected in the past. In the case of cobalt, Boguk cobalt is known only in South Korea, but there is only a record that cobalt was produced as a minor constituent of hydrothermal deposit. According to the literature, a cobalt ore body was found in the contact area between serpentinite and granite, and a protocol for cobalt exploration in Korea will be established.

Recovery of Platinum Group Metals from the Leach Solution of Spent Automotive Catalysts by Cementation (자동차(自動車) 폐촉매(廢觸媒)의 침출액(浸出液)으로부터 시멘테이션에 의한 백금족(白金族) 금속(金屬)의 회수(回收))

  • Kim, Min-Seuk;Kim, Byung-Su;Kim, Eun-Young;Kim, Soo-Kyung;Ryu, Jae-Wook;Lee, Jae-Chun
    • Resources Recycling
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    • v.20 no.4
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    • pp.36-45
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    • 2011
  • The recovery of platinum group metals (PGMs) from the leach solution of spent auto-catalyst and the wash solution of the leach residue was investigated in the laboratory scale experiments by the cementation process using metal powders as the reductant. In this study, the effect of Al, Mg and Zn powders on the cementation process was particularly examined. Aluminum powder was selected as the most suitable reductant for the cementation of PGMs. At the cementation time of 10 minute under the aluminium stoichimetric amount of 19.3 and the reaction temperature of $50{\sim}60^{\circ}C$, the recovery of platinum group metals from the leach solution of the spent auto-catalyst was found to be 99.3%, 99.4%, 90.2% for Pt, Pd and Rh, respectively. Under the same conditions with the aluminium stoichimetric amount of 45, the recovery of platinum group metals from the wash solution of the leach residue of spent catalyst was observed to be 97%, 97% and 90% for Pt, Pd and Rh, respectively. In addition, it was possible to upgrade the platinum group metals in the precipitates obtained from the cementation process by about 10% through the removal of metal impurities by the nitric acid leaching at ambient temperature.

Current Research Trends for Treatment of Microplastics (미세플라스틱 처리를 위한 연구동향)

  • Kim, Seong-Min;Baek, Sang-Ho;Han, Yosep;Davaadorj, Tsogchuluun;Go, Byung-Hun;Jeon, Ho-Seok
    • Resources Recycling
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    • v.29 no.5
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    • pp.15-27
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    • 2020
  • Microplastics are recognized as critical and serious environmental problem in worldwide. Plastics are inexpensive, lightweight, excellent in processability, and various in material-specific properties. Along industrial development, the production and disposal amount of plastics are also rapidly increasing. In particular, abundant plastic wastes are eventually disposed into marine environment with harmful impacts on the ecosystem. Therefore, lots of relevant studies were recently progressed in various fields. However, many studies are being just conducted due to its difficulty in applying a general treatment method for those small particle sizes and their various characteristics. In the meantime, lots of researches are being conducted on applying methods using physical properties such as specific gravity, magnetic, and electrostatic separation, which are beneficiation processes of minerals. However, since it is still in the laboratory stage, the development of larger scale separation technology for efficient treatment is urgent.

Setting and Compressive Strength Development of Hihg Flowing Concrete (고유동 콘크리트의 응결특성과 압축강도 발현)

  • 권영진;김무한
    • Proceedings of the Korea Concrete Institute Conference
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    • 1995.10a
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    • pp.8-13
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    • 1995
  • High flowing concrete has been made using a combination of different cementitious material. The use of supplementary cementitious material like ground granulated slag is not only interesting from an economical point of view but also from a mechanical and rheological point of view. In the case of high strength concrete, relation between the maturity and compressive strength development of high strength concrete is aproximated by appling gompertz curve and suggested new estimating method. It is the aim of this study to analysis the effect of different types of mineral fine power on the setting and compressive strength development of high flowing concrete.

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