• 전기화학회지
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• 제11권1호
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• pp.47-50
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• 2008

현재 상용화 되어있는 흑연의 저용량 문제를 해결하기 위해 실리콘이나 주석계 등 고용량 비탄소계 음극전극재료들이 연구되고 있다. 이 중 산화실리콘(SiO)은 초기 충전(환원)과정에서 Li이 삽입되면서 $Li_2O$생성으로 비가역 비용량이 발생하여 초기 싸이클에서 쿨롱효율이 낮고, 싸이클링에 따라 리튬 탈 삽입 과정의 비용량이 증가하는 특징으로 실제의 전지를 설계할 시 문제점을 가진다. 본 연구에서는 고용랑 특성을 나타내는 비탄소계 실리콘을 포함하는 리튬이차전지용 음극활물질과 흑연의 복합체를 제조하여 흑연으로 실리콘의 부피팽창을 완화시키고, 사이클 특성을 향상시키는 실리콘(SiO-Graphite) 재료를 개발하고, 산화실리콘과 흑연 복합체의 높은 비가역 용량의 해소와 싸이클에 따른 리튬 탈삽입 과정의 용량증가를 해소하기 위한 전처리를 통하여 초기 효율을 향상한 전극의 제조에 대하여 연구하였다.

• 한국정밀공학회지
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• 제21권12호
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• pp.174-181
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• 2004

Ultra precision positioning mechanism has widely been used on semiconductor manufacturing equipments, optical spectrum analyzer and cell manipulations. Ultra precision positioning mechanism is consisted of several actuators, sensors, guides and control systems. Its efficiency depends on each performance of components. The object of this study is to design, analysis and manufacture all of the inchworm linear motor system, which is one of the equipments embodied in ultra precision positioning mechanism. Inchworm linear motor system is consisted of a controller system and an inchworm linear motor, and its driving form is similar to a motion of spanworm. A design and manufacture of inchworm linear motor, which is consisted of three PZT actuators, a rod, two columns and a guide plate, are performed. Minimizing the von-Mises stress of the hinge using Taguchi method and simulation by FEM software optimizes the structural design in a column of flexure hinge. The designed columns and guide plates are manufactured by a W-EDM and NC-milling. A controller system, which is an apparatus to drive inchworm linear motor, can easily adjust driving conditions by varying resonance frequency and input-output voltage of actuators and amplifiers. The performance of manufactured inchworm linear motor system is verified and valuated. In the future, inchworm linear motor system will be used to make a more precision positioning by reinforcing a sensor and feedback system.

• 대한전자공학회:학술대회논문집
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• 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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• pp.315-324
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• 2001

Mechanochemical effects that occurred in the fine grinding process of quartz particles using planetary ball mill was investigated. Quartz particles have been frequently utilized for optical materials, semiconductor molding materials. We determined that grinding for a long time can be create amorphous structures from the crystalline quartz by Mechanochemical effects. But, to be produced nano-composite particles that the critical grinding time reached for composite materials in a short time. Henceforth, a qualitative estimation must be conducted on the filler for EMC(Epoxy molding compound) materials. It can be produced mechanochemically treated composite materials and also an integrated grinding efficiency considering of the nano-composite amorphous structured particles. The mechanochemical characteristics were evaluated based on particle morphology, size distribution, specific surface area, density and the amount of amorphous phase materials into the particle surface. The grinding operation in the planetary ball mill can be classified into three stages. During the first stage, initial particle size was reduced for the increase of specific surface area. In the second stage, the specific surface areas increased in spite of the increase in particle size. The final stage as a critical grinding stage, the ground quartz was considered mechanochemically treated particles as a nano- composite amorphous structured particles. The development of amorphous phase on the particle surface was evaluated by X-ray diffractometry, thermal gravity analysis and IR spectrometer. The amount of amorphous phase of particles ground for 2048 minutes was 85.3% and 88.2% by X-ray analysis and thermal gravity analysis, respectively.

• 자원리싸이클링
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• 제17권5호
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• pp.44-51
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• 2008

본 연구에서는 국산 99.7%순도의 수산화알루미늄을 대상으로 미량원소로 함유되어 있는 Na, Ca및 Fe의 제거실험을 수행하였다. 용출액으로는 유기산인 oxalic acid와 citric acid를 사용하였으며 수산화알루미늄은 초기 입도가 서로 다른 2종류의 시료를 사용하였다. 수산화알루미늄의 미립화를 위해 ball mill을 사용하여 미분쇄 실험을 수행하였으며, 용출조건에 따른 미량원소의 용출특성을 조사하였다. 실험결과 0.1$\sim$1.0mole/l 농도범위에서 oxalic acid에 의한 원소 용출율이 citric acid보다 높은 것으로 나타났으며, 유기산 농도가 증가할수록 또한 반응온도가 증가할수록 원소의 용출율은 증가하였다. 미분쇄 공정시 순수한 물에 의한 Na의 용출율은 약 45%에 달해 aluminum hydroxide에 함유된 Na성분의 상당 부분은 수용성 화합물인 것으로 확인되었다.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 1995년도 춘계학술대회 논문집
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• pp.400-407
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• 1995

The straightness property is one of fundamental geometric tolerances to be strictly controlled for guideways of machine tools and measuring machines. The staightness measurement for long guideways was usually difficult to perform, and it needed additional equipments or special treatment with limited application. In this paper, a new approach is proposed using the profile matching technique for the long guideways, which can be applicable to most of straghtness measurements. An edge of relativelly sthort length is located along a divided section of a long guideway, and the local straightness measurement is performed. The edge is then moved to the next section with several positions overlap. After thelocal straightness profile is measured for every section along the long guideway with overlap, the global straightness profile is constructed using the profile matching technique based on theleast squares method. The proposed techinique is numerically tested for two cases of known global straightness profile arc profile and irregular profile and those profiles with and without random error intervention, respectively. When norandom errors are involved, the constructed golval profile is identical to the original profile. When the random errors are involved, the effect of the number of overlap points are investigated, and it is also found that the difference between the difference between the constructed and original profiles is very close to the limit of random uncertainty with juist few overlap points. The developed technique has been practically applied to a vertical milling machine of moving table type, and showed good performance. Thus the accuracy and efficiency of the proposed method are demonstrated, and shows great potential for variety of application for most of straightness measuirement cases using straight edges, laser optics, and angular measurement equipments.

• 한국추진공학회지
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• 제20권2호
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• pp.18-23
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• 2016

유기 분자의 자기조립 다분자막은 기질의 표면에서 전자기적인 상호작용을 통해 자발적으로 형성된다. 본 연구에서는 이 기술을 응용하여 고에너지물질의 안전성과 취급용이성이 향상됨을 입증하였다. 최근 다양한 연구에서 고에너지물질 결정 내부의 결함은 물질의 안전성을 저하시키는 요인이므로, 결정 입자의 크기를 감소시키는 연구가 중요시되고 있다. 이에 따라, 결정화 방법을 통해 제조된 나노 수준의 고에너지물질을 사용하였으며, 자기조립 다분자막 기술을 응용하여 물질의 안전성을 향상시켰다. 입도/표면전하/마찰감도/정전기 전하 등을 측정하여 표면개질 여부를 확인하였다.

• 폴리머
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• 제37권4호
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• pp.470-477
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• 2013

가공이 쉬우면서도 성능이 우수한 염료 감응 태양 전지(DSSC)용 상대 전극을 제조하기 위하여 다중벽 탄소 나노튜브(MWCNT) 기반의 고충전 나노복합 페이스트를 제조하고, MWCNT의 분산 제어가 미치는 영향에 대하여 조사하여 보았다. MWCNT의 분산성을 향상시키기 위하여 폴리스티렌 기반의 기능성 블록 공중합체를 리빙 라디칼 중합법으로 합성하여 MWCNT의 표면 개질제로 사용하였으며, 적절한 용매 조건의 선택을 통하여 고충전 나노복합 페이스트의 가공성이 향상되는 것을 확인할 수 있었다. MWCNT의 분산 제어를 통해 이를 상대 전극으로 도입한 DSSC의 광전 변환 효율이 향상됨을 확인할 수 있었으며, 이는 볼밀법을 이용한 MWCNT의 물리적 분산을 통해서도 검증할 수 있었다. 미량의 platinum(Pt) 나노입자와 복합화시킬 경우, 표준 Pt 상대 전극보다도 더 우수한 성능을 가지는 MWCNT 기반 상대 전극을 제조할 수 있음을 확인하였다.

• 한국지반환경공학회 논문집
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• 제20권11호
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• pp.5-10
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• 2019

본 연구에서는 장파장에서 감응하는 광촉매를 개발하기 위하여 상용화된 $TiO_2$에 Ag를 도핑하여 제조하였으며 광촉매 효율을 향상시키기 위하여 귀금속의 분산을 증대시키는 마이크로에멀젼 방법을 이용하였다. 제조된 $Ag/TiO_2$의 물리적 특성은 SEM(Scanning Electron Microscopy), FE-TEM(Field Emission Transmission Electron Microscopy), DRS(Diffuse Reflectance Spectroscopy)를 통해 분석하였다. RO 16(Reactive Orange 16)에 대한 광촉매의 제거 효율은 25ppm의 RO 16을 대상으로 UV-A 영역(365nm)에서 수행하였다. Ag의 도핑방법에 의한 광촉매 효율을 비교하기 위해 볼밀링 및 딥코팅 방법으로 제조하여 광촉매 효율을 분석하였으며 광촉매 효율에 대한 Ag 및 계면활성제 함량에 대한 최적화를 진행하였다. 도핑방법에 따른 RO 16 제거효율 분석 결과, 마이크로에멀젼 방법으로 제조한 $Ag/TiO_2$의 RO 16 제거효율이 가장 높았으며 Ag 함량 2wt%, 계면활성제 0.5g에서 가장 높은 제거효율을 보였다.

• 한국정밀공학회지
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• 제10권2호
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• pp.114-125
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• 1993

In the present study the newly developed CAD/CAM system is applied to the process of the molding design, machining for mini-sized and precise processive die, and the production of press-stamped parts. When the design of a die was completed by means of CAD, wire cut NC data were generated with the aid of a design drawing in the CAD system and then inputed into the wire cut machine, and with the aid of a hole chart which had been made for this purpose, all the data were classified into the categories of CNC milling, jig boring, jig grinding, and machine center, and then developing a program of generating NC data, errors in process were reduced and programming time was shortened. The program was developed by using Autolisp language which was built-in the CAD, and realizing the intergation of designing a die, generating and processing NC data directly by a designer, designing time and machinery processing time were shorted. And the traditionally required working time for design. NC program required 6 days of work becomes 4 days of work by using the developed CAD/CAM system so that the efficiency shows 150% of the reduction working time. The prpgram of the design of the automation a progressive die mold was developed in the PC-Class Autocad system, therefore development expense could be reduced, and the integration of the CAD/CAM of the progressive die mold with the standard DB being built could be realized.

• Journal of Electrochemical Science and Technology
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• 제15권2호
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• pp.291-298
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• 2024

Due to its high theoretical capacity, Silicon (Si) has shown great potential as an anode material for lithium-ion batteries (LIBs). However, the large volume change of Si during cycling leads to poor cycling stability and low Coulombic efficiency. In this study, we synthesized Si/Carbon C45:Graphene composites using a ball-milling method with a fixed Si content (20%) and investigated the influence of the C45/Gr ratio on the electrochemical performance of the composites. The results showed that carbon C45 networks can provide good conductivity, but tend to break at Si locations, resulting in poor conductivity. However, the addition of graphene helps to reconnect the broken C45 networks, improving the conductivity of the composite. Moreover, the C45 can also act as a protective coating around Si particles, reducing the volume expansion of Si during charging/discharging cycles. The Si/C45:Gr (70:10 wt%) composite exhibits improved electrochemical performance with high capacity (~1660 mAh g^-1 at 0.1 C) and cycling stability (~1370 mAh g^-1 after 100 cycles). This work highlights the effective role of carbon C45 and graphene in Si/C composites for enhancing the performance of Si-based anode materials for LIBs.