• Journal of Korea Foundry Society
• /
• v.25 no.1
• /
• pp.16-22
• /
• 2005

This study aims to investigate the effects of the microstructures and nodule type on the fatigue characteristics of cast iron. Fatigue tests were carried out in tension-tension mode using a servo-hydraulic testing machine with load control mode operating at a frequency of 15 Hz. The tests were conducted at stress ratio R=Kmin/Kmax, of 0.1. Initial crack ${\Dalta}K$ values were highly performed with increase in tensile strength of DCI fatigue specimens. ${\Dalta}K_{th}$ region, fatigue crack propagation was primarily advanced through cell boundary and in periphery of near nodule. Fatigue crack propagation rate of D2 consisted with 2Phase(Ferrite+Pearlite) was slow due to crack closure enhanced by crack deflection and occurred crack branching. The generation of crack branch was occurred due to interaction of crack-nodule. At Threshold and Paris zone, the fractographs of the fatigue fracture surface for DCI show typical striations of a ductile fracture and isolated cleavage planes near graphite. The effect of microstructure on fatigue crack propagation of GC strongly depends on the type of flake. The generation of crack branch occurred due to interaction of crack-nodule. The fractographs of the fatigue fracture surface for GC show cleavage plane along the flake graphite.

• Journal of Korea Foundry Society
• /
• v.18 no.4
• /
• pp.340-348
• /
• 1998

C/V graphite iron has superior tensile strength, toughness and ductility than grey iron, and better castability than ductile iron. The retained austenite content of C/V graphite iron by austempering treatment affects on the mechanical properties such as ductility, hardness, wear properties and machinability. C/V graphite iron alloyed with Cu and Mo were carried out on the austenitizing at $900^{\circ}C$ for 1 hour, and the austempering at $240{\sim}400^{\circ}C$ for 1 hr. And then the mechanical and wear properties of austempered C/V graphite iron have been investigated by the retained austenite content. In consequence, the retained austenite content was found to be 18.2% in austempering temperature at $240^{\circ}C$, and was increased 39.2% at $400^{\circ}C$. Tensile strength and hardness of austempered C/V graphite iron were decreased as the retained austenite content increased, but elongation was increased. The rolling wear loss were increased as the retained austenite content increased. The wear surface of as-cast became to be rough. The microstructure of austempered C/V graphite iron was became to be acicular ausferrite in austempering at $240^{\circ}C$, and feathery ausferrite at $400^{\circ}C$.

• Journal of Korea Foundry Society
• /
• v.14 no.5
• /
• pp.455-463
• /
• 1994

Aluminum matrix composites reinforced by fine steel wires were fabricated by squeeze casting process. Preforms made of fine steel wires were prepared with different surface conditions, namely uncoated(TN), carbo-nitriding treated(TT), and brass coated(TA). Squeeze casting were performed under the pressure of $1500kg/cm^2$ for 3min. during solidification, and pouring temp. of the melt being $750^{\circ}C$ and the steel mold being preheated at $250^{\circ}C$. Microstructural characteristics were evaluated, particularly concerned with the effect of the surface conditions of the preforms. The results obtained from this study are like these. TN specimens show partially non-wetted regions, due to easy formation of oxides on the surface of the fine steel wires. TT specimens show no interfacial reaction between the steel wires and the aluminum alloy matrix, possibly due to the formation of carbo-nitrided zone on the surface of the steel wires. TA specimens show excellent wettabillity between the reinforced steel wires and the aluminum alloy matrix and very thin interfacial zone is formed between them. During the solution hardening treatment of TA specimens, thickness of the interfacial reaction zones were increased with the solution treating time. TA specimens show typical ductile fracture in tensile test, but TT specimens show brittle fracture possibly due to the formation of the brittle hard surface on the steel wires during carbo-nitriding treatments. TA specimens which were reinforced with 40 vol.% of the fine steel wires exhibit high tensile strength of $77.1kgf/mm^2$ and impact value of $8.1kgf-m/cm^2$.

• Journal of Korea Foundry Society
• /
• v.38 no.5
• /
• pp.87-94
• /
• 2018

The effects of Sr and (Ti-B) additives on the tensile properties of AC4A recycled (35% scrap content) aluminum alloys were investigated. An acicular morphology of the eutectic Si phase of as-cast specimens was converted to a fibrous morphology upon the addition of Sr. Moreover, morphology of the Sr modified eutectic Si phase became finer due to a T6 heat treatment. The grain size of the ${\alpha}$-solid solution was decreased by the addition of (Ti-B) additives. Depending on the treatment conditions of the as-cast specimens, i.e., no addition, a Sr addition and a (Ti-B)+Sr addition, the tensile strength levels of the as-cast specimens were 182, 192, and 204MPa, respectively. The corresponding strengths of T6 heat-treated specimens were 293, 308, and 318MPa. Elongations of the as-cast specimens were 2.2, 3.1, and 5.6%, and the corresponding elongations of the T6 heat-treated specimens were 4.6, 6.1, and 7.6%. The percentage of the reduced section area in the tensile specimens was also increased by the Sr and (Ti-B) additives. Sr and (Ti-B) additives changed the microstructure and the distribution of defects in the castings, resulting in an improvement of the tensile properties of AC4A aluminum alloys. According to our test results, recycled (35% scrap content) AC4A aluminum alloy met all of the KS requirements of the tensile strength and elongation values of AC4A aluminum alloy except for the elongation value of the one specimen condition, in this case the as-cast no-addition condition.

• Korean Journal of Materials Research
• /
• v.25 no.12
• /
• pp.659-665
• /
• 2015

The self-propagating high temperature synthesis approach was applied to synthesize amorphous boron nano-powders in argon atmospheres. For this purpose, we investigated the characteristics of a thermally induced combustion wave in the $B_2O_3+{\alpha}Mg$ system(${\alpha}=1.0-8.0$) in an argon atmospheres. In this study, the exothermic nature of the $B_2O_3-Mg$ reaction was investigated using thermodynamic calculations. Experimental study was conducted based on the calculation data and the SHS products consisting of crystalline boron and other compounds were obtained starting with a different initial molar ratio of Mg. It was found that the $B_2O_3$ and Mg reaction system produced a high combustion temperature with a rapid combustion reaction. In order to regulate the combustion reaction, NaCl, $Na_2B_4O_7$ and $H_3BO_3$ additives were investigated as diluents. In an experimental study, it was found that all diluents effectively stabilized the reaction regime. The final product of the $B_2O_3+{\alpha}Mg$ system with 0.5 mole $Na_2B_4O_7$ was identified to be amorphous boron nano-powders(< 100 nm).

• Korean Journal of Materials Research
• /
• v.30 no.10
• /
• pp.550-557
• /
• 2020

Used in the ceramic tile market as a representative building material, relief ceramic tile is showing increased demand recently. Since ceramic tiles are manufactured through a sintering process at over 1,000 ℃ after uniaxial compression molding by loading granule powders into a mold, it is very important to secure the flowability of granular powders in a mold having a relief pattern. In this study, kaolin, silica, and feldspar are used as starting materials to prepare granule powders by a spray dryer process; the surface of the granule powders is subject to hydrophobic treatment with various concentrations of stearic acid. The effect on the flowability of the granular powder according to the change of stearic acid concentration is confirmed by measuring the angle of repose, tap density, and compressibility, and the occurrence of cracks in the green body produced in the mold with the relief pattern is observed. Then, the green body is sintered by a fast firing process, and the water absorption, flexural strength, and durability are evaluated. The surface treatment of the granule powders with stearic acid improves the flowability of the granule powders, leading to a dense microstructure of the sintered body. Finally, the hydrophobic treatment of the granule powders makes it possible to manufacture relief ceramic tiles having a flexural strength of 292 N/cm, a water absorption of 0.91 %, and excellent mechanical durability.

• Polymer(Korea)
• /
• v.25 no.1
• /
• pp.56-62
• /
• 2001

When polyethylene terephthalate(PET) film specimen were stepwise elongated under tension with various speeds of about 0.5~500 mm/min, the necking area, consisted of transparent and opaque bands, was formed during plastic deformation. Stress oscillation was apparently obtained in the stress-strain curve of above specimen. However, stress oscillation was not obtained in the stress-strain curve of annealing specimen. Microstructure was examined dynamically using an optical microscopy and thermal analysis was carried out in a differential scanning calorimeter at a heating rate of 10${\circ}$/min. Also, orientation and crystallization were examined using monochromatic-pinhole technique and elastic modulus was measured by a dynamic mechanical analyzer in the temperature range of -150~70 ${\circ}$ with the frequency of 1 Hz. Transparent PET products were fabricated by use of the PET pellets annealed at 83${\circ}$ for 30 min in an electric furnace.

• Korean Journal of Materials Research
• /
• v.12 no.12
• /
• pp.897-903
• /
• 2002

Morphological evolution and growth mechanism at the solid/liquid interface during solidification were investigated in the Ni-base superalloy GTD111M by directional soldification and quenching(DSQ) technique. The experiments were conducted by changing solidification rate(V) and thermal gradient(G) which are major solidification process variables. High thermal gradient condition could be obtained by increasing the furnace temperature and closely attaching the heating and cooling zones in the Bridgeman type furnace. The dendritic/equiaxed transition was found in the G/V value lower than $0.05$\times$10{^3}^{\circ}C$s/$\textrm{mm}^2$, and the planar interface of the MC-${\gamma}$ eutectic was found under $17 $\times$ 10{^3}^{\circ}C$ s/$\textrm{mm}^2$. It was confirmed that the dendrite spacing depended on the cooling rate(GV), and the primary spacing was affected by the thermal gradient more than solidification rate. The dendrite lengths were decreased as increasing the thermal graditne, and the dendrite tip temperature was close to the liquidus temperature at $50 \mu\textrm{m}$/s.

• Korean Journal of Materials Research
• /
• v.8 no.9
• /
• pp.807-812
• /
• 1998

Interfacial reaction and mechanical properties between Sn-Bi-X ternary alloys(X : 2Cu. 2Sb 5In) and Cu-substrate were studied. Cu/solder joints were subjected to aging treatments for up to 60days to see interfacial reaction at $100^{\circ}C$ and then were examined changes of microstructure and interfacial compound by optical microscopy, SEM and EDS. Cu/solder joints were aged to 30days and then loaded to failure at cross head speed of 0.3mm $\textrm{min}^{-1}$ to measure strength and elongation. According to the result of EDS, it is supposed that the soldered interfacial zone was composed of $\textrm{Cu}_{3}\textrm{Sn}$ and $\textrm{Cu}_{6}\textrm{Sn}_{5}$. According to the tensile test of Cu/solder joint, joint strength was decreased by aging treatment. Fractographs of Cu/Sn-Bi solder detailed the effect of aging on fracture behavior. When intermetallic was thin, the fracture occurred through the solder. But as the interfacial intermetallic is thickened, the fracture propagated along the intermetallic/solder interface.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2003.07a
• /
• pp.168-171
• /
• 2003

Bismuth layered structure, Cerium-substituted $Bi_4Ti_3O_{12}$ ($(Bi,Ce)_4Ti_3O_{12}$) thin films were prepared on the $Pt/TiO_2/SiO_2/Si$ substrates by the pulsed laser deposition method. We investigated the Ce-subsitituted effect on the grain orientation and ferroelectric properties. $Ce^{3+}$ ion substitution for $Bi^{3+}$ ion in perovskite layers of BTO decreased the deeree of c-axis orientation and increased the remanent polariation (2Pr). The structure and morphology of the films were characterized using X-ray diffraction and atomic force microscopy. The $(Bi,Ce)_4Ti_3O_{12}$ (BCT) thin films, which were annealed $700^{\circ}C\;and\;800^{\circ}C$ for 10min and 30min, showed a perovskite phase and dense microstructure. As the thickness of the BCT film was decresed that the ferroelectric properties of the BCT thin films were good.