• Journal of Powder Materials
• /
• v.16 no.4
• /
• pp.285-290
• /
• 2009

HDDR treated anisotropic Nd-Fe-B powders have been widely used, due to their excellent magnetic properties, especially for sheet motors and sunroof motors of hybrid and electric vehicles. Final microstructure and coercivity of such Nd-Fe-B powders depend on the state of starting mother alloys, so additional homogenization treatment is required for improving magnetic properties of them. In this study, a homogenization treatment was performed at $900\sim1140^{\circ}C$ in order to control the grain size and Nd-rich phase distribution, and at the same time to improve coercivity of the HDDR treated magnetic powders. FE-SEM was used for observing grain size of the HDDR treated powder and EPMA was employed to observe distribution of Nd-rich phase. Magnetic properties were analyzed with a vibrating sample magnetometer.

• Journal of Powder Materials
• /
• v.19 no.5
• /
• pp.379-384
• /
• 2012

This paper reports the microstructures and thermal conductivities of $ZrB_2$-SiC composite ceramics with size and amount of SiC. We fabricated sintered bodies of $ZrB_2$-x vol.% SiC (x=10, 20, 30) with submicron and nanosized SiC densified by spark plasma sintering. Microstructure retained the initial powder size of especially SiC, except the agglomeration of nanosized SiC. For sintered bodies, thermal conductivities were examined. The observed thermal conductivity values are 40~60 W/mK, which is slightly lower than the reported values. The relation between microstructural parameter and thermal conductivity was also discussed.

• Journal of Powder Materials
• /
• v.15 no.1
• /
• pp.1-5
• /
• 2008

ZnS-$SiO_2$ composite is normally used for sputtering target. In recent years, high sputtering power for higher deposition rate often causes crack formation of the target. Therefore the target material is required that the sintered target material should have high crack resistance, excellent strength and a homogeneous microstructure with high sintered density. In this study, raw ZnS and ZnS-$SiO_2$ powders prepared by a 3-D mixer or high energy ball-milling were successfully densified by spark plasma sintering, the effective densification method of hard-to-sinter materials in a short time. After sintering, the fracture toughness was measured by the indentation fracture (IF) method. Due to the effect of crack deflection by the residual stress occurred by the second phase of fine $SiO_2$, the hardness and fracture toughness reached to 3.031 GPa and $1.014MPa{\cdot}m^{1/2}$, respectively.

• Journal of Powder Materials
• /
• v.21 no.1
• /
• pp.39-43
• /
• 2014

Bulk nanostructured copper was fabricated by a shock compaction method using the planar shock wave generated by a single gas gun system. Nano sized powders, average diameter of 100 nm, were compacted into the capsule and target die, which were designed to eliminate the effect of undesired shock wave, and then impacted with an aluminum alloy target at 400 m/s. Microstructure and mechanical properties of the shock compact specimen were analyzed using an optical microscope (OM), scanning electron microscope (SEM), and micro indentation. Hardness results showed low values (approximately 45~80 Hv) similar or slightly higher than those of conventional coarse grained commercial purity copper. This result indicates the poor quality of bonding between particles. Images from OM and SEM also confirmed that no strong bonding was achieved between them due to the insufficient energy and surface oxygen layer of the powders.

• Analytical Science and Technology
• /
• v.7 no.2
• /
• pp.155-164
• /
• 1994

A conventional Grimm-type glow discharge source was constructed and applied to radio-frequency(13.56MHz) discharge for metal and ceramic analysis. We investigated the emission spectrum for aluminium and aluminium oxide and the influence of discharge operating paramaters including argon pressure, rf-power and DC-bias voltages at the sample-side electrode. Scanning Electron Microscope(SEM) also was used to investigate the effect of rf-sputtering on the microstructure formation of the aluminium oxide. Linear analytical calibration curves were constructed for Manganese and zinc element in samples of low alloy steel(BAS 401-405) and brass(NIST 1108-1117).

• Journal of the Korean Society for Heat Treatment
• /
• v.12 no.4
• /
• pp.287-293
• /
• 1999

Effect of heat-treatment on the microstructure and recrystallization behavior of pure Zr was studied. The specimens were prepared under the various annealing temperatures from $400^{\circ}C$ to $800^{\circ}C$ and times from 300 to 5000 minutes after vacuum arc remelting. The recrystallization behavior was observed by a polarized optical microscope, TEM and micro-vickers hardness tester. With increasing the annealing time, the temperature region of hardness drop moved to the lower temperature region due to the recovery and recrystallization behaviors at the lower temperature. The recrystallization of cold-worked pure Zr was completed between 450 and $600^{\circ}C$. The size of recrystallized grain increased at $700^{\circ}C$ for 600min. Activation energy(Q) of pure Zr measured by the time for constant fraction technique was 78 KJ/mol.

• Journal of the Korean Society for Heat Treatment
• /
• v.26 no.3
• /
• pp.113-119
• /
• 2013

Grain growth behaviors of hot-rolled AZ31 (Mg-3%Al-1%Zn) and AZ31-0.3%CaO alloys at elevated temperatures have been investigated in order to clarify the effect of CaO addition on grain stability of Mg-Al-based wrought alloy. The grain size of CaO-free alloy increased steeply from 673 K with an increase in annealing temperature from 573 to 773 K, whereas the grains of CaO-containing alloy were relatively stable up to 723 K. The activation energies for grain growth ($E_g$) were 12.2 and 18.3 kJ/mole between 573 and 673 K and 119.2 and 126.9 kJ/mole between 673 and 773 K in the AZ31 and AZ31-0.3%CaO alloys, respectively. This result indicates that grains in the CaO-added alloy possess higher thermal stability than CaO-free alloy. SEM observations on the annealed alloy samples revealed that higher grain stability resulting from CaO addition would be associated with the suppression of grain growth by Ca-related precipitate particles distributed in the microstructure.

• Journal of the Korean Society for Heat Treatment
• /
• v.33 no.5
• /
• pp.232-238
• /
• 2020

Heating experiments using the 7075 aluminum alloy in the state of billet and extrudate have been performed to investigate the pertinent ranges of working temperatures and holding times for the application to the various automobile parts. The 7075 specimens from raw billet of 152 mm in diameter and 400 mm in length prior to extrusion were used for heating with a holding time of 10 minutes at temperatures between 380℃ and 550℃. Then, an extrusion process using the billet has been fulfilled at 380℃ with extrusion speed of 0.8 mm/min to get an plate-type extrudate of 75 mm in width and 4.2 mm in thickness. The samples from the extrudate were subjected to heating experiments at temperatures between 380℃ and 440℃ with holding times such as 10 min, 30 min, 60 min and 120 min at each heating temperature. The microstructures were investigated on the optical and EBSD micrographs. The hardness measurement and the tensile test have been performed to investigate the effect of the heat treatment on the mechanical property. The results showed for the 7075 extrusion process that the safe heating of billet can be performed below 450℃ and the extrusion can be done safely up to 400℃.

• Computers and Concrete
• /
• v.14 no.2
• /
• pp.175-191
• /
• 2014

In recent years, the emergence of nanotechnology and nanomaterial has created hopes to improve various properties of concrete. Nano silica as one of these materials has been introduced as a cement replacement material for concrete mixture in construction applications. It can modify the properties of concrete, due to high pozzolanic reactions and also making a denser microstructure. On the other hand, it is well recognized that the use of mineral admixtures such as silica fume affects the mechanical properties and durability of cementitious materials. In addition, the superior performance of self-consolidating concrete (SCC) and self-consolidating mortars (SCM) over conventional concrete is generally related to their ingredients. This study investigates the effect of nano silica and silica fume on the compressive strength and chloride permeability of self-consolidating mortars. Tests include compressive strength, rapid chloride permeability test, water permeability, capillary water absorption, and surface electrical resistance, which carried out on twenty mortar mixtures containing zero to 6 percent of nano silica and silica fume. Results show that SCMs incorporating nano silica had higher compressive strength at various ages. In addition, results show that nano silica has enhanced the durability SCMs and reduced the chloride permeability.

• Journal of Powder Materials
• /
• v.10 no.1
• /
• pp.15-20
• /
• 2003

Hybrid $A1_2O_3-TiC$ ceramic particle reinforced 6061 and 5083 Al composite powders were prepared by the combination of twin rolling and stone mill crushing process, followed by consolidating processes of cold compaction, degassing and hot extrusion. The composite bar consists of lamellar structure of ceramic particle rich area and matrix area, in which the hybrid was decomposed into each TiC of about $3-4\mutextrm{m}$ and $AI_2O_3$ particles of about $1-2\mutextrm{m}$ in diameter. It also found that fine $Mg_2Si$ precipitates of about 30 nm were embedded in the matrix, which have grains of about 3 $\mutextrm{m}$. Higher UTS was measured at the 5083 composite bar compared to the conventionally fabricated composite, due to again refinement effect by the rapid solidification. No particle was shown to form in the interface between the matrix and reinforcement, whereas carbon was diffused into the matrix.