• Title/Summary/Keyword: microscopic structure

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Partial Molal Volumes of Anilinium Chloride in Isopropanol-Water Mixtures (2-프로판올-물 혼합 용액에서의 염화아닐린늄의 분몰랄 부피)

  • Cho, Byung-Rin;Lee, Young-Ja;Lee, Ik-Choon
    • Journal of the Korean Chemical Society
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    • v.13 no.3
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    • pp.195-198
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    • 1969
  • Determination of partial molal volumes of anilinium chloride isopropanol-water mixtures at 30.00$^{\circ}$showed a distinct minimum at 0.20 mole fraction isopropanol. This was interpreted as maximum in electrostriction effect and minimum in water structure. The depth in $\bar{V}^{\circ}$for alcohol-water mixtures was in the order MeOH > i-PrOH > EtOH, which indicated the importance of microscopic structure around ions.

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A Study on the Basic Physical Properties of Concrete Containing Waterproofing Agent (${\cdot}$습도 조건이 구체방수제를 혼입한 모르타르의 기초물성에 미치는 영향)

  • Han Da Hee;Park Hee Gon;Kim Kwang Ki;Kim Sang Kyu;Song Byung Chang;Jung Sang Jin
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.11a
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    • pp.777-780
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    • 2004
  • Recently, the use of structure compound waterproof agent (hereinafter referred to as 'SCWA') that is used when manufacturing concrete for concrete structures, increases in quantity. However, while it is expected that the SCWA that is mixed in the concrete inside can significantly affect the change of physical properties that lift the internal force of a structure. This study has been conducted through an experiment for the effects of cement hardener on the formation of microscopic texture, and newly generated hydrates from that result were not confirmed in the. present experiment. It was found that at the hydrate reaction it has the property that can be hardened within the limit of pore diameterar a specific size rather than there is the internal gap filling capacity due to generating other hydrates.

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New doping technique of Mn Activator on ZnS Host for Photoluminescence Enhancement

  • Wentao, Zhang;Lee, Hong-Ro
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2008.11a
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    • pp.9-10
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    • 2008
  • Triple layers structure of $SiO_2$/ZnS:Mn/ZnS was synthesized by using ion substitution and chemical precipitation method. Each layer thickness was controlled by adjusting the concentration of manganese (II) acetate ($Mn(CH_3COO)_2$) and tetraethyl orthosilicate (TEOS). The structure and morphology of prepared phosphors were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM) and electron probe microscopic analyzer (EPMA). Photoluminescence (PL) properties of ZnS with different layer thickness and amount of Mn activator were analyzed by PL spectrometer. PL emission intensity and PL stability were analyzed for evaluating effects of Mn activator.

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Structural Analysis of Simulated Fission-Produced Noble Metal Alloys and Their Superconductivities

  • Park, Yong Jun;Lee, Gwang Yong;Lee, Jong Gyu;Heo, Yong Deuk;Kim, Won Ho
    • Bulletin of the Korean Chemical Society
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    • v.21 no.12
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    • pp.1187-1192
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    • 2000
  • Ternary (Mo-Ru-Pd) and binary (Mo-Ru, Mo-Pd) alloys have been prepared using an Ar arc melting furnace. Mo and the noble metals, Ru and Pd, are the constituents of metallic insoluble residues, which were found in the early days of post-irradiation studies on uranium oxide fuels. In the present study, the structure of the alloys was evaluated using a powder X-ray diffractometer. Unit cell parameters were determined by least squares refinements of powder X-ray diffraction data. Scanning electron microscopic analyses of the surface of the alloys indicated that surface morphology was dependent on the crystallographic structure as well as its composition. Measurements of the magnetic susceptibility of the alloys showed evidence of superconducting transition from 3 to 9.2 K. Among the ternary and binary alloys, the ${\sigma}-phase$ showed the highest superconducting transition temperature,~9.2 K.

An Electron Microscopic Investigation of the Structure of Thin Film Tin Oxide Material

  • Jeon, Eok-Gui;Choy, Jin-Ho;Choi, Q.-won;Kim, Ha-Suck
    • Bulletin of the Korean Chemical Society
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    • v.6 no.5
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    • pp.304-308
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    • 1985
  • Morphological structure of tin oxide thin films was examined by transmission electron microscopy. TEM samples were prepared by chemical etching in hydrogen fluoride solution: firstly floating for 2-3 minutes in acid solution, then suspending on water found to be useful for the preparation of TEM samples. Electron micrographs showed the size of grains of the tin oxide crystal was dependent upon the temperature of the film preparation. Dopant concentration and heating time also influence the grain size. The resistivity of tin oxide material was explained by grain size and grain boundaries in a limited temperature and dopant concentration ranges.

Turning and Metalic Characterization for CAM Shaft Materials of Diessel Engine (디젤 엔진용 캠축 소재의 금속적 특성 및 선삭 가공 특성에 관한 연구)

  • Chae, W.S.;Kim, K.W.;Kim, D.H.
    • Journal of the Korean Society for Precision Engineering
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    • v.14 no.7
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    • pp.22-28
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    • 1997
  • In this paper, We have studied internal quality incluiding chemical compositions, microscopic structure and nonmetalic inclusion of test material. We have analyzed dynamic characteristics of cutting resistence and compared chip treatment of the test material. In analyzing internal quality, all of the test material have typical ferrite+pearlite structure. But, nonmetallic inclusion has oxide and sulfide inclusion has oxide and sulfide inclusion in medium carbon steel, mainly sulfide inclusion is existed in S-free cutting steel. In Ca+S-free cutting steel, calcium aluminate and sulfide complex inclusion, had low-melting point, as deformation of sulfide and oxide inclusion is existed. Machining characteristics, cutting resistence is maximum in medium carbon steel. Chip treatement are excellent in S-free cutting steel, similar to the Ca+S free cutting steel and medium carbon steel.

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Long arm octopus (Octopus minor) extract prevents eye injury caused by particulate matter exposure in zebrafish (Danio rerio) embryos

  • Thilini Ranasinghe;Seon-Heui Cha
    • Fisheries and Aquatic Sciences
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    • v.27 no.2
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    • pp.111-121
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    • 2024
  • Particulate matter (PM) is a mixture of microscopic solid inhalable particles including airborne liquid droplets, and it is implicated with several diseases. The eye does not have a protective barrier among the human organs, consequently it get directly exposed to environmental substances such as PM. The scarcity of treatments for damage to the eyesight and the vision and eye structure being closely related to the structure and function of the central nervous system highlights the cruciality of novel therapeutics. In this study was conducted using in vivo zebrafish vertebrate model which is a useful model due to the conserved genes between human. We found that protective effect of Octopus minor extract against particulate matter-induced adverse effects on eye development in zebrafish (Danio rerio) embryos by regulating antioxidant and anti-inflammatory mRNA expression.

Changes in Microflora, Enzyme Activities and Microscopic Structure of Waxy Rice and Steeping Water in Response to Different Steeping Conditions During Preparation of Gangjung (강정 제조시 찹쌀의 수침조건에 따른 찹쌀과 수침액의 미생물상, 효소활성 및 미세구조 변화)

  • Kim, Haeng-Ran;Kim, Kyung-Mi;Kim, Kwang-Ok
    • Korean Journal of Food Science and Technology
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    • v.41 no.6
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    • pp.644-651
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    • 2009
  • This study was conducted to investigate the effects of steeping periods and temperatures of waxy rice on the microflora and enzyme activities of steeping water and waxy rice, as well as on the microscopic structures of waxy rice during the preparation of gangjung. When the steeping water was 15 and $35^{\circ}C$, yeast and lactic acid bacteria were the major microflora after 1 day. After 11 days, Lactobacillus spp. were the major bacteria, while Bacillus spp. were the primary microflora after 21 days. At $25^{\circ}C$ the primary species were Bacillus spp., Leuconostoc spp., and Bacillus spp. after 1, 11 and 21 days, respectively. The $\alpha$-amylase activity of steeping water increased proportionally with the increase of temperature and period, while the protease activity tended to increase for 11 days, but decreased at 21 days. The enzyme activities of the steeped waxy rice, especially the $\alpha$-amylase activity, decreased with higher steeping temperature, while the $\beta$-amylase and glucoamylase activity remained constant for up to 21 days. Observation using scanning electron microscopy indicated that intracellular cleavage of steeped waxy rice endosperm resulted in a rough surface morphology due to the exposure of polygonal starch granules. Tiny pinholes on the surface of waxy rice starch granules were also observed after steeping for 11 days.

Chemical Bonding Nature and Mesoporous Structure of Nickel Intercalated Montmorillonite Clay

  • Park, Hye-Mi;Kim, Tae-Woo;Hwang, Seong-Ju;Choy, Jin-Ho
    • Bulletin of the Korean Chemical Society
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    • v.27 no.9
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    • pp.1323-1328
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    • 2006
  • Mesoporous nickel intercalated aluminosilicate nanohybrid has been synthesized through a recombination reaction between the colloidal suspension of exfoliated montmorillonite nanosheets and aqueous nickel acetate solution. According to powder X-ray diffraction and field emission-scanning electron microscopic analyses, the intercalation of nickel species expands significantly the basal spacing of the host montmorillonite clay and the crystallites of the intercalation compound are assembled to form a house-of-card structure. $N_2$ adsorption-desorption isotherm measurements with BJH pore analyses clearly demonstrated that the porosity of the intercalate originates mainly from mesopores (diameter $\sim50\;\AA$) formed by the house-of-card type stacking of clay crystallites. From FT-IR and X-ray absorption spectroscopic analyses, it becomes certain that intercalated nickel ion is stabilized in an isolated $NiO_6$ octahedral unit. The present mesoporous intercalation compound is expected to be applicable as efficient catalysts or absorbents.

FE Analysis and Experiments of Milli-fart forming Using Grain and Grain Boundary Element (입자요소를 이용한 미세 성형 부품의 유한요소 해석 및 실험)

  • Ku, Tae-Wan;Kang, Beom-Soo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.27 no.1
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    • pp.109-118
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    • 2003
  • The recent trend towards miniaturization causes an increased demand for parts with very small dimensions. Milli-structure components are classified as a component group whose size is between macro- and micro-scale. The manufacturing process of these components of thin sheet metal forming has a microscopic properties in addition to a typical phenomenon of bulk deformation because of the forming size. Also, the material properties and the deformation behavior change with miniaturization, which means that, a coarse grained materials show a higher resistance against deformation, when the grain size is in the range of the sheet thickness. In this study, a new numerical approach is proposed to simulate intergranular milli-structure in forming by the finite element method. The grain element and grain boundary element are introduced to simulate the milli-structure in the bending. The grain element is used to analyze the deformation of individual grain while the grain boundary element is for the investigation on the movement of the grain boundary. Also, the result of the finite element analysis is confirmed by a series of milli-sized forming experiments.