• Title/Summary/Keyword: microscopic characteristics

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Characteristics of $Al_2O_3/TiO_2$ multi-layers as moisture permeation barriers deposited on PES substrates using ECR-ALD

  • Gwon, Tae-Seok;Mun, Yeon-Geon;Kim, Ung-Seon;Mun, Dae-Yong;Kim, Gyeong-Taek;Park, Jong-Wan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.457-457
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    • 2010
  • Flexible organic light emitting diodes (F-OLEDs) requires excellent moisture permeation barriers to minimize the degradation of the F-OLEDs device. Specifically, F-OLEDs device need a barrier layer that transmits less than $10^{-6}g/m^2/day$ of water and $10^{-5}g/m^2/day$ of oxygen. To increase the life time of F-OLEDs, therefore, it is indispensable to protect the organic materials from water and oxygen. Severe groups have reported on multi-layerd barriers consisting inorganic thin films deposited by plasma enhenced chemical deposition (PECVD) or sputtering. However, it is difficult to control the formation of granular-type morphology and microscopic pinholes in PECVD and sputtering. On the contrary, atomic layer deoposition (ALD) is free of pinhole, highly uniform, conformal films and show good step coverage. Thus, $Al_2O_3/TiO_2$ multi-layer was deposited onto the polyethersulfon (PES) substrate by electron cyclotron resonance atomic layer deposition (ECR-ALD), and the water vapor transmission rates (WVTR) were measured. WVTR of moisture permeation barriers is dependent upon density of films and initial state of polymer surface. A significant reduction of WVTR was achieved by increasing density of films and by applying low plasma induced interlayer on the PES substrate. In order to minimize damage of polymer surface, a 10 nm thick $TiO_2$ was deposited on PES prior to a $Al_2O_3$ ECR-ALD process. High quality barriers were developed from $Al_2O_3$ barriers on the $TiO_2$ interlayer. WVTR of $Al_2O_3$ by introducing $TiO_2$ interlayer was recorded in the range of $10^{-3}g/m^2.day$ at $38^{\circ}C$ and 100% relative humidity using a MOCON instrument. The WVTR was two orders of magnitude smaller than $Al_2O_3$ barriers directly grown on PES substrate without the $TiO_2$ interlayer. Thus, we can consider that the $Al_2O_3/TiO_2$ multi-layer passivation can be one of the most suitable F-OLEDs passivation films.

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Renal Manifestations and Imaging Studies of Kawasaki Disease (가와사키 질환에서의 신증상과 영상 검사 소견)

  • Oh, Ji Young;Park, Se Jin;Kim, Sun Jung;Jang, Gwang-Cheon;Kim, Uria;Shin, Jae Il;Kim, Kee Hyuck
    • Childhood Kidney Diseases
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    • v.17 no.2
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    • pp.86-91
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    • 2013
  • Purpose: The aim of this study was to verify renal inflammation following Kawasaki disease (KD) using single photon emission computed tomography along with Technetium-99m dimercaptosuccinic acid scintigraphy (DMSA renal SPECT). Methods: From March 2011 to October 2011, 15 patients diagnosed with KD at the National Health Insurance System Ilsan Hospital were enrolled in the study. All patients underwent DMSA renal SPECT to evaluate renal involvement during the acute phase of KD. Urine ${\beta}2$-microglobulin (${\beta}2$-MG), a marker of renal proximal tubular dysfunction, was also measured to assess renal damage. Results: All 15 patients had normal renal function test results. However, microscopic hematuria and pyuria were observed in 13% and 33% of the patients, respectively. Moreover, urine ${\beta}2$-MG was elevated in 46% of the patients. In addition, patients were divided into two groups based on ${\beta}2$-MG level: those with an increased ${\beta}2$-MG level, and those with a normal ${\beta}2$-MG level. No significant differences were found between these two groups in clinical characteristics, laboratory, sonography, and echocardiography findings. All patients' DMSA renal SPECT scans were normal. Conclusion: Our study showed that mild abnormalities in the urinalysis and elevated urine ${\beta}2$-MG were the only findings of renal involvement in KD. However, no aggressive renal manifestations were detected on DMSA renal SPECT.

Study on Characteristics of SCC and AE Signals for Weld HAZ of HT-60 Steel (HT-60강 용접부의 SCC및 AE신호특성에 관한 연구)

  • Na, Eui-Gyun;Yu, Hyo-Sun;Kim, Hoon
    • Journal of the Korean Society for Nondestructive Testing
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    • v.21 no.1
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    • pp.62-68
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    • 2001
  • In order to characterize the microscopic fracture behaviour of the weldment din stress corrosion cracking(SCC) phenomena, SCC and acoustic emission(AE) tests were carried out simultaneously and the correlation between mechanical paramenters obtained from SCC and AE tests was investigated. In the case of base metal, much more AE events were produced at -0.5V than at -0.8V because of the dissolution mechanism before the maximum load. Regardless of the applied voltages to the specimens, however, AE events decreased after the maximum load. In the case of weldment, lots of AE events with larger amplitude $range(40{\sim}100dB)$ were produced because of the singularities of weld HAZ in comparision to the base metal and post-weld heat-treated(PWHT) specimens. Numerous and larger cracks for the weldment were observed on the fractured surfaces by SEM examination. From these results, it was concluded that SCC for the weldment appeared most severely in synthetic seawater. Weld HAZ was softened by PWHT which also contributed to the reduced susceptibility to corrosive environment in comparison to the weldment.

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A Comparative Study on Joy in Russian and Korean (기쁨의 의미연구 - 러시아어와 한국어의 비교를 중심으로 -)

  • Kim, Jung-Il
    • Cross-Cultural Studies
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    • v.41
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    • pp.113-140
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    • 2015
  • This paper explains how the basic and instinctive emotion "joy" is verbally expressed in Russian and Korean. In particular, the main concern of this pater is on the cultural context with which the emotion "joy" is related and the ways in which the emotion "joy" has a wide range of uses. The semantic and pragmatic characteristics of the uses of the expression "joy" can be explained through the cultural and historical backgrounds in both languages. In Russian, joy has two variants, radost' and udovol'stvie. It is very difficult to distinguish a significant difference between them; however, the former is mainly connected with more mental, spiritual, cultural, and religious contexts, whereas the latter is mainly related with more concrete, instantaneous contexts and daily life. The former produces an impression that has a more wide, spiritual, and macroscopic attitude toward a situation, whereas the latter produces an impression that has a microscopic and instantaneous attitude toward a situation. Compared with the Russian expressions, the Korean equivalents, 기쁨 and 즐거움, have a very similar opposition like that of the Russian. The former is based on a more logical and causal relation between an anticipation or desire and the current situations, whereas the latter is based on the participation of speakers in a situation and has a very instantaneous characteristic, like a udovol'stvie in Russian. Thus, it can be reasonable argued that the Russian udovol'stvie and the Korean 즐거움 share many similar semantic properties. In brief summary, in both languages there exists two distinctive variants that show a privative opposition to express the emotional concept of joy.

Study of the method of production of excavated arrow bundle and its conservation treatment (발굴 출토 화살다발 제작기법 연구 및 보존처리)

  • Lee, Byeonghoon;Choi, Bobae;Huh, Ilgwon
    • Conservation Science in Museum
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    • v.25
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    • pp.9-26
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    • 2021
  • This paper describes the production methods that were originally used for an arrow bundle excavated from a Bronze Age residential area in Auraji in Jeongseon, Gangwon-do Province and the conservation treatment process that it subsequently underwent. An arrow conventionally consists of an arrowhead and a shaft. It is rare to excavate a shaft along with an arrowhead in a complete form since the shaft is made of organic materials. Notably, the arrow bundle from the Auraji site is of great significance as it shows traces of tangless stone arrowheads attached to charred shafts and offers an important case of the split end of a piece of a tree being inserted into an arrowhead. For a further examination of the characteristics of the arrows from Auraji, microscopic investigation was conducted and the type of wood used for the arrow shafts was examined. The sequence and direction of processing and the particle sizes of the grinding tools were revealed through the analysis of traces of grinding on the stone arrowheads. The shaft is presumed to have been made from a green length of three-year-old willow (Salix spp.). A curing agent with a high degree of waterproofing and reversibility was used during the on-site curing process according to demands of the surrounding environment, and a technique that the authors call the "Bridge" method was used for emergency collection of the relics. Once the bundle was transferred to the conservation treatment lab, reinforcing materials were carefully chosen as it was important not to damage the relics during the process of turning them for the repair of their reverse sides. For this purpose, artificial clay was selected since it can safely bear a load and has excellent physical properties. Finally, detached parts were rejoined, the relics and their surrounding materials were cleaned, and the bottom sides were finished with epoxy resin prior to the display of the relics at the museum.

Analysis on the Characteristics of Academic Achievement About 'properties of matter' and 'change of matter': Focusing on the Results of the National Assessment of Educational Achievement (NAEA) in the 2009 Revised Curriculum (물질의 성질 및 물질의 변화 영역에서 중학생들의 학업성취 특성 분석 : 2009 개정 교육과정 시기 국가수준 학업성취도 평가 결과를 중심으로)

  • Jongho, Baek;Wonho, Choi
    • Journal of the Korean Chemical Society
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    • v.66 no.6
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    • pp.493-508
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    • 2022
  • Chemistry is the subject which includes properties, change, and composition of matter. Chemistry has the system which explains observable properties and change with microscopic level, it explains them using scientific theory and laws. In the national-level curriculum, the properties and changes of matter are continuously dealt with from elementary school to high school, and the curriculum are organized so that students could strengthen their understanding about matter. In other words, understanding of the properties and changes of matter is the base to explain everyday life with the view of chemistry, and these two are classified as domains of chemistry in the 2015 revised science curriculum. In this study, we confirmed students' understanding about properties of matter and change of matter, through the analysis about results of the National Assessment of Educational Achievement (NAEA). For that purpose, this study analyzed the 12 items about properties of matter, and 19 items about change of matter, which were used in the NAEA from 2015 to 2019. According to the results of classifying and analyzing questions according to the core concept, the understanding about the two domains significantly changed between the proficient achievement-level students and basic achievement-level students. Depending on the achievement-level, there was a difference in explaining the phenomenon by using the perspective of particles, and by associating scientific concepts and models, or there was a difference in understanding the inquiry related to these two domains. Based on this analysis, this study discussed some implications to be improved on teaching-learning for 'properties of matter', and 'change of matter'.

Metallurgical Study of Iron Artifacts from Guryong-ri Site in Ungcheon, Boryeong

  • Choi, Eun Young;Cho, Nam Chul
    • Journal of Conservation Science
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    • v.38 no.4
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    • pp.289-300
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    • 2022
  • In the 6th and 7th centuries, 5 iron artifacts excavated form the Baekje Stone Tomb in Guryong-ri site, Ungcheon, Boryeong, were studied. The sample were metal microscopic observation, SEM-EDS analysis and Raman micro-spectroscopy analysis were conducted to understand the metallurgical characteristics. The microstructure observation showed the presence of ferrite and pearlite throughout, and differences in carbon content existed depending on the direction. Non-metallic inclusions were in the form of long lines, and most of them were wüstite, fayalite. It is indicated that the artifacts were forge welded using hypoeutectoid steel, with signs of carburizing and decarburizing processes. Some crystals with high P2O5, TiO2, CaO content were identified as sarcopside, ulvöspinel, and perovskite, respectively, through Raman spectroscopy. A comparison of the results with previous studies on the sites of Bujang-ri site in Seosan and Bongseon-ri site in Seocheon, which are adjacent sites in the coastal area, revealed that, while heat treatment technology was available, the artifacts were not heat-treated considering the purpose for use for these artifacts. The chemical composition of the non-metallic inclusions P2O5, TiO2, CaO were plotted in proportions to SiO2 and compared with adjacent sites. Considering that the P2O5/SiO2 ratio was widely distributed, the refining technology was not uniform. In addition, the TiO2/SiO2 ratio was found to be higher than that of other sites, meaning that a titanium-containing ore was used to manufacture the artifacts, unlike in surrounding sites, but it is not detected in all artifacts, so it may have been affected by various factors such as furnace walls in addition to raw materials. Although slag formers were used, considering the CaO/SiO2 ratio and the (Al2O3/SiO2)/(CaO/SiO2) ratio, which appear to be similar to the surrounding sites, but it is possible that CaO containing raw ore was used because it is also affected by the components of raw ore. As a result of the study, it is highly likely that ore different from that of the surrounding sites was used for production, but a more comprehensive comparative study with the surrounding sites is needed in the future.

Low Velocity Impact Property of CF/Epoxy Laminate according to Interleaved Structure of Amorphous Halloysite Nanotubes (비정질 할로이사이트 나노입자의 교차적층 구조에 따른 탄소섬유/에폭시 라미네이트의 저속 충격 특성)

  • Ye-Rim Park;Sanjay Kumar;Yun-Hae Kim
    • Composites Research
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    • v.36 no.4
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    • pp.270-274
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    • 2023
  • The stacking configuration of fiber-reinforced polymer (FRP) composites, achieved via the filament winding process, exhibits distinct variations compared to conventional FRP composite stacking arrangements. Consequently, it becomes challenging to ascertain the influence of mechanical properties based on the typical stacking structures. Thus, it becomes imperative to enhance the mechanical behavior and optimize the interleaved structures to improve overall performance. Therefore, this study aims to investigate the impact of incorporating amorphous halloysite nanotubes (A-HNTs) within different layers of five unique layer arrangements on the low-velocity impact properties of interleaved carbon fiber-reinforced polymer (CFRP) structures. The low-velocity impact characteristics of the laminate were validated using a drop weight impact test, wherein the resulting impact damage modes and extent of damage were compared and evaluated under microscopic analysis. Each interleaved structure laminate according to whether nanoparticles are added was compared at impact energies of 10 J and 15 J. In the case of 10 J, the absorption energy showed a similar tendency in each structure. However, at 15 J, the absorption energy varies from structure to structure. Among them, a structure in which nanoparticles are not added exhibits the highest absorption energy. Additionally, various impact fracture modes were observed in each structure through optical microscopy.

Vehicle Acceleration and Vehicle Spacing Calculation Method Used YOLO (YOLO기법을 사용한 차량가속도 및 차두거리 산출방법)

  • Jeong-won Gil;Jae-seong Hwang;Jae-Kyung Kwon;Choul-ki Lee
    • The Journal of The Korea Institute of Intelligent Transport Systems
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    • v.23 no.1
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    • pp.82-96
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    • 2024
  • While analyzing traffic flow, speed, traffic volume, and density are important macroscopic indicators, and acceleration and spacing are the important microscopic indicators. The speed and traffic volume can be collected with the currently installed traffic information collection devices. However, acceleration and spacing data are necessary for safety and autonomous driving but cannot be collected using the current traffic information collection devices. 'You Look Only Once'(YOLO), an object recognition technique, has excellent accuracy and real-time performance and is used in various fields, including the transportation field. In this study, to measure acceleration and spacing using YOLO, we developed a model that measures acceleration and spacing through changes in vehicle speed at each interval and the differences in the travel time between vehicles by setting the measurement intervals closely. It was confirmed that the range of acceleration and spacing is different depending on the traffic characteristics of each point, and a comparative analysis was performed according to the reference distance and screen angle to secure the measurement rate. The measurement interval was 20m, and the closer the angle was to a right angle, the higher the measurement rate. These results will contribute to the analysis of safety by intersection and the domestic vehicle behavior model.

Characteristics of finishing materials used in tomb No.1 of the Songje-ri, in Naju (나주 송제리 고분군 1호분에 사용된 마감재의 재료적 특성)

  • KIM Eunkyung;KANG Soyeong
    • Korean Journal of Heritage: History & Science
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    • v.57 no.3
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    • pp.56-67
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    • 2024
  • This study aims to characterize the material of the finishing materials used in the No.1 stone chamber tomb of the Baekje-era tumuli in Songjeri, Naju with mineralogical, chemical, and physical analyses. The finishing material is a mixture of white lumps and fragments, presumed to be shells, that remain on the surface and between the gaps of the stone walls inside the tomb. The analysis results revealed that the main constituent mineral of the finishing material is calcite. Infrared spectroscopy showed peaks due to calcium carbonate, and thermal reaction decarbonation in the 700~800℃ range, high calcium content, and loss on ignition were confirmed. Therefore, the main material of the finishing materials was determined to be lime, and since no aggregates such as sand or gravel were found, it was identified as lime paste. The shell fragments mixed into the lime paste appear dark blue or grayish-white in color, with no original shape remaining. The surface has a layered structure, and microscopic observations revealed prismatic layers with a columnar structure and nacreous layers with a consistent orientation, suggesting that the shells are from bivalve mollusks. Additionally, X-ray imaging of the shell fragments showed holes and tunnels caused by boring marine organisms both on the surface and inside, and radiocarbon dating results confirmed that the dating of the shells was consistent with the construction period of the tomb. It is concluded that the finishing material used in Tomb No. 1 in Songje-ri, Naju, was lime paste mixed with shell fragments, and the lime was made using the shells of bivalve mollusks as the raw material.