• Title/Summary/Keyword: micro-structures

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Nanoscale Characterization of a Heterostructure Interface Properties for High-Energy All-Solid-State Electrolytes (고에너지 전고체 전해질을 위한 나노스케일 이종구조 계면 특성)

  • Sung Won Hwang
    • Journal of the Semiconductor & Display Technology
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    • v.22 no.1
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    • pp.28-32
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    • 2023
  • Recently, the use of stable lithium nanostructures as substrates and electrodes for secondary batteries can be a fundamental alternative to the development of next-generation system semiconductor devices. However, lithium structures pose safety concerns by severely limiting battery life due to the growth of Li dendrites during rapid charge/discharge cycles. Also, enabling long cyclability of high-voltage oxide cathodes is a persistent challenge for all-solid-state batteries, largely because of their poor interfacial stabilities against oxide solid electrolytes. For the development of next-generation system semiconductor devices, solid electrolyte nanostructures, which are used in high-density micro-energy storage devices and avoid the instability of liquid electrolytes, can be promising alternatives for next-generation batteries. Nevertheless, poor lithium ion conductivity and structural defects at room temperature have been pointed out as limitations. In this study, a low-dimensional Graphene Oxide (GO) structure was applied to demonstrate stable operation characteristics based on Li+ ion conductivity and excellent electrochemical performance. The low-dimensional structure of GO-based solid electrolytes can provide an important strategy for stable scalable solid-state power system semiconductor applications at room temperature. The device using uncoated bare NCA delivers a low capacity of 89 mA h g-1, while the cell using GO-coated NCA delivers a high capacity of 158 mA h g−1 and a low polarization. A full Li GO-based device was fabricated to demonstrate the practicality of the modified Li structure using the Li-GO heterointerface. This study promises that the lowdimensional structure of Li-GO can be an effective approach for the stabilization of solid-state power system semiconductor architectures.

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Procesos de Configuración Regional y Localidades de Uruguay 1900-1960

  • Fernandez, Tabare;Wilkins, Andres
    • Iberoamérica
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    • v.21 no.1
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    • pp.159-206
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    • 2019
  • The objective of the article is to describe the social structure of Uruguay at the beginning of the sixties, presenting the social differences that configured the level of urban centers or localities since the beginning of the 20th century. The willing is to identify what historical processes would have intervened to have institutionalized a highly heterogeneous distribution of welfare in the territory. The sources of information are four: (i) the population censuses of 1908 and 1963; (ii) the agricultural censuses of 1908, 1951, 1956 and 1961; (iii) the work of historical demography; and (iv) the indices published by the General Directorate of Statistics and Censuses in 1971 and 1989. Due to the lack of a dictionary of the localities, the authors matched these sources. The regional configuration processes analyzed here are: the departmentalization of the territory; the agriculturization; the industrialization and the balnearización. In each case, the regional and local impact of the political, economic and social transformation is analyzed. The article dedicate a wide space to describe the changes in the entity, the legal status, the territorial distribution and the wellbeing of the localities, marking especially those under 1500 inhabitants, which make up an important micro-urbanization of the country. The foundation of 70% of the localities occurred during the reformist period that locates that project as a type of "social democratic" State with its "Bismarkian" type traits. The institutionalization of these territories is based on their precarious and very poor character, the inequality in the most elementary welfare enjoyed by the established towns and cities increases. The processes of spatialization that reconfigured the territory during this time, contributed to the urbanization and population relocation, but in a framework in the political project of the "small model country" did not plan on the territory, the state have no special attention to correct the asymmetries in local welfare distribution structures. We finished with the hypothesis that beyond the social advances of the "Battlista" period, the territorial inequality of opportunities has grown between 1908 and 1963 because the lack of a public planification.

Analysis Method Considering the Ground Reinforcement Effect of Micropile by Field Loading Tests (재하시험을 통한 소구경말뚝의 지반보강효과를 고려한 해석법)

  • Hong, Seok-Woo
    • Journal of the Korean Geotechnical Society
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    • v.25 no.1
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    • pp.89-99
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    • 2009
  • Compared to standard piling methods, micropile construction can be used in downtown areas since it generates less vibration and noise. Since it only causes less soil disturbance, it is commonly used as reinforcement to existing structures. In this study, a field wherein the bearing capacity and settlement of soil can not support the weight of the superstructure was selected and micropiles were implemented instead of ordinary piles. The deformation modulus of the micropile reinforced ground was determined and was directly reflected in the design. Loading testing was used to check whether or not the allowable bearing capacity satisfies the condition of the designed bearing capacity. The computed deformation modulus based from the test was used in the numerical analysis of soil to investigate the stability of the foundation and analysis method. And a method for controlling the bearing capacity and settlement was recommended.

Direct Numerical Simulation of Composite laminates Under low velocity Impact (저속충격을 받는 적층복합재료 평판의 직접 수치모사)

  • Ji, Kuk-Hyun;Kim, Seung-Jo
    • Composites Research
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    • v.19 no.1
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    • pp.1-8
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    • 2006
  • Prediction of damage caused by low-velocity impact in laminated composite plate is an important problem faced by designers using composites. Not only the inplane stresses but also the interlaminar normal and shear stresses playa role in estimating the damage caused. But it is well known that the conventional approach based on the homogenization has the limit in description of damage. The work reported here is an effort in getting better predictions of dynamic behavior and damage in composite plate using DNS approach. In the DNS model, we discretize the composite plates through separate modeling of fiber and matrix for the local microscopic analysis. In the view of microscopic mechanics with DNS model, interlaminar stress behaviors in the inside of composite materials are investigated and compared with the results of the homogenized model which has been used in the conventional approach to impact analysis. Also the multiscale model based on DNS concept is developed in order to enhance the effectiveness of impact analysis, and we present the results of multiscale analysis considering micro and macro structures simultaneously.

Analysis of Bonding Characteristics of Ag-System Brazing Filler Metal (은계 필러메탈 브레이징 접합부의 특성 분석)

  • Soon-Gil Lee;Hwa-In Lee;Jin-Oh Son;Gwang-Il Ha;Bon-Heun Koo
    • Korean Journal of Materials Research
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    • v.33 no.5
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    • pp.214-221
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    • 2023
  • As a filler metal for lowering the melting point of Ag, many alloy metal candidates have emerged, such as cadmium, with zinc, manganese, nickel, and titanium as active metals. However, since cadmium is known to be harmful to the human body, Cd-free filler metals are now mainly used. Still, no study has been conducted comparing the characteristics of joints prepared with and without cadmium. In addition, studies have yet to be conducted comparing the typical characteristics of brazing filler metals with special structures, and the joint characteristics of brazing filler metals with available frames. In this study, the characteristics of junctions of silver-based intercalation metals were compared based on the type of filler metal additives, using a special structure, a filler metal sandwich structure, to protect the internal base metal. The general filler metal was compared using the structure, and the thickness of the filler metal according to the thickness was reached. A comparison of the characteristics of the junction was conducted to identify the characteristics of an intersection of silver-based brazing filler metal and the effect on joint strength. Each filler metal's collective tensile strength was measured, and the relationship between joint characteristics and tensile joint strength was explored. The junction was estimated through micro strength measurement, contact angle measurement with the base metal when the filler metal was melted, XRD image observation, composition analysis for each phase through SEM-EDS, and microstructure phase acquisition.

Characterization of deterioration of concrete lining in tunnel structures (터널 콘크리트 라이닝 구조물의 성능저하 특성)

  • Kim, Dong-Gyou;Jung, Ho-Seop;Bae, Gyu-Jin;Shin, Hyu-Soung
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.11 no.4
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    • pp.387-394
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    • 2009
  • The objective of this study is to evaluate the durability and deterioration of concrete lining in the seven conventional tunnels. These tunnels were constructed about 40~70 years ago, and closed about 10~40 years ago. The field investigation and various laboratory testings were performed for this study. It was observed from the visual, examinations that the concrete linings of 7 tunnels were severely deteriorated, such as, cracks, leakages, desquamation, and exploitations. The compressive strengths obtained from rebound hardness method and uniaxial compressive strength test on core specimens largely differed depending on the locations in the tunnel. The maximum compressive strength of concrete lining was greater about 2 times than the minimum compressive strength of concrete lining in the same tunnel. The results of micro-structural analysis showed that the substances deteriorating the concrete lining, such as ettringite and thaumasite, were detected in the concrete lining of tunnel.

A Data-driven Multiscale Analysis for Hyperelastic Composite Materials Based on the Mean-field Homogenization Method (초탄성 복합재의 평균장 균질화 데이터 기반 멀티스케일 해석)

  • Suhan Kim;Wonjoo Lee;Hyunseong Shin
    • Composites Research
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    • v.36 no.5
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    • pp.329-334
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    • 2023
  • The classical multiscale finite element (FE2 ) method involves iterative calculations of micro-boundary value problems for representative volume elements at every integration point in macro scale, making it a computationally time and data storage space. To overcome this, we developed the data-driven multiscale analysis method based on the mean-field homogenization (MFH). Data-driven computational mechanics (DDCM) analysis is a model-free approach that directly utilizes strain-stress datasets. For performing multiscale analysis, we efficiently construct a strain-stress database for the microstructure of composite materials using mean-field homogenization and conduct data-driven computational mechanics simulations based on this database. In this paper, we apply the developed multiscale analysis framework to an example, confirming the results of data-driven computational mechanics simulations considering the microstructure of a hyperelastic composite material. Therefore, the application of data-driven computational mechanics approach in multiscale analysis can be applied to various materials and structures, opening up new possibilities for multiscale analysis research and applications.

Effect of perforation patterns on the fundamental natural frequency of microsatellite structure

  • Ahmad M. Baiomy;M. Kassab;B.M. El-Sehily;R.M. El-Kady
    • Advances in aircraft and spacecraft science
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    • v.10 no.3
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    • pp.223-243
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    • 2023
  • There is a burgeoning demand for minimizing the mass of satellites because of its direct impact on reducing launch-to-orbit cost. This must be done without compromising the structure's efficiency. The present paper introduces a relatively low-cost and easily implementable approach for optimizing structural mass to a maximum natural frequency. The natural frequencies of the satellite are of utmost pertinence to the application requirements, as the sensitive electronic instrumentation and onboard computers should not be affected by the vibrations of the satellite structure. This methodology is applied to a realistic model of Al-Azhar University micro-satellite in partnership with the Egyptian Space Agency. The procedure used in structural design can be summarized in two steps. The first step is to select the most favorable primary structural configuration among several different candidate variants. The nominated variant is selected as the one scoring maximum relative dynamic stiffness. The second step is to use perforation patterns reduce the overall mass of structural elements in the selected variant without changing the weight. The results of the presented procedure demonstrate that the mass reduction percentage was found to be 39% when compared to the unperforated configuration that had the same plate thickness. The findings of this study challenge the commonly accepted notion that isogrid perforations are the most effective means of achieving the goal of reducing mass while maintaining stiffness. Rather, the study highlights the potential benefits of exploring a wider range of perforation unit cells during the design process. The study revealed that rectangular perforation patterns had the lowest efficiency in terms of modal stiffness, while triangular patterns resulted in the highest efficiency. These results suggest that there may be significant gains to be made by considering a broader range of perforation shapes and configurations in the design of lightweight structures.

SURFACE CHARACTERISTICS AND BIOACTIVITY OF ANODICALLY OXIDIZED TITANIUM SURFACES (양극산화에 의한 티타늄 산화막의 표면 특성 및 생체 활성에 관한 연구)

  • Lee, Sang-Han;Cho, In-Ho
    • The Journal of Korean Academy of Prosthodontics
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    • v.45 no.1
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    • pp.85-97
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    • 2007
  • Statement of problem: Recently, anodic oxidation of cp-titanium is a popular method for treatment of titanium implant surfaces. It is a relatively easy process, and the thickness, structure, composition, and the microstructure of the oxide layer can be variably modified. Moreover the biological properties of the oxide layer can be controlled. Purpose: In this study, the roughness, microstructure, crystal structure of the variously treated groups (current, voltage, frequency, electrolyte, thermal treatment) were evaluated. And the specimens were soaked in simulated body fluid (SBF) to evaluate the effects of the surface characteristics and the oxide layers on the bioactivity of the specimens which were directly related to bone formation and integration. Materials and methods: Surface treatments consisted of either anodization or anodization followed thermal treatment. Specimens were divided into seven groups, depending on their anodizing treatment conditions: constant current mode (350V for group 2), constant voltage mode (155V for group 3), 60 Hz pulse series (230V for group 4, 300V for group 5), and 1000 Hz pulse series (400V for group 6, 460V for group 7). Non-treated native surfaces were used as controls (group 1). In addition, for the purpose of evaluating the effects of thermal treatment, each group was heat treated by elevating the temperature by $5^{\circ}C$ per minute until $600^{\circ}C$ for 1 hour, and then bench cured. Using scanning electron microscope (SEM), porous oxide layers were observed on treated surfaces. The crystal structures and phases of titania were identified by thin-film x-ray diffractmeter (TF-XRD). Atomic force microscope (AFM) was used for roughness measurement (Sa, Sq). To evaluate bioactivity of modified titanium surfaces, each group was soaked in SBF for 168 hours (1 week), and then changed surface characteristics were analyzed by SEM and TF-XRD. Results: On basis of our findings, we concluded the following results. 1. Most groups showed morphologically porous structures. Except group 2, all groups showed fine to coarse convex structures, and the groups with superior quantity of oxide products showed superior morphology. 2. As a result of combined anodization and thermal treatment, there were no effects on composition of crystalline structure. But, heat treatment influenced the quantity of formation of the oxide products (rutile / anatase). 3. Roughness decreased in the order of groups 7,5,2,3,6,4,1 and there was statistical difference between group 7 and the others (p<0.05), but group 7 did not show any bioactivity within a week. 4. In groups that implanted ions (Ca/P) on the oxide layer through current and voltage control, showed superior morphology, and oxide products, but did not express any bioactivity within a week. 5. In group 3, the oxide layer was uniformly organized with rutile, with almost no titanium peak. And there were abnormally more [101] orientations of rutile crystalline structure, and bonelike apatite formation could be seen around these crystalline structures. Conclusion: As a result of control of various factors in anodization (current, voltage, frequency, electrolytes, thermal treatment), the surface morphology, micro-porosity, the 2nd phase formation, crystalline structure, thickness of the oxide layer could be modified. And even more, the bioactivity of the specimens in vitro could be induced. Thus anodic oxidation can be considered as an excellent surface treatment method that will able to not only control the physical properties but enhance the biological characteristics of the oxide layer. Furthermore, it is recommended in near future animal research to prove these results.

Analyze of I-V Characteristics and Amorphous Sturcture by XRD Patterns (XRD 패턴에 의한 비정질구조와 I-V 특성분석)

  • Oh, Teresa
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.7
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    • pp.16-19
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    • 2019
  • A thinner film has superior electrical properties and a better amorphous structure. Amorphous structures can be effective in improving conductivity through a depletion effect. Research is needed on the Schottky contact, where potential barriers are formed, as a way to identify these characteristics. $SiO_2/SnO_2$ thin films were prepared to examine the amorphous structure and Schottky contact, $SiO_2$ thin films were prepared using Ar = 20 sccm. $SnO_2$ thin films were deposited using mixed gas with a flow rate of argon and oxygen at 20 sccm, and $SnO_2$ thin films were added by magnetron sputtering and treated at $100^{\circ}C$ and $150^{\circ}C$. To identify the conditions under which the amorphous structure was constructed, the XRD patterns were investigated and C-V and I-V measurements were taken to make Al electrodes and perform electrical analysis. The depletion layer was formed by the recombination of electrons and holes through the heat treatment process. $SiO_2/SnO_2$ thin films confirmed that the pores were well formed when heat treated at $100^{\circ}C$ and an electric current was applied over the micro area. An amorphous $SiO_2/SnO_2$ thin film with heat treatment at $100^{\circ}C$ showed no reflection at $33^{\circ}\;2{\theta}$ in the XRD pattern, and a reflection at $44^{\circ}2\;{\theta}$. The macroscopic view (-30 V