• The Korean Journal of Pesticide Science
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• v.3 no.1
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• pp.66-77
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• 1999

In order to elucidate the fate of the residues of the bipyridylium herbicide paraquat in soil, maize plants were grown for 4 weeks on the specially-made pots filled with two different types of soils containing fresh and 6-week-aged residues of [$^{14}C$]paraquat, respectively. The mineralization of [$^{14}C$]paraquat to $^{14}CO_{2}$ during the aging period and the cultivation period of maize plants amounted to $0.13{\sim}0.18%$ and $0.02{\sim}0.17%$, respectively, of the original $^{14}C$ activities. At harvest the roots and shoots contained less than 0.1% and 0.01% of the originally applied $^{14}C$ activities, respectively, whereas the $^{14}C$ activities remaining in soil were more than 97% in both soils. The water extractability of the soil where maize plants were grown for 4 weeks was less than 1.2% of the original $^{14}C$ activities. Most of the non-extractable soil-bound residues of [$^{14}C$]paraquat were incorporated into the humin fraction. Soil pHs during the aging of soil B and after cultivation in all treatments increased. The distribution of the $^{14}C$ activities in subcellular particles of the maize plant roots was the highest in the residue fraction(incompletely homogenized tissue). Dehydrogenase activities increased after vegetation, regardless of soil aging.

• Journal of the Korea institute for structural maintenance and inspection
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• v.21 no.6
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• pp.178-184
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• 2017

This study was aimed to investigate the tensile behaviors of PE(Polyethylene) fiber-reinforced highly ductile cementitious composites with different combinations of micro silica sand and normal sand(river sand) with maximum particle size of 4.75 mm. Flow test result indicated the increase of flowability with higher replacement ratio of river sand. There was no noticeable difference in the mean compressive strength with different replacement ratio of river sand, but the variation in the compressive strength increased as higher amount of river sand was adopted for the replacement. The difference in the uniaxial tensile strength was negligible, but the tensile strain capacity was significantly influenced by the replacement ratio of river sand. It is thought that increased density of multiple cracks induced improved tensile strain capacity when higher percentage of river sand was adopted for fine aggregate. The deviation in the strain capacity increased as the replacement ratio of river sand was higher, as in the compressive strength. This study presented the feasibility of using normal sand instead of micro silica sand for highly ductile cementitious composites with equivalent or better uniaxial tensile performance, even though it might increase the deviation in the performance.

• Journal of Adhesion and Interface
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• v.20 no.1
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• pp.23-28
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• 2019

In this study, the micro- and nano-particles were used and their shapes were transferred into the polydimethylsiloxane (PDMS) film to fabricate the dry adhesives and their properties were investigated. The Cu nanoparticles of the sizes of 20 nm, 40 nm and 70 nm and the polymethylmethacrylate (PMMA) beads of the size of $5{\mu}m$ were used to transfer their images and the resultant properties of the dry adhesives were compared. The effects of particle size and materials on the mechanical property, tensile adhesion strength, light transmittance, surface morphology, water contact angle were studied. The dry adhesives obtained from the transfer process of Cu nanoparticles with the size of 20 nm resulted in the enhancement of tensile adhesion strength more than 300% compared to that of the bare PDMS. The formation of nanostructure of large surface area on the surface of the PDMS film by the Cu nanoparticles may responsible for the improvement. This study suggests that the use of nanoparticles during the fabrication of PDMS dry adhesives is easy and effective and could be applied to the fabrication of the medical patch.

• Journal of the Microelectronics and Packaging Society
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• v.28 no.2
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• pp.71-79
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• 2021

In this study, we have successfully fabricated the Sn-Ni paste and evaluated the bonding properties for high-temperature endurable EV (Electric Vehicle) power module applications. From evaluating of the micro-structural changes in the TLPS (Transient Liquid Phase Sintering) joints with Sn and Ni contents in the Sn-Ni pastes, a lack of Ni powders and Ni particle agglomerations by Ni surplus were observed in the Sn-20Ni and Sn-50Ni joints (in wt.%), respectively. In contrast, relatively dense microstructures are observed in the Sn-30Ni and Sn-40Ni TLPS joints. From differential scanning calorimetry (DSC) thermal analysis results of the fabricated Sn-Ni paste and TLPS bonded joints, we confirmed that the complete reactions of Sn with Ni to form Ni-Sn intermetallic compounds (IMCs) at bonding temperatures occurred, and there is no remaining Sn in the joints after TLPS bonding. In addition, the interfacial reactions and IMC phase changes of the Sn-30Ni joints under various bonding temperatures were reported, and their mechanical shear strength were investigated. The TLPS bonded joints were mainly composed of residual Ni particles and Ni₃Sn₄ intermetallic phase. The average shear strength tended to increase with increasing bonding temperature. Our results indicated a high shear strength value of approximately 30 MPa at a bonding temperature of 270 ℃ and a bonding time of 30 min.

• Nuclear Engineering and Technology
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• v.52 no.9
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• pp.1939-1944
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• 2020

Pool boiling heat transfer of a copper microporous coating was experimentally studied in borated water with a concentration of boric acid from 0.0 to 5.0 vol percent (vol%) to determine the effect of boric acid on boiling heat transfer in water. A high-temperature, thermally conductive microporous coating (HTCMC) was created by sintering copper powder with an average particle size of 67 ㎛ onto a 1 cm × 1 cm plain copper surface with a coating thickness of ~300 ㎛ within a furnace in a vacuum environment. The tests showed that the nucleate boiling heat transfer coefficient (NBHT) of HTCMC became slightly less enhanced as the concentration of boric acid increased but the NBHT coefficient values were still significantly higher than those of the plain surface. The critical heat flux (CHF) values from 0 to 1.0 vol% were maintained at ~2,000 kW/㎡, and then, they gradually decreased down to ~1,700 kW/㎡ as the concentration increased further to 5.0 vol%. It is believed that the micro-scale pores of the HTCMC were partially blocked by the high boric acid concentration during the nucleate boiling such that the small bubbles were not effectively created using the HTCMC reentrant cavities as the boric acid concentration increased.

• Proceedings of the Korean Society for Agricultural Machinery Conference
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• 2017.04a
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• pp.9-9
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• 2017

입자거동해석소프트웨어(EDEM)은 DEM(Discrete Element Method)기법을 이용한 입자 거동 전용 해석툴로 입자 유입량, 위치 등을 조절하여 입자거동과 관련된 제품 개발, 프로세스 최적화를 위한 비용 및 시간 절감에 활용도가 뛰어난 소프트웨어이다. EDEM을 활용하기 위해선 적용대상에 대한 물성치를 적용하여야 한다. 따라서 본 연구에서는 EDEM를 이용하여 현재 연구개발 중인 카드클리너 방식의 고추 선별기의 성능을 분석을 수행하기 위해 고추 물성측정 실험을 수행 하였다. EDEM을 이용한 입자거동해석에 필요한 개인 물성치에는 포아송비, 전단탄성계수, 밀도가 있다. 또한 입자-입자, 입자-Geometry 간의 상호관계를 위한 물성치인 반발계수, 정지마찰계수, 구름마찰계수가 필요하다. 공시 시료인 고추는 광주광역시 남구 승촌동 소재의 개인농가 Plastic 온실로 재배된 '천상'품종을 사용하였다. 푸아송 비와, 전단 탄성계수를 측정하기 위한 인장시험기기로는 만능인장시험기(TA-XT2, Stable Micro, 영국)를 이용하였으며, 인장에 의한 고추의 변형량 축정은 초고속카메라(NX4-SI, IDT, 미국)을 이용하였다. 밀도는 비중병법에 기초하여 질량과 부피를 측정하여 밀도를 계산하였다. 반발계수는 고추의 충돌 실험을 통해 변화한 높이를 이용하여 계산하였고, 충동 실험을 통해 변화한 높이는 초고속카메라를 이용하여 측정하였다. 정지마찰계수와 구름마찰계수는 고추의 미끄러짐이 시작하는 각도와 등속도 운동으로 구르는 각도를 초고속카메라를 이용하여 측정 후 계산하였다. 모든 실험은 3번 반복을 통해 평균값을 시험 결과 값으로 이용하였다. 고추의 대한 물성치 실험결과 고추의 푸아송 비는 0.294(std : 0.2), 전단탄성계수 4.624E+06 Pa, 밀도 $600kg/m^3$로 나타났다. 또한 입자-입자 간의 물성치인 반발계수는 0.383, 정지마찰계수는 0.455, 구름마찰 계수는 0.043로 나타났다. 추후 본 연구에서 측정한 고추의 물성치를 적용한 EDEM 입자거동해석 시뮬레이션을 통해 카드클리너 방식의 고추 선별기의 성능에 대한 분석을 하고자 한다.

• Ceramist
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• v.19 no.3
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• pp.26-35
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• 2016

The purpose of this study is to find the optimum conditions for manufacturing titanium dioxide using a hybrid self-assembly forming method, to confirm the shape, properties and synergy effect of UV protection for hybrid titanium dioxide. Hybrid titanium dioxide, manufactured by forming self-assembly of different sizes consisting of two kinds of titanium dioxides, has micro titanium dioxide (250nm~300nm) for support material, Nano titanium dioxide (20~30nm) for surface material, coating support material. Adjustment experiments of $AlCl_3$ concentration and both titanium dioxide ratio were conducted to find the optimized conditions for the surface coating of titanium dioxide striking a negative charge, a sample made of the optimized process was confirmed through an optical analysis, particle size analysis, and potentiometric analysis. The SPF in-vitro value of the cosmetics samples containing hybrid titanium dioxide showed 15~30% higher levels than the cosmetics samples containing both titanium dioxides mixture.

• The Journal of Engineering Geology
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• v.28 no.1
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• pp.61-67
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• 2018

Grouting is reinforcement or cutoff method which uses the hardening agent which is typically represented by portland cement and injected into the ground or the structure. When mixing the cement in powder form with water, the particles tend to cohere each other. Once they cohered, the particle size tends to become larger while injection efficiency becomes lower. This study, in a bid to reduce the cohesion of cement, the screen was set inside the grout mixer so that the cement particles are separated while vibrating them. To validate the effect of vibration screen, comparison test was conducted by using ordinary portland cement, slag cement and micro cement. Viscosity test, bleeding test and grain-size analysis indicated that the characteristics varied significantly after passing through the vibration filter. It is expected that the vibration filter installed inside the grout mixer will reduce the cement cohesion when mixing with water.

• Journal of the Korea Concrete Institute
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• v.26 no.4
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• pp.449-456
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• 2014

Material properties of geopolymer, whose the reaction is very complicated, have been influenced by chemical compositions and particle size distributions of fly ash, concentrations and types of alkali-activators and curing conditions such as temperatures and time. In this research, experiments with several variables such as curing temperatures, preset prior to the high temperature curing and high temperatures have been conducted in order to evaluate to investigate effects on the compressive strengths of geopolymer caused by curing condition. Experiment results were evaluated with compressive strengths and micro-structures such as SEM and MIP of geopolymer pastes. As a result, as higher curing temperature or longer preset time were applied to the pastes, higher compressive strengths were observed. However, compressive strengths of geopolymer pastes declined due to increases in macropores (>50 nm) under high temperatures elapsed after 24 hours. In this sense, it can be considered that strengths and microstructures of geopolymers depends on curing temperature and time.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.283-283
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• 2013

Because of beautiful glossy and color, the value of gold leverage is very high in Europe. To improve the quality of gold alloys, we performed heat treatment on 14 K white gold alloys by variously changing age-hardening conditions. Age-hardening behavior and the related phase transformation changes were studied to elucidate the hardening mechanism of 14 K white gold alloy. For solid solution treatment [ST], casted gold alloy specimens were treated at high temperature ($750^{\circ}C$) for 30 minutes, and the specimens dropped to water to quench them. For Age-hardening treatment [AT], the specimens were treated at various temperatures ($250{\sim}300^{\circ}C$). After the heat treatment, we observed the phenomenon to increase hardness from 126 Hv to 166 Hv by Vicker's hardness tester. Through electron probe micro-analysis (EPMA) mapping analysis, we investigated that irregular particles were changed uniformly. In the SEM and OM images, two phases of matrix and particle-likestructures were observed, and the precipitation of these elements from the matrix progressed during age-hardening. By transmission electron microscope and X-ray diffraction observation, it was revealed that the formation of the Au3Cu superstructure contributed to the age-hardening at $270^{\circ}C$ in the gold alloy. After the heat treatment, this analysis shows that casted gold alloys were to improve hardness and to moderate surface defects at specific temperatures and duration.