• Title/Summary/Keyword: metallic glass

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Magnetic Properties and Crystallization of Co-pt Amorphous Metallic Alloys

  • Yoo, Chung-Sik;Lim, Sung-K.;Yoon, C.S.;Kim, C.K.
    • Journal of Magnetics
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    • v.8 no.3
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    • pp.113-117
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    • 2003
  • $Co_{78-x}Pt_xB_{10}Si_{12}$ alloys were produced using the melt-spin process in order to study the crystallization behavior and ensuing magnetic properties of the $Co_{78-x}Pt_xB_{10}Si_{12}$ (Co-Pt) amorphous alloys as a function of the Pt content. We showed that when $\chi$ $>$ 15 well below its stoichiometric composition, CoPt crystallized in the amorphous alloy, thus greatly altering the crystallized microstructure and magnetic properties during annealing. Below this composition, the main crystallization product was Co with Pt dissolved in its lattice. In spite of the nucleation of CoPt with high magnetic anisotropy, the highest coercivity was obtained when x was 15. It was also concluded that the Pt addition deteriorated the glass stability, triggering the devitrification at a progressively lower temperature.

Recovery of Copper from Sludge of Copper Electro-Plating Plant (동전해도금공장 Sludge로부터 동의 회수)

  • Young-Gil Hwang;Youn-Soo Kim;Jae-Il Kim
    • Resources Recycling
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    • v.5 no.3
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    • pp.31-36
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    • 1996
  • The metallic copper was recovered from sludge of the copper electro-plating plant by pyrometallurgical process. The reducing agent was Pyrolysized from waste tires and the flux was a mixture $Na_2CO_3$, $NaB_4O_7$, and glass. The green sludge contained 87.5% moisture and 12.5% solid with 56.5% Cu and 1.59% Fe. The sludge dried at $100^{\circ}C$ was analyized to be $Cu_4SO_4(OH)_6{\cdot}2H_2O$ and CuO by XRD analysis. The former was 84% and the latter 16%, However, the calcined sludge at $500^{\circ}C$ was 49% $Cu_2O(SO_4)$ and 51% CuO. The sludge could by smelted at $1100^{\circ}C$ for two hours with 6 to 8 moles carbon with respect to copper to produce metallic copper (>90%) with recovery of 9% above.

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A Study on the Micro Forming of Al-based Superplastic Alloy and Zr-BMG for the Cavity Position (Al5083 초소성 합금과 Zr-BMG의 Cavity 위치에 따른 마이크로 성형연구)

  • Son, S.C.;Park, K.Y.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2008.05a
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    • pp.258-262
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    • 2008
  • Micro forming is a suited technology to manufacture very small metallic parts(several $mm{\sim}{\mu}m$). In this study, the micro forming property was studied, using Al5083 superplastic alloy with micro grain, suitable for the micro forming process and Zr-BMG amorphous with pseudo-superplastic phenomena in the supercooled liquid state. Micro forming experiments under stastic load status showed that distortion by slip and spin of the grain system and slip inside the grain was observed in the Al5083 superplastic alloy. In case of Zr-BMG, because there is no grain, the distribution of the forming property was similar to the load distribution between punch and metal.

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MAGNETIC PROPERTIES OF NANOCRYSTALLIZED METALLIC GLASSES AT ELEVATED TEMPERATURES

  • Lachowicz, Henryk K.
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.589-596
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    • 1995
  • In the present paper some of the magnetic properties of the nanocrystalline Fe-based magnets produced by an appropriate annealing of their metallic glass precursors are reviewed. These properties are discussed on the grounds of their characteristics measured at the elevated temperatures. It is shown that the effective magnetostriction these magnets display, results from the competition among two contributions of the opposite sign originating from the individual magnetic phases, crystalline phase and the residual glassy matrix in which the nanocrystallites are embedded. It is also shown that at certain conditions the magnets considered expose superparamagnetic behavior and that their isothermal magnetization characteristics can successfully be used to calculate the distribution of the particle volumes. Application of the recently invented new genetic algorithm method, a powerful tool to calculate these distributions is, finally, presented.

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Sensitive Fiber-Optic Mach-Zehnder Interfermeter for the Detection of Low Frequency Magnetic Field (미소 저주파 자기장 측정을 위한 Mach-Zehnder 형 광섬유 간섭계 쎈서의 특성조사)

  • 안준태
    • Proceedings of the Optical Society of Korea Conference
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    • 1991.06a
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    • pp.109-109
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    • 1991
  • 자기변형 효과가 큰 Metallic glass 2605SC에 20cm의 광섬유를 붙여서 교류 자기장 측정을 위한 Mach-Zehnder형 광섬유 간섭계를 구성하였다. 능동 위상 추적 방법을 사용하여 간섭계의 위상차를 최대 측정감도를 갖는 $\pi$/2로 고정시킴으로써 온도 및 진동등의 영향에 의한 신호소멸 현상을 해결하였다. 0.2~2.0 KHz에서 주파수특성, dc bias의 영향 그리고 교류 자기장과 간섭계 출력 사이의 선형성을 조사하였다.

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Study on nano-level mirror surface finishing on mold core to glass lens molding (유리렌즈 성형 금형의 나노 경면가공)

  • Kwak, Tae-Soo;Kim, Cyung-Nyun;Lee, Yong-Chul
    • Journal of the Korean Society for Precision Engineering
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    • v.23 no.1 s.178
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    • pp.97-104
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    • 2006
  • ELID(Electrolytic In-process Dressing) grinding is an excellent technique for mirror grinding of various advanced metallic or nonmetallic materials. A polishing process is also required for elimination of scratches present on ELID grinded surfaces. MAP(Magnetic Assisted Polishing) has been used as polishing method due to its high polishing efficiency and to its resulting in a superior surface quality. This study is describing an effective fabrication method combining ELID and MAP of nano-precision mirror grinding for glass-lens molding mould. It also presents some techniques for achieving the nanometer roughness of the hard metals, such as WC-Co, which are extensively used in precision tooling material.

Cure Characteristics of Metal Particle Filled DGEBA/MDA/SN/ zeolite Composite System for EMI Shielding

  • Cho, Young-Shin;Lee, Hong-Ki;Shim, Mi-Ja;Kim, Sang-Wook
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.05a
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    • pp.548-551
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    • 1999
  • The cure characteristics of metal particle filled DGEBA/MDA/SN/ zeolite epoxy resin composite system for EMI shielding were investigated by dynamic DSC run method and FT-lR spectroscopy. As the heating rate increased, the peak temperature on dynamic DSC curve increased because of the rapid cure reaction. From the straight line of the Kissinger plot, the curing reaction activation energy and pre-exponential factor could be obtained. As the post-curing time at 15$0^{\circ}C$ increased, the glass increased the glass transition temperature or the thermal stability increased. When the post curing time is too long, the system filled with metallic Al particle can be thermally oxidized by the catalytic reaction of metal filler and the thermal stability of the composite for the EMI shielding application may be decreased.

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