• Title/Summary/Keyword: metallic fuel

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EFFECT OF IMPURITIES ON THE MICROSTRUCTURE OF DUPIC FUEL PELLETS USING THE SIMFUEL TECHNIQUE

  • Park, Geun-Il;Lee, Jae-Won;Lee, Jung-Won;Lee, Young-Woo;Song, Kee-Chan
    • Nuclear Engineering and Technology
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    • v.40 no.3
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    • pp.191-198
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    • 2008
  • The influence of fission products' contents on the DUPIC fuel powder and pellet properties was experimentally evaluated using SIMFUEL as a surrogate for actual spent PWR fuel due to the high radioactivity of spent fuel. Pure $UO_2$ and SIMFUEL pellets with fission products equivalent to a burn-up of 35,000 MWd/tU and 60,000 MWd/tU were used as impurities in this study. The specific surface area of the powder milled after the OREOX treatment increased and resulted in sintered pellets with a theoretical density (TD) higher than 95%, regardless of the impurity contents. However, the grain size of the sintered pellets decreased with the increasing impurity contents. As a result of the dissolved oxides in $UO_2$ from the impurity groups, the specific surface area of the OREOX powder increased with an increase of the impurities. The grain size of the sintered pellets was significantly decreased by the metallic and oxide precipitates.

Corrosion Characteristics Improvement of Aluminium Tube for Diesel Engine Intercooler with LP-EGR(Low Pressure-Exhaust Gas Recirculation) (LP-EGR이 적용된 디젤 엔진 인터쿨러용 알루미늄 튜브의 내식성 향상)

  • Ahn, Joon;Ha, Seok;Kwak, Dong-Ho;Jung, Byung-Jun
    • Transactions of the Korean Society of Automotive Engineers
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    • v.20 no.6
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    • pp.140-145
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    • 2012
  • Recently, various after-treatment systems, such as LP-EGR(Low Pressure-Exhaust Gas Recirculation), SCR(Selective Catalytic Reduction) and LNT(Lean NOx Trap), were developed to obey the stringent emission regulations of diesel engine. There are many researches on LP-EGR system because it has advantages of NOx reduction and low fuel consumption. But, condensation water is generated in internal of intercooler tube and it contains various types of anion that cause the corrosion of aluminium tube. In this study, it is examined that the condensation water effects on corrosion of aluminium tube. And method for improvement of corrosion characteristics is investigated using the dipping and electrochemical test.

Characteristics of $PM_{10}S$ and Air-borne Metallic Elements in Asan and Seoul (아산 및 서울 일부 지역의 대기 중 $PM_{10}S$의 농도 및 금속원소 성분의 특성 연구)

  • 양원호;손부순;김윤신;최경호;손종렬;이종대
    • Journal of Environmental Health Sciences
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    • v.30 no.2
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    • pp.123-132
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    • 2004
  • The purpose of this study was to characterize background mass concentration of PM$_{10}$ and metallic composition from September 2001 to August 2002 in comparison with Asan and Seoul. Annual mean of PM$_{10}$ concentrations in Asan and Seoul were 47.98 and 75.33$\mu\textrm{g}$/㎥, respectively. The concentrations of PM$_{10}$ were highest in spring season in both cities. The concentrations of measured metals except for As and Pb in Asan were higher than those in Seoul. Yellow dust could affect the mass and metals concentrations of measured PM$_{10}$ in Asan and Seoul. Relationship between measured metals concentrations showed that Si and Fe were associated with natural sources such as soil. Pb, Cu and Zn were closely related to urban anthropogenic sources such as fuel combustion. Especially, relationship between metals showed different association during yellow dust. Proper management for PM$_{10}$ will need in Asan, considered the concentrations of metallic elements in PM$_{10}$ in Asan were relatively higher than those in Seoul.se in Seoul.

Evaluation by Rocket Combustor of C/C Composite Cooled Structure for Combined-cycle Engine

  • Takegoshi, Masao;Ono, Fumiei;Ueda, Shuichi;Saito, Toshihito;Hayasaka, Osamu
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2008.03a
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    • pp.804-809
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    • 2008
  • In this study, the cooling performance of a C/C composite material structure with metallic cooling tubes fixed by elastic force without chemical bonding was evaluated experimentally using combustion gas in a rocket combustor. The C/C composite chamber was covered by a stainless steel outer shell to maintain its airtightness. Gaseous hydrogen as a fuel and gaseous oxygen as an oxidizer were used for the heating test. The surface of these C/C composites was maintained below 1500 K when the combustion gas temperature was about 2900 K and heat flux to the combustion chamber wall was about 9 $MW/m^2$. No thermal damage was observed on the stainless steel tubes which were in contact with the C/C composite materials. Results of the heating test showed that such a metallic-tube-cooled C/C composite structure is able to control the surface temperature as a cooling structure(also as a heat exchanger), as well as indicating the possibility of reducing the amount of the coolant even if the thermal load to the engine is high. Thus, application of the metallic-tube-cooled C/C composite structure to reusable engines such as a rocket-ramjet combined cycle engine is expected.

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Molybdenum release from high burnup spent nuclear fuel at alkaline and hyperalkaline pH

  • Sonia Garcia-Gomez;Javier Gimenez;Ignasi Casas;Jordi Llorca;Joan De Pablo;Albert Martinez-Torrents;Frederic Clarens;Jakub Kokinda;Luis Iglesias;Daniel Serrano-Purroy
    • Nuclear Engineering and Technology
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    • v.56 no.1
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    • pp.34-41
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    • 2024
  • This work presents experimental data and modelling of the release of Mo from high-burnup spent nuclear fuel (63 MWd/kgU) at two different pH values, 8.4 and 13.2 in air. The release of Mo from SF to the solution is around two orders of magnitude higher at pH = 13.2 than at pH = 8.4. The high Mo release at high pH would indicate that Mo would not be congruently released with uranium and would have an important contribution to the Instant Release Fraction, with a value of 5.3%. Parallel experiments with pure non irradiated Mo(s) and XPS determinations indicated that the faster dissolution at pH = 13.2 could be the consequence of the higher releases from metallic Mo in the fuel through a surface complexation mechanism promoted by the OH- and the oxidation of the metal to Mo(VI) via the formation of intermediate Mo(IV) and Mo(V) species.