• 공업화학
• /
• 제25권2호
• /
• pp.157-160
• /
• 2014

폐 젤리충진 통신케이블로부터 고순도 구리회수를 위하여 실리콘계 및 톨루엔계 합성 열매유와 폐식용유를 사용하여 적용성을 평가하였다. 실리콘계 오일의 경우 모든 조건에서 분리효율이 낮은 반면, 톨루엔계 오일 및 폐식용유의 경우 처리온도 및 시간을 조절함에 따라 높은 분리효율을 얻을 수 있었다. 폐식용유를 사용하는 50 kg급 밀폐형 대용량 설비를 이용하여 $300^{\circ}C$에서 60 min 이상 처리할 경우 99.2% 이상의 고순도 구리와이어를 100% 회수할 수 있었다.

• 방사성폐기물학회지
• /
• 제14권1호
• /
• pp.35-44
• /
• 2016

Leading national R&D project to design a PWR spent nuclear fuel interim dry storage system that has been under development since mid-2009, which consists of a dual purpose metal cask and concrete storage cask. To ensure the safe operation of dry storage systems in foreign countries, major confinement monitoring techniques currently consist of pressure and temperature measurement. In the case of a dual purpose metal cask, a pressure sensor is installed in the interspace of bolted double lid(primary and secondary lid) in order to measure pressure. A concrete storage cask is a canister based system made of double/redundant welded lid to ensure confinement integrity. For this reason, confinement monitoring method is real time temperature measurement by thermocouple placed in the air flow(air intake and exit) of the concrete structure(over pack and module). The use of various monitoring technologies and operating experiences for the interim dry storage system over the last decades in foreign countries were analyzed. On the basis of the analysis above, development of the confinement monitoring technology that can be used optimally in our system will be available in the near future.

• 한국기계가공학회지
• /
• 제13권4호
• /
• pp.69-74
• /
• 2014

A waste gate valve (WGV) assembly for a gasoline turbocharger is typically manufactured by means of precision casting. In this study, however, it was newly manufactured in a more innovative way, metal injection molding (MIM) using Inconel 713C alloy, and its performance was tested in a 1.6L direct injection gasoline engine by a thermal shock durability test that lasted 300 hours, after which the results were compared to those of a precision-cast WGV assembly with regard to the engine intake boost pressure, turbine wheel speed, and transient intake pressure. It was found that the two WGV assemblies showed similar performance levels throughout the durability test.

• Nuclear Engineering and Technology
• /
• 제34권1호
• /
• pp.80-89
• /
• 2002

A laboratory investigation of the behavior of radioactive metals under the various waste combustion atmospheres was conducted to predict the parameters that influence their partitioning behavior during waste incineration. Neodymium, samarium, cerium, gadolinium, cesium and cobalt were used as non-radioactive surrogate metals that are representative of uranium, plutonium, americium, curium, radioactive cesium, and radioactive cobalt, respectively. Except for cesium, all of the investigated surrogate metal compounds converted into each of their stable oxides at medium temperatures from 400 to 90$0^{\circ}C$, under oxygen- deficient and oxygen-sufficient atmospheres (0.001-atm and 0.21-atm $O_2$). At high temperatures above 1,40$0^{\circ}C$, cerium, neodymium and samarium in the form of their oxides started to vaporize but the vaporization rates were very slow up to 150$0^{\circ}C$ . Inorganic chlorine (NaCl) as well as organic chlorine (PVC) did not impact the volatility of investigated Nd$_2$O$_3$, CoO and Cs$_2$O. The results of laboratory investigations suggested that the combustion chamber operating parameters affecting the entrainment of particulate and filtration equipment operating parameters affecting particle collection efficiency be the governing parameters of alpha radionuclides partitioning during waste incineration.

• 한국염색가공학회지
• /
• 제17권1호
• /
• pp.20-29
• /
• 2005

Cotton fabric was treated with a reactive anionic agent in order to have anionic sites(-S03-) on it, which made it possible for the fabric to adsorb various cationic materials. In this study, the adsorptivity of various heavy metal ions such as Pb(II), Cd(II), Cr(III), Co(II), Cu(II), Ni (II) and Cr(VI) on the cotton fabrics treated with anionic agent was examined at the various conditions; concentrations of heavy metal ions, pHs of solution, reaction time and temperature. As a result, the adsorptivity of the heavy metal ions on the cotton fabrics treated with the anionic agent was highly increased comparing to that of untreated cotton fabrics. The order of the adsorptivity was as follows: $Pb(II)>Cd(II)>Cu(II)\geqNi(II)\geqCo(II)>Cr(III)\ggCr(VI)$. The adsorption amounts of most heavy metal ions were increased in weak alkaline conditions and were reached to an adsorption equilibrium within 10 ~ 30 minutes. The maximum adsorption ratios of Pb(II) and Cd(II) were respectively 99% and 80% of the initial concentration of heavy metal ions. Therefore the anionized cotton fabrics seem to be utilized as an adsorption fabrics for the removal of heavy metal ions in the waste water.

• 한국광물학회지
• /
• 제28권3호
• /
• pp.209-220
• /
• 2015

폐광산에 방치되어 있는 폐광석으로부터 유용금속이온을 그 지역 토착박테리아를 이용하여 효과적으로 용출시키고자 하였다. 토착호산성박테리아를 중금속 이온에 내성이 형성될 수 있도록 중금속 이온에 주기적으로 반복 적응시켰다. 그 결과 적응실험이 진행될수록 성장-배양액의 pH가 더 안정적으로 감소하였다. $CuSO_4{\cdot}5H_2O$에 9주와 12주 동안 적응시킨 박테리아를 이용하여 42일 동안 미생물용출을 수행한 결과, 용출-배양액의 pH는 적응 횟수에 비례하여 더 빠르게 감소하였다. 황동석과 Cu 함량이 고성 폐광석에 비하여 상대적으로 적게 포함된 연화 폐광석에서 더 많은 박테리아들이 부착하였고, 또한 Cu와 Fe 함량은 고성 박테리아 시료(각각의 용출률 = 66.77%와 21.83%)에 비하여 연화 박테리아 시료(각각의 용출률 = 92.79%와 55.88%)에서 더 많이 용출되었다. 따라서 중금속으로 오염된 광산에 오랫동안 서식한 토착호산성 박테리아를 이용한다면 또한 이 박테리아들을 목적중금속 이온이 포함된 성장-배양액에 계속하여 주기적으로 적응시킨다면, 폐광석으로부터 유용금속이온을 더 효과적으로 용출시킬 수 있을 것으로 확신한다.

• 대한기계학회논문집
• /
• 제19권12호
• /
• pp.3372-3381
• /
• 1995

An equilibrium analysis was carried out to determine principal species of heavy metals in waste incineration and their behaviors with variation of temperature, chlorine concentration, excess air ratio, and C/H ratio. The waste was assumed as a compound of hydrocarbon fuel, chlorine, and metals. Calculated results showed that the most important parameter to determine the principal species was temperature. Chlorine concentration also affected on mole fractions of the principal species. Generally principal species at high temperature were chlorides while there were some metals of which principal species were oxides. At low temperature mole fractions of the principal species increased, but at high temperature mole fractions of some metal species decreased. C/H ratio of the hydrocarbon fuel and excess air ratio had little effect on mole fractions of the metal species, compared to the temperature and chlorine concentration.

• 한국환경과학회지
• /
• 제11권9호
• /
• pp.993-999
• /
• 2002

Waste paper cup was sulfonated to be used as ion exchanger. Removal characteristic of copper and lead ion by prepared ion exchanger was investigated. The sulfonation was conformed by the high intensity band of $SO_3H$ group around 1100~$1160cm^{-1}$. The synthesized ion exchanger had greater removal ability for copper and lead ion than the original waste paper cup. Ion exchange system reached the final equilibrium plateau within 30min. The maximum removal capacities $q_{max}$ were calculated as 9.79mg/g fur copper and 15.95mg/g for lead, respectively. The affinity of lead based on a weight was higher than that of copper. The ion exchange phenomena appeared to follow a typical Freundlich isotherm.

• 한국방사성폐기물학회:학술대회논문집
• /
• 한국방사성폐기물학회 2007년도 학술논문요약집
• /
• pp.55-56
• /
• 2007

• 한국방사성폐기물학회:학술대회논문집
• /
• 한국방사성폐기물학회 2018년도 추계학술논문요약집
• /
• pp.323-324
• /
• 2018