• 제목/요약/키워드: metal stability

검색결과 1,252건 처리시간 0.021초

GMA용접에 있어서 스패터 발생에 미치는 와이어 탈산원소의 영향 (The Effect of Deoxidizers in a Wire on Spatter Generation in Gas Metal Arc Welding)

  • 방국수;안영호
    • Journal of Welding and Joining
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    • 제14권5호
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    • pp.145-150
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    • 1996
  • The variation of spatter generation in gas metal arc welding with welding conditions and wire compositions was investigated and interpreted in terms of arc stability. The transition range from a short circuit mode to a spray mode in the mixed gas welding showed an unstable arc and generated the largest amount of spatters. Titanium reduced spatters only in the globular mode of $CO_2$welding and silicon and manganese showed the same effect The effect of silicon and manganese, however, was no longer seen when titanium was added simultaneously to the wire. It is believed that deoxidizers easily form oxides on the anode and make the arc stable even in DCRP welding. The wires with deoxidizers also showed low short circuit frequency, resulting in the increase of large size spatters.

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래들에 의한 재해발생 실태와 예방대책 (The Status of Accident and Prevention Measures for Ladles)

  • 최승주;신운철
    • 대한안전경영과학회지
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    • 제16권3호
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    • pp.201-207
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    • 2014
  • This study is aimed to improve safety of ladle in the metal products manufacturing industry. Burns may occur from spills, spatters or eruptions of hot metal from ladles during pouring or transporting. According to the statistics of occupational accidents about the ladle, many victims were exposed to or contacted with extreme temperatures. The many fatal injuries occurred as a result of unexpected discharging of molten metal due to tipping over ladles. To prevent ladles from turning over, the trunnion axis shall be located below the center of gravity of the ladle at all operating condition. For this purpose, the equation is proposed to calculate the minimum location of a trunnion axis for definite static stability when tilting.

Cure Characteristics of Metal Particle Filled DGEBA/MDA/SN/ zeolite Composite System for EMI Shielding

  • Cho, Young-Shin;Lee, Hong-Ki;Shim, Mi-Ja;Kim, Sang-Wook
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1999년도 춘계학술대회 논문집
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    • pp.548-551
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    • 1999
  • The cure characteristics of metal particle filled DGEBA/MDA/SN/ zeolite epoxy resin composite system for EMI shielding were investigated by dynamic DSC run method and FT-lR spectroscopy. As the heating rate increased, the peak temperature on dynamic DSC curve increased because of the rapid cure reaction. From the straight line of the Kissinger plot, the curing reaction activation energy and pre-exponential factor could be obtained. As the post-curing time at 15$0^{\circ}C$ increased, the glass increased the glass transition temperature or the thermal stability increased. When the post curing time is too long, the system filled with metallic Al particle can be thermally oxidized by the catalytic reaction of metal filler and the thermal stability of the composite for the EMI shielding application may be decreased.

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Bonding and Electronic Consideration in the Metal-Metal Bonded Edge Sharing Complexes

  • Jaejung Ko;Kuk-Tae Park;Ikchoon Lee;LEe Bon-Su
    • Bulletin of the Korean Chemical Society
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    • 제10권6호
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    • pp.515-521
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    • 1989
  • The molecular interaction of $W_2(NH_2)_4Cl_4$ fragment with chlorine ligands has been studied by means of extended Huckel calculations. We have extended the Huckel calculation to unknown edge-sharing $W_2(NH_2)_4Cl_4({\eta}-X)_2$ complexes (X = CO, H) in order to compare the stability of the complexes. The calculations showed that the size and electronic property of bridged ligand are important in determining the stability. The stabilities of the related metal-metal bonded edge-sharing complexes are discussed.

식품 소재로서 장미꽃잎 색소의 안정성 (Stability for Rose Petals Pigment as a Food Material)

  • 양미옥;조은자
    • 동아시아식생활학회지
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    • 제16권4호
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    • pp.468-473
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    • 2006
  • This study was conducted to develop pigment of flowers as a food material and the red rose(Rosa hybrida L.) was used for this study. To check the possibility of using the rose pigment as a food additive we have extracted the pigment from rose and examined all the factors (pH, temperature, free sugars, organic acids, metal ions) for stability. The results obtained are as follows: In examining the stability of the pigment, the residue of the pigment noticeably decreased with the increase of the pH and the temperature, and among free sugars (fructose, glucose, sucrose) the addition of fructose made the residue the lowest. With the addition of organic acids the samples exhibited the hyperchromic effect throughout the period of the storage. The pigment residue decreased when the amount of the metal ions increased and especially the Cu$^{2+}$ ion was most destructive.

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질소-산소계 시프염기 리간드의 합성과 전이금속(II) 착물의 안정도상수결정 (Synthesis of Schiff-Base Ligands and Determination of Stability Constants of Their Transition Metal(II) Complexes)

  • 김선덕;송찬익;김준광;김정성
    • 한국환경과학회지
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    • 제13권9호
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    • pp.835-843
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    • 2004
  • N,N-bis(2-salicylaldehyde)dipropylenetriamine(5- Hsaldipn), N,N-bis( 5-bromosalicyl-aldehyde) dipropylenetriamine (5-Brsaldipn), N,N-bis(5-chlorosalicy laldehyde )dipropylene-triamine(5-Clsaldipn), N,N-bis(2-hydroxy- $5-methoxy-benzaldehyde)dipropylenetriamine(5-OCH_3saldipn)$ and N,N-bis (2-hydroxy-5-nitrobenzaldehyde)dipropylenetriamine $(5-NO_2saldipn)$ were synthesized and characterized by elemental analysis, infrared spectrometry, NMR spectrometry and mass spectrometry. Their proton dissociation constants were determined in 70% dioxane/30% water solution by potentiometric. Stability constants of the complexes between these ligands and the metal ions such as Cu(II), Ni(II) and Zn(II) were measured in dimethyl sulfoxide by a polarographic method. Stability constants for the ligands were in the order of $5-OCH_3$ > 5-H > 5-Br > 5-Cl > $5-NO_2$ saldipn. Enthalpy and entropy changes were obtained in negative values.

Stability of five layer sandwich beams - a nonlinear hypothesis

  • Smyczynski, Mikolaj J.;Magnucka-Blandzi, Ewa
    • Steel and Composite Structures
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    • 제28권6호
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    • pp.671-679
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    • 2018
  • The paper is devoted to the stability analysis of a simply supported five layer sandwich beam. The beam consists of five layers: two metal faces, the metal foam core and two binding layers between faces and the core. The main goal is to elaborate a mathematical and numerical model of this beam. The beam is subjected to an axial compression. The nonlinear hypothesis of deformation of the cross section of the beam is formulated. Based on the Hamilton's principle the system of four stability equations is obtained. This system is approximately solved. Applying the Bubnov-Galerkin's method gives an ordinary differential equation of motion. The equation is then numerically processed. The equilibrium paths for a static and dynamic load are derived and the influence of the binding layers is considered. The main goal of the paper is an analytical description including the influence of binding layers on stability, especially on critical load, static and dynamic paths. Analytical solutions, in particular mathematical model are verified numerically and the results are compared with those obtained in experiments.

Vibration and stability of composite cylindrical shells containing a FG layer subjected to various loads

  • Sofiyev, A.H.
    • Structural Engineering and Mechanics
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    • 제27권3호
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    • pp.365-391
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    • 2007
  • The vibration and stability analysis is investigated for composite cylindrical shells that composed of ceramic, FGM, and metal layers subjected to various loads. Material properties of FG layer are varied continuously in thickness direction according to a simple power distribution in terms of the ceramic and metal volume fractions. The modified Donnell type stability and compatibility equations are obtained. Applying Galerkin's method analytic solutions are obtained for the critical parameters. The detailed parametric studies are carried out to study the influences of thickness variations of the FG layer, radius-to-thickness ratio, lengths-to-radius ratio, material composition and material profile index on the critical parameters of three-layered cylindrical shells. Comparing results with those in the literature validates the present analysis.

Oxidation Behaviors of Porous Ferritic Stainless Steel Support for Metal-supported SOFC

  • Moon, I.J.;Lee, J.W.;Cho, H.J.;Choi, G.M.;Sohn, H.K.
    • Corrosion Science and Technology
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    • 제9권5호
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    • pp.196-200
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    • 2010
  • Recently porous metal has been used as supporting metal in planar type SOFC. In order to search optimum alloys for porous metal support and estimate the stability of metal-supported SOFC at high temperature, it is necessary to investigate the oxidation behaviors of porous material for metal support in comparison with dense material. Oxidation tests of porous and dense stainless steels were conducted at $600^{\circ}C$ and $800^{\circ}C$. Since the specific surface area of porous material is much larger than that of dense material, surface area should be considered in order to compare the oxidation rate of porous stainless steel with that of dense stainless steel. The specific surface area of porous body was measured using image analyzer. The weight gain of porous stainless steel was much greater than those of dense stainless steels due to its larger specific surface area. considering the specific surface area, the oxidation rate of porous stainless steel is likely to be the same as that of dense stainless steel with the same surface area. The change in chromium content in stainless steel during oxidation was also investigated. The experimental result in chromium content in stainless steel during oxidation corresponded with the calculated value. While the change in chromium content in dense stainless steel during oxidation is negligible, chromium content in porous stainless steel rapidly decreases with oxidation time due to its large specific surface area. The significant decrease in chromium content in porous stainless steel during oxidation may affect the oxidation resistance of porous stainless steel support and long term stability of metal-supported SOFC.

다량의 붕소원소를 함유하는 식물의 중금속 이온 교환반응 (Heavy Metal Son Exchange Reaction in Boron-Rich Containing Plants)

  • 배계선;성대동
    • 한국환경과학회지
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    • 제5권6호
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    • pp.757-762
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    • 1996
  • The removal effectiveness of various heavy metal ions in boron-rich containing plants has been studied by means of spectroscopic and pH methods. Treatment of the boron-rich containing sample which was collected from cherry and root of cabbage to heavy metal ions is resulted in that an excellent removal effect shows in the case of large ionic size of heavy metal. Stability constants are depended on the variation of pH.

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